The mean free path of gas molecules depends on (d = molecular diameter)

  •  d                                         

  •  d2

  •  d-2                                   

  •  d-1

For Boyle's law to hold the gas should be :

  • Perfect and of constant mass and temperature

  • Real and of constant mass and temperature

  • Perfect and at a constant temperature but variable mass

  • Real and at a constant temperature but variable mass

The kinetic energy of one mole gas at 300 K temperature, is E. At 400 K temperature kinetic energy is E'. The value of E'/E is

  •   1.33                         

  •   43

  •   169                           

  •   2

Consider a 1 c.c. sample of air at the absolute temperature T0 at sea level and another 1 c.c. sample of air at a height where the pressure is the one-third atmosphere. The absolute temperature T of the sample at that height is :

  • Equal to 3/T0

  • Equal to T0/3

  • Equal to T0

  • Cannot be determined in terms of T0 from the above data

To double the volume of a given mass of an ideal gas at 27°C keeping the pressure constant, one must raise the temperature in degree centigrade to

  • 54°                                   

  •  270°

  • 327°                                 

  • 600°

Which of the following statements about kinetic theory of gases is wrong

  • The molecules of a gas are in continuous random motion

  • The molecules continuously undergo inelastic collisions

  • The molecules do not interact with each other except during collisions

  • The collisions amongst the molecules are of short duration

If a Vander-Waal's gas expands freely, then final temperature is

  • Less than the initial temperature

  • Equal to the initial temperature

  • More than the initial temperature

  • Less or more than the initial temperature depending on the nature of the gas

In Vander Waal's equation P+aV2V-b=RT, the dimensions of a are

  •  M1L5T-2                    

  •  M0L2T-3 

  •  M1L3T-2                    

  • M1L1T-2

Which law states that effect of pressure is same for all portion

  • Pascal’s law                               

  • Gay-lussac’s law

  • Dalton’s law                             

  • None of these

The equation for an ideal gas is PV = RT, where V represents the volume of

  • 1 gm gas                         

  • Any mass of the gas

  • One gm mol gas               

  • One litre gas

Under which of the following conditions is the law PV = RT obeyed most closely by a real gas

  • High pressure and high temperature

  • Low pressure and low temperature

  • Low pressure and high temperature

  • High pressure and low temperature

The gas equation PVT= constant is true for a constant mass of an ideal gas undergoing

  • Isothermal change                           

  • Adiabatic change

  • Isobaric change                               

  • Any type of change

That gas cannot be liquified :

  • Which obeys Vander Waal's equation

  • Which obeys gas equation at every temperature and pressure

  • The molecules of which are having potential energy

  • Which is a inert gas

At STP the mass of one litre of air is 1.293 gm. The value of the specific gas constant will be :

  • 0.29 J/K-gm                       

  • 4.2 J/K-gm

  • 8.3 J/K-gm                         

  • 3. 16.5 J/K-gm

The pressure P, volume V and temperature T of gas in the jar A and the other gas in the jar B at pressure 2P, volume V/4 and temperature 2T, then the ratio of the number of molecules in the jar A and B will be :

  •   1 : 1                             

  •   1 : 2

  •   2 : 1                             

  •   4 : 1

A balloon contains 500 m3 of helium at 27°C and 1 atmosphere pressure. The volume of the helium at – 3°C temperature and 0.5 atmosphere pressure will be :

  •   500 m3                                 

  •   700 m3

  •   900 m3                                 

  •  1000 m3

A vessel contains 1 mole of O2 gas (molar mass 32) at a temperature T. The pressure of the gas is P. An identical vessel containing one mole of He gas (molar mass 4) at temperature 2T has a pressure of

  • P/8                                   

  • P

  • 2P                                   

  • 8P

A given mass of a gas is allowed to expand freely until its volume becomes double. If Cb and Ca are the velocities of sound in this gas before and after expansion respectively, then Ca is equal to :

  •  2Cb                                 

  •  2Cb

  •  Cb                                   

  •  12Cb

One litre of Helium gas at a pressure 76 cm of Hg and temperature 27°C is heated till its pressure and volume are doubled. The final temperature attained by the gas is :

  •   927°C                                 

  •   900°C

  •   627°C                                 

  •   327°C

The molecular weight of a gas is 44. The volume occupied by 2.2 g of this gas at 0°C and 2 atm pressure will be-

  •   0.56 litre                           

  •   1.2 litres

  •   2.4 litres                           

  •   5.6 litres

A gas at 27°C temperature and 30 atmospheric pressure is allowed to expand to the atmospheric pressure. If the volume becomes 10 times its initial volume, then the final temperature becomes

  •   100°C                             

  •   173°C

  •   273°C                             

  •   – 173°C

In the relation n=PVRT, n=

  •   Number of molecules                             

  •   Atomic number

  •   Mass number                                         

  •   Number of moles

The equation of state corresponding to 8 g of O2 is :

  •   PV = 8RT                           

  •   PV = RT/4

  •   PV = RT                             

  •   PV = RT/2

Three containers of the same volume contain three different gases. The masses of the molecules are m1, m2 and m3 and the number of molecules in their respective containers are N1, N2 and N3 . The gas pressure in the containers are P1, P2 and P3 respectively. All the gases are now mixed and put in one of the containers. The pressure P of the mixture will be :

  •  P<P1+P2+P3                               

  •  P=P1+P2+P33

  •  P=P1+P2+P3                                 

  •  P>P1+P2+P3

At a given volume and temperature, the pressure of a gas :

  • Varies inversely as its mass

  • Varies inversely as the square of its mass

  • Varies linearly as its mass

  • Is independent of its mass

The rate of diffusion is :

  • Faster in solids than in liquids and gases

  • Faster in liquids than in solids and gases

  • Equal to solids, liquids, and gases

  • Faster in gases than in liquids and solids

At the top of a mountain a thermometer reads 7°C and a barometer reads 70 cm of Hg. At the bottom of the mountain these read 27°C and 76 cm of Hg respectively. Comparison of density of air at the top with that of bottom is

   

  •   75/76                             

  •   70/76

  •   76/75                             

  •   76/70

Two thermally insulated vessels 1 and 2 are filled with air at temperatures T1, T2, volume V1, V2 and pressure P1, P2 respectively. If the valve joining the two vessels is opened, the temperature inside the vessel at equilibrium will be

  •  T1+T2                               

  •  T1+T2/2

  •  T1T2P1V1+P2V2P1V1T2+P2V2T1                 

  •  T1T2P1V1+P2V2P1V1T2+P2V2T2

For matter to exist simultaneously in gas and liquid phases :

  • The temperature must be 0 K.

  • The temperature must be less than 0°C.

  • The temperature must be less than the critical temperature.

  • The temperature must be less than the reduced temperature.

The value of critical temperature in terms of Vander Waal’s constant a and b is

  •  Tc=8 a27 Rb                           

  •  Tc=a2 Rb

  •  Tc=827 Rb                             

  •  Tc=27 a8 Rb

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