JEE Questions for Chemistry The D And F Block Elements Quiz 2 - MCQExams.com

The spin only magnetic moment of Mn4+ ion is nearly
  • 3 BM
  • 6 BM
  • 4 BM
  • 5 BM
FeSO4∙(NH4 )2 SO4∙6H2O is called
  • green salt
  • Glauber's salt
  • Mohr's salt
  • alum
Which of the following is called white vitriol ?
  • ZnCl2
  • MgSO4 ∙ 7H2O
  • Al2 (SO4)3
  • ZnSO4 ∙ 7H2O
Which of the following is not correct about transition metals ?
  • Their compounds are generally coloured
  • They can form ionic or covalent compounds
  • Their melting and boiling points are high
  • They do not exhibit variable valency
Carbon content of
  • steel is in between those of cast iron and wrought iron
  • cast iron is in between those of steel and wrought iron
  • wrought iron is in between those of steel and cast iorn
  • steel is higher than that of pig iron
Which one of the following transition metal ions is diamagnetic ?
  • Co2+
  • Ni2+
  • Cu2+
  • Zn2+
Which of the following statements concerning transition elements is false ?
  • They are all metals
  • They easily form complex coordination compounds
  • Compounds containing their ions are mostly coloured
  • They show multiple oxidation states always differing by units of two

Chemistry-The d and f Block Elements-8376.png
  • 3
  • 4
  • 1
  • 2
'Hydride gap' is referred to which region of the periodic table ?
  • Groups 3, 4 and 5
  • Groups 5, 6 and 7
  • Groups 4, 5 and 6
  • Groups 7, 8 and 9
  • Groups 6, 7 and 8
Stainless steel has iron and
  • Cr
  • Cu
  • Co
  • Zn
Formation of coloured ions by transition metals signifies
  • absorption of light from UV range
  • emission of light
  • presence of unpaired electrons in s and p-orbitals
  • complimentary colours to the absorbed light
Transition metal ions show colour because
  • they absorb light
  • they emit light
  • they are paramagnetic
  • they exhibit d -d transition
What is the oxidation state of iron in Mohr's salt?
  • +3
  • 0
  • +2
  • +1
The gas obtained by reaction of K4Fe(CN)6 with conc. H2 SO4 is
  • H2S
  • CO
  • NO2
  • CO2
Magnetic moment of manganese in (NH4)2 MnBr2 is
  • 3.87 BM
  • 5.91 BM
  • 4.89 BM
  • 2.82 BM

Chemistry-The d and f Block Elements-8377.png
  • MnBr4
  • MnOBr2

  • Chemistry-The d and f Block Elements-8378.png
  • MnO , BrO
Among the following, the coloured compound is
  • CuCl
  • K3[Cu (CN)4]
  • CuF2
  • [Cu (CH3 CN)4 ]BF4
Which of the following is not a characteristic of transition elements ?
  • Variable oxidation states
  • Formation of coloured compounds
  • Formation of interstitial compounds
  • Natural radioactivity
The magnetic moment of a salt containing Zn2+ ion is
  • 0
  • 1.87
  • 5.92
  • 2
Which of the oxide of manganese is amphoteric?
  • MnO2
  • Mn2O3
  • Mn2O7
  • MnO
Which of the following ions is colourless in solution ?
  • V3+
  • Cr3+
  • Co2+
  • Sc3+
Mercury is a liquid metal because
  • it has a completely filled s-orbital
  • it has a small atomic size
  • it has a completely filled d-orbital that prevents d-d overlapping of orbitals
  • it has a completely filled d-orbital that causes d-d overlapping
Pick out the correct statements from the following.
I. Cobalt (III) is more stable in octahedral complexes.
II. Zinc forms coloured ions or complexes.
III. Most of the d-block elements and their compounds are ferromagnetic.
IV. Osmium shows (VIII) oxidation state.
V. Cobalt (II) is more stable in octahedral complexes.
  • I and II
  • I and III
  • II and IV
  • I and IV
  • II and V
Which of the following is not a member of 3d-transition series '?
  • Fe
  • Co
  • Au
  • Cu
KMnO4 (acidic/alkaline) is not decolourised by
  • Mohr salt
  • oxalic acid
  • benzene
  • propene
The highest oxidation state exhibited by transition metals is
  • +7
  • +8
  • +6
  • +5
Which one of the following statements is not true with regard to transition elements ?
  • They readily form complex compounds
  • They show variable oxidation states
  • All their ions are colourless
  • Their ions contain partially filled d-electrons
The highest magnetic moment is shown by the transition metal ion with the configuration
  • 3d 2
  • 3d 5
  • 3d 7
  • 3d 9
A transition metal ion exists in its highest oxidation state. It is expected to behave as
  • a chelating agent
  • a central metal in a coordination compound
  • an oxidising agent
  • a reducing agent
When oxyhaemoglobin changes to deoxyhaemoglobin, Fe2+ ion changes from
  • diamagnetic to paramagnetic
  • paramagnetic to diamagnetic
  • diamagnetic to ferromagnetic
  • paramagnetic to ferromagnetic
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