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CBSE Questions for Class 11 Engineering Chemistry Some P-Block Elements Quiz 12 - MCQExams.com

Which of the following is incorrect regarding the structural features of borax?
  • It has two tetrahedral and two triangular units
  • All the boron atoms are not in same hybrid state
  • Each boron atom of a pair is tetravalent
  • Only one boron atom has a lone pair of electrons
Consider the following reactions:

i)Cr2O3+2AlAl2O3+2Cr+heat
ii)Al2O3+2CrCr2O3+2Al+heat
iii)2Al+6NaOH2Na3AlO3+3H2

Out of these, the possible reactions are:
  • i and iii
  • ii and iii
  • i and ii
  • i , ii and iii
Order of stability of the ions of Ge, Sn and Pb is:
  • Ge2+<Sn2+<Pb2+
  • Ge4+<Sn4+<Pb4+
  • Sn4+<Sn2+
  • Pb2+<Pb4+
List -I                                                                           List -2
A. Al2O3                                                                Dimer
B. AlCl3                                                                  Non-metal
C. B                                                                          Acidic
D.B2O3                                                                    Amphoteric 

The correct match is:
  • A-4, B-3, C-2, D-1
  • A-1, B-4, C-3, D-2 
  • A-2, B-3, C-4, D-1
  • A-4, B-1, C-2, D-3
Select the correct order with respect to acidic nature of the given compounds.
  • Al2O3<In2O3<Tl2O<B2O3
  • Tl2O<In2O3<Al2O3<B2O3
  • Al2O3<B2O3<In2O3<Tl2O
  • Tl2O<Al2O3<B2O3<In2O3
Which of the following statement is/are correct?
  • B2H6 is not an electron-deficient compound
  • Boron has an extremely high melting point because of the strong binding forces in the covalent polymer
  • BF3 and BrF3 molecules have different shapes
  • Ortho boric acid contains pyramidal BO33 units
In representative elements the ionization energy values generally decrease smoothly down the group. But in boron group the values show an erratic trend. This is mainly due to : 
  • increase in metallic nature down the group
  • inert pair effect in the heavier elements of the group
  • d-block contraction and lanthanide contraction affecting the values of later elements due to poor shielding by d and f electrons
  • the different type of packing in their crystalline structure
Which of the following have a three dimensional network structure?
  • SiO2
  • (BN)5
  • P4(white)
  • CCl4
Consider the following compound 
If hybridization of 'C' is sp (s+px) and nodal plane of π-bond present between C and S is 'XY' plane then which of the following statement(s) is/are CORRECT regarding given information for above compound.

1200928_9311d2520eab4d5c8973bf131667dde1.PNG
  • π- bond between N and C atom is formed by sideways overlapping of py orbitals
  • (2pπ3dπ) back bond between N and Si atom can be formed by (dxzpz) orbital overlapping
  • σ- bond between N and Si atom is formed by sp3 hybrid orbital of Si and spx hybrid orbital of N atom. 
  • Six atoms of given compound are lying in same plane.
Which one of the following statements is incorrect about the structural properties of BF3?
  • The unsual shortness of BF bonds is due to pπpπ interaction between B and F atoms
  • All the three BF bond lengths are equal
  • Double bond is delocalized giving three resonance structures.
  • Due to back bonding, BF3 and BCl3 are not isostructural molecules
The aqueous solution of 'A' is alkaline due to
  • the presence of Ca2+ ions
  • the presence of H3BO3
  • hydrolysis of B4O27
  • hydrolysis of CO23
Select the correct statements.
  • Oxides of boron (B2O3) and silicon (SiO2) are acidic in nature.
  • Oxides of aluminium (Al2O3) and gallium (Ga2O3) are amphoteric in nature.
  • Oxides of indium (In2O3) and thallium (Tl2O3) are basic in nature.
  • Oxides of germanium (GeO2) and tin (SnO2) are acidic in nature.
Alkyl substituted chlorosilane, RnSiCl(4n), on hydrolysis and then condensation polymerisation yields silicones. What is the value of n in the alkyl substituted chlorosilane used for the preparation of cross-linked silicone?
  • 1
  • 2
  • 3
  • 4
How many oxygen atoms are shared per SiO4 tetrahedral unit in mineral wollastonite [Ca3(Si3O9)]?
  • 2
  • 3
  • 1
  • 4
Silica reacts with Mg to form a magnesium compound A. A reacts with dilute HCl and forms B. The compound B is:
  • MgSiO
  • MgO
  • MgCl2
  • SiCl4
The chain length of silicone polymer can be controlled by adding:
  • MeSiCl3
  • Me2SiCl2
  • Me3SiCl
  • Me4Si
Which of the following oxides is acidic in nature?
  • B2O3
  • Al2O3
  • Ga2O3
  • In2O3
Ammonia gas is not prepared by :
  • reduction of sodium nitrite or sodium nitrate by the reaction of zinc dust and sodium hydroxide.
  • hydrolysis of calcium cyanamide.
  • heating ammoniumchloridewith slaked lime.
  • heating of (NH4)2Cr2O7
In silicones, the maximum number of silicon atoms directly linked to an oxygen atom is :
  • 3
  • 4
  • 1
  • 2
Which among the following substances is not a component of the mixture used for glazing pottery?
  • Feldspar
  • Silica
  • Borax
  • Alumina
Which of the following does not react with cold water?
  • SiC
  • AIN
  • CaC2
  • Al4C3
Me3SiCl is mixed with Me2SiCl2 to get a polymers called silicones of the type:

  • Both A and B
  • None of these
Which of following stability order is /are correct due to inert pair effect?
  • Hgo>Hg2+
  • Bi3+<Bi5
  • Pb2+>Pb4+
  • Fe2+<Fe3+
Among the following, the element which show inert-pair effect are:
  • Bi
  • Sn
  • Pb
  • C
The correct B --- F bond length follows the sequence :
  • BF3<BF2OH<BF2NH2<BF4
  • BF2NH2<BF2OH<BF3<BF4
  • BF3<BF4<BF2OH<BF2NH2
  • BF3<BF2NH2<BF2OH<BF4
Microcosmic salt and borax are used in the identification of cations by dry tests. They are respectively :
  • NaBO2 and NaPO3
  • NaNH4HPO4.4H2O and Na2B4O7.10H2O
  • NaPO3 and NaBO2
  • Na2B4O7 and NaNH4HPO4
Read the following write-ups and answer the questions at the end of it. 
Silicons are synthetic polymers containing repeated R2SiO units. Since, the empirical formula is that of a ketone (R2CO), the name silicone has been given to these materials. Silicones can be made into oils, rubbery elastomers and resins. They find a variety of applications because of their chemical inertness, water repelling nature, heat- resistance and good electrical insulating property. Commercial silicon polymers are usually methyl derivatives and to a lesser extent phenyl derivatives and  are synthesised by the hydrolysis of R2SiCl2[R=methyl (Me) or phenyl (Ph)]

If we mix Me3SiCl with Me2SiCl2, we get silicones of the type:
  • both of the above
  • none of the above
The silicate anion in the mineral kinoite is a chain of three SiO4 tetrahedra that share corners with adjacent tetrahedra. The mineral also contains Ca2+ ions, Cu2+ ions and water molecules in a 1:1:1 ratio. The mineral is represented as :
  • CaCuSi3O10H2O
  • Ca2Cu2Si3O10H2O
  • Ca2Cu2Si3O102H2O
  • none of these
(Si2O5)2nn anion is obtained when :
  • no oxygen of a SiO44 tetrahedron is shared with another SiO44 tetrahedron
  • one oxygen of a SiO44 tetrahedron is shared with another SiO44 tetrahedron
  • two oxygen of a SiO44 tetrahedron is shared with another SiO44 tetrahedron
  • three oxygen of a SiO44 tetrahedron is shared with another SiO44 tetrahedron
Al+N2(A)H2O(B)K2HgI4/OH(D) (brown ppt.)

What is (D)?
  • H2NHgHgI
  • H2NHgOHgI
  • H2NOHgHgI
  • H2NHgIHgO
One natural source of atmospheric CO2 is precipitation reaction such as the precipitation of silicates in the oceans:

Mg2+(aq)+SiO2(dispersed)+2HCO3(aq)MgSiO3(s)+2CO2(g)+H2O(l)

How many grams of magnesium silicate would be precipitated during the formation of 100 L of CO2 at 30oC and 775 torr? 
(Mg=24,Si=28,C=12,O=16)
  • 102 g
  • 410 g
  • 205 g
  • 51 g
Borax in its crystal possess:
  • 3 tetrahedral unit
  • 2 tetrahedral and 2 planar triangular units
  • 3 tetrahedral and 2 planar triangular units
  • all tetrahedral units
Borax is converted into crystalline boron by the following steps:

BoraxXH3BO3ΔB2O3YΔB
Then X and Y are respectively:
  • HCl,Mg
  • HCl,C
  • C,Al
  • HCl,Al
Select the correct statement(s) :
  • When Al is added to potassium hydroxide solution,hydrogen gas is evolved
  • H2SiF6 is formed when silica reacts with hydrogen fluoride followed by hydrolysis
  • Phosphine gas is formed when red phosphorus is heated with NaOH
  • (NH4)2SO4.FeSO4.6H2O is called alums
One type of silicon adhesive uses a polymer that has two OH groups left on the ends of the chain:
HOSi(CH3)2[OSi(CH3)2]nOSi(CH3)2OH
It has been found that this kind of polymer reacts easily with an organic-silicon molecule that contains acetate (CH3COO) group. Which of these three molecules CH3COOSi(CH3)3,  (CH3COO)2Si(CH3)2(CH3COO)3SiCH3 would you choose to add to the hydroxy polymer in order to make a strong adhesive?
  • CH3COOSi(CH3)3,
  • (CH3COO)2Si(CH3)2
  • (CH3COO)3SiCH3
  • None of the above
Select correct statements:
  • Hydrides of B and Si are volatile and catch fire on exposure to air.
  • Oxides of B and Si(B2O3 and SiO2) are acidic in nature.
  • Borates and silicates have tetrahedral BO4 and SiO4 structural units.
  • All the above are correct statements.
Select correct statement about stability of cations.
  • Ge4+>Sn4+>Pb4+
  • Ge2+<Sn2+<Pb2+
  • Pb2+>Pb4+,Sn4+>Sn2+
  • All the above are correct statements.
Silicone's :
  • are synthetic polymer containing repeating (R2SiO) units.
  • are formed by hydrolysis of R2SiCl2.
  • are natural occurring repeated (SiO4) units.
  • single R2SiO unit.
Silicone's are : 
  • synthetic polymers containing repeated R2SiO units.
  • silicates with common SiO4 unit.
  • ketones with silyl group (SiH3) similar to alkyl (SiH3)2CO
  • Zircon (neso silicates)
The color imparted by Co(Il) compounds to glass is :
  • deep blue.
  • green.
  • yellow.
  • red.
Which is incorrect statement about silicons?
  • They are repeating units (SiO4) in silicates
  • They are synthetic polymers containing repeated R2SiO units
  • They are formed by hydrolysis of R2SiCl2
  • All the above are incorrect statements
Select correct statement(s) :
  • Si uses all of its valence electrons in an sp3-hybridization and crystallizes in an fcc structure similar to diamond.
  • Diamond is an electrical insulator, graphite is an electrical conductor but silicon is a semiconductor.
  • Most common silica is quartz.
  • All of the above are correct statements.
If we mix SiMe3Cl with SiMe2Cl2, we get silicone's of the type:
165021_5d65947ae1264057afae22fadcfeabac.png
  • both (a) and (b)
  • none of the above
Ca2B6O11Δ[X]+CaCO3+NaBO2 (unbalanced equation) Which of the following is/are correct choice(s) for [X]?
  • The structure of anion of crystalline [X] has one boron atom sp3 hybridized and other three boron atoms sp2 hybridized
  • X with NaOH(aq) gives a compound which on reaction with hydrogen peroxide in alkaline medium yields a compound used as the brightener in soaps
  • Hydrolysis of [X] with HCl or H2SO4 yields a compound which on reaction with HF gives fluoroboric acid
  • [X] on heating with chromium salts in oxidizing flame gives green colored bead
B3+ ion can not exist in aqueous solution because of its :
  • strong reducing ability
  • strong oxidizing ability
  • small size and large charge
  • large size and small charge
Aqueous solution of borax reacts with 2 mol of acids. This is because of?
  • Formation of 2 mol of B(OH)3 only.
  • Formation of 2 mol of [B(OH)4] only.
  • Formation of 1 mol each of B(OH)3 and [B(OH)4] only.
  • Formation of 2 mol each of [B(OH)4] and B(OH)3, of which [B(OH)4] reacts with acid.
Borax is actually made of two tetrahedral and two triangular units joined together and should be 
written as : Na2[B4O5(OH)4].8H2O.
Consider the following statements about borax:
Each boron atom has four B-O bonds
EAch boron atom has three B-O bonds
Two boron atoms have four B-O bonds while other two have three B-O bonds
Each boron atom has one-OH groups
Select correct statement(s) -
  • 1, 2
  • 2, 3
  • 3, 4
  • 1, 3
Identify the only 'INCORRECT' statement of the following.
  • B - O - B bonds in sodium peroxoborate are similar
  • B-O-B bonds in potassium trioborate are 3
  • Ortho borate ion is triangular plannar
  • B -O-B bonds in diborate ion is 1.
Identify the correct order of boiling point :
  • HF<HCl<HBr<HI
  • NH3<PH3<AsH3<SbH3
  • CH4<SiH4<GeH4<SnH4
  • H2S<H2Se<H2Te<H2O
The incorrect statements among the following are:
  • NCl5 does not exist while PCl5 does
  • Pb prefers to form tetravalent compounds
  • The three CO bond are not equal in the carbonate ion
  • Both O+2 and NO are paramagnetic
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