Explanation
The inertness of s subshell electrons towards the bond formation is called inert pair effect or it can be said as the inactiveness of electrons present in outermost shell (i.e. ns2) to get unpaired and involve in bond formation is called inert pair effect.
for example:
1) In 13th group, thallium can exhibit +1 and +3 oxidation states but it is stable in +1 oxidation state only due to inert pair effect
2) In 14th group , lead shows both +2 and +4 oxidation states but it is stable in +2 oxidation state due to inert pair effect.
3)In group 15 elements, the stability of +3 oxidation state increases down the group and that of +5 oxidation state decreases down the group, due to inert pair effect."
The inertness of s subshell electrons towards the bond formation is called inert pair effect or it can be said as the inactiveness of electrons present in the outermost shell (i.e. ns2) to get unpaired and involve in bond formation is called inert pair effect.
2) In 14th group, lead shows both +2 and +4 oxidation states but it is stable in +2 oxidation state due to inert pair effect.
3)In group 15 elements, (Bi) the stability of +3 oxidation state increases down the group and that of +5 oxidation state decreases down the group, due to inert pair effect.
Hence, the correct options are A, B and C
Hence, the correct option is A.
Explanation:
In NCl5, there is absence of d−orbitals. PCl5 has d−orbitals, so it exists.
Due to inert pair effect Pb2+ is more stable than Pb4+. So it doesn’t form tetravalent compounds.
In carbonate ion the bonds are equal due to the resonance.
The configuration of O+2(8+8−1=15)=σ1s2,σ∗1s2,σ2s2,σ∗2s2 σ2p2z,π2p2x≈2p2y,π2p∗x1≈π2p∗y0
The configuration of NO(7+8=15)=σ1s2,σ∗1s2,σ2s2,σ∗2s2 σ2p2z,π2p2x≈2p2y,π2p∗x1≈π2p∗y0
Both have one unpaired electron so they are paramagnetic.
Final answer: The statements B and C are incorrect. So the correct answer is options B and C.
Please disable the adBlock and continue. Thank you.