JEE Questions for Chemistry Organic Chemistry Some Basic Principles And Techniques Quiz 1 - MCQExams.com

Which type of isomerism is shown by 2, 3-dichlorobutane ?
  • Structural
  • Geometric
  • Optical
  • Diastereomer
Among the following compounds, the most acidic is
  • p-nitrophenol
  • p-hydroxybenzoic acid
  • o-hydroxybenzoic acid
  • p-toluic acid
Orbital interaction between the a-bonds of a substituent group and a neighbouring it-orbital is known as
  • hyperconjugation
  • inductive effect
  • steric effect
  • electric quadrapole interactions
+I-effect is shown by
  • -CH3
  • -Br
  • -Cl
  • -NO2
The IUPAC name of the following compound is
Chemistry-Organic Chemistry Some Basic Principles and Techniques-5828.png
  • trans-2-chloro-3-iodo-2-pentene
  • cis-3-iodo-4-chloro-3-pentene
  • trans-3-iodo-4-chloro-3-pentene
  • cis-2-chloro-3-iodo-2-pentene
The reaction intermediate produced by homolytic cleavage of a bond is called
  • carbene
  • carbocation
  • carbanion
  • free radical
Which kind of fission is favoured by sunlight?
  • None of these
  • Heterolytic fission
  • Homolytic fission
  • Both (and (2)
The correct order for homolytic bond dissociation energies (AH in kcal/mol) for CH4 (A), C2 H6 (B) and CH3 Br (C), under identical experimental conditions, is
  • C > B > A
  • B > C > A
  • C > A > B
  • A > B > C
Chlorobenzene is o, p -directing in electrophilic substitution reaction. The directing influence is explained by
  • +M of Ph
  • +I of Cl
  • +M of Cl
  • -I of Ph
The state of hybridization of C2, C3, C5 and C6 of the hydrocarbon,
Chemistry-Organic Chemistry Some Basic Principles and Techniques-5834.png
  • sp3, sp2, sp2 and sp
  • sp, sp2, sp2 and sp3
  • sp, sp2, sp3 and sp2
  • sp, sp3, sp2 and sp3
Geometry of methyl free radical is
  • pyramidal
  • planar
  • tetrahedral
  • linear
Due to the presence of an unpaired electron, free radicals are
  • cations
  • anions
  • chemically inactive
  • chemically reactive
Which is the most stable carbocation?
  • iso-propyl cation
  • Triphenylmethyl cation
  • Ethyl cation
  • n-propyl cation
How many enols (including stereo isomers) exist for 3-hexanone?
  • Two
  • Three
  • Four
  • Six
The number of possible structural isomers of butene are
  • 3
  • 2
  • 4
  • 5
  • 1
In the hydrocarbon
Chemistry-Organic Chemistry Some Basic Principles and Techniques-5839.png
  • sp2, sp, sp3
  • sp, sp3, sp2
  • sp, sp2, sp3
  • sp3, sp2, sp
The maximum number of possible optical isomers in 1-bromo-2-methyl cyclobutane is
  • 4
  • 2
  • 8
  • 16
The general molecular formula, which represents the homologous series of alkanols is
  • CnH2nO
  • CnH2n + 1O
  • CnH2n + 2O
  • CnH2n O2
Least stable conformer of cyclohexane is
  • chair
  • boat
  • twist boat
  • planar hexagon
Optical isomerism is shown by
  • propanol-2
  • butanol-2
  • ethanol
  • methanol
The number of stereoisomers obtained by bromination of trans-2-butene is
  • 1
  • 2
  • 3
  • 4

Chemistry-Organic Chemistry Some Basic Principles and Techniques-5844.png
  • 1- chloro -1-oxo - 2, 3- dimethyl pentane
  • 2-ethyl -3- methylbutanoyl chloride
  • 2, 3-dimethylpentanoyl chloride
  • 3, 4-dimethyl pentanoyl chloride
Identify, which of the below does not possess any element of symmetry ?
  • (+) (-) tartaric acid
  • Carbon tetrachloride
  • Methane
  • Meso-tartaric acid
The correct order regarding the electronegativity of hybrid orbitals of carbon is
  • sp > sp2 > sp3
  • sp < sp2 > sp3
  • sp < sp2 < sp3
  • sp > sp2 < sp3
Which one of the following shows functional isomerism ?
  • C2 H4
  • C3 H6
  • C2 H5 OH
  • CH2 Cl2
The number of isomers for the compound with the molecular formula C2Br ClFI is
  • 3
  • 4
  • 5
  • 6
  • 7
Geometrical isomerism is possible in
  • acetone oxime
  • isobutene
  • acetophenone oxime
  • benzophenone oxime
Ethers are isomeric with
  • aldehydes
  • ketones
  • both aldehydes and ketones
  • alcohols
Geometrical isomerism is possible in case of
  • pentene-2
  • propane
  • pentane
  • ethene
Propanal and propanone are
  • functional isomers
  • enantiomers
  • chain isomers
  • structural isomers
How many structural isomers are possible for C4 H9 Cl ?
  • 2
  • 4
  • 8
  • 10
The incorrect IUPAC name is

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5851.png
  • 2)
    Chemistry-Organic Chemistry Some Basic Principles and Techniques-5852.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5853.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5854.png
Pick out the alkane which differs from the other members of the group.
  • 2,2-dimethyl propane
  • Pentane
  • 2-methyl butane
  • 2,2-dimethyl butane
Which of the following is a dynamic isomerism?
  • Metamerism
  • Geometrical isomerism
  • Tautomerism
  • Coordinate isomerism
Nitroethane can exhibit which one of the following kinds of isomerism
  • Metamerism
  • Optical activity
  • Tautomerism
  • Position isomerism
Names of some compounds are given. Which one is not correct in IUPAC system?

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5858.png
  • 2)
    Chemistry-Organic Chemistry Some Basic Principles and Techniques-5859.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5860.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5861.png
Enol content is highest in
  • acetone
  • acetophenone
  • acetic acid
  • acetyl acetone
Racemic mixture is formed by mixing two
  • isomeric compounds
  • chiral compounds
  • meso compounds
  • enantiomers with chiral carbon
Naphthalene can be easily purified by
  • sublimation
  • crystallisation
  • distillation
  • vaporisation
The best method to separate the mixture of ortho and para nitrophenol (1:is
  • vaporisation
  • colour spectrum
  • distillation
  • crystallisation
Which method is used to separate sugars ?
  • Fractional crystallisation
  • Sublimation
  • chromatography
  • Benedict's, reagent
A device called nitrometer is used in
  • Dumas method
  • Kjeldahl’s method
  • Carius method
  • Leibig’s method
Kjeldahl’s method can not be used for estimation of nitrogen in ...
  • DNA
  • RNA
  • 1 and 2
  • Neither 1 and 2
Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is :

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5862.png
  • 2)
    Chemistry-Organic Chemistry Some Basic Principles and Techniques-5863.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5864.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5865.png
The structure of isobutyl group in an organic compound is :

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5866.png
  • 2)
    Chemistry-Organic Chemistry Some Basic Principles and Techniques-5867.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5868.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5869.png
Which nomenclature is not according to IUPAC system?

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5871.png
  • 2)
    Chemistry-Organic Chemistry Some Basic Principles and Techniques-5872.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5873.png

  • Chemistry-Organic Chemistry Some Basic Principles and Techniques-5874.png
Which of the following mentioned is a type of hydrocarbon?
  • Saturated hydrocarbon
  • Unsaturated hydrocarbon
  • Aromatic hydrocarbon
  • All of the above
Which one of the following acid does not have a carboxylic group?
  • Methanoic acid
  • Ethanoic acid
  • Propanoic acid
  • Picric acid
What is the IUPAC name of isopropylamine?
  • Propan–2–amine
  • Ethanamine
  • 2–aminotoluene
  • Propan–l–amine
The IUPAC name of acryldehyde is
  • prop-2-en-l-al
  • propenyl aldehyde
  • but-2-en-l-al
  • propenal
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