Explanation
Hint: Using ideal gas equation rearrange the given equation and then differentiate.
Where P - Pressure, T - Temperature
Consider the ideal gas equation and substitute the value of pressure in the given equation.
Explanation of Correct Option:
Step 1: Consider the formulas mentioned
Expression of is given by,
Volume expansion can be expressed as:
V={{V}_{0}}(1+\gamma t)
Where V is the volume at temperature t
{{V}_{0}} Is the volume at temperature t = 0
\gamma is the coefficient of volume expansion and t is temperature.
Step 2: Consider the ideal gas expansion
Ideal gas is expansion is given as
P{{T}^{2}}=\text{constant}….. (1)
Step 3: Consider the ideal gas equation,
PV=nRT
\dfrac{PV}{T}=\text{constant}
P=\dfrac{\text{constant}\times T}{V}......\left( 2 \right)
Coefficient of volume expansion can be calculated by the values of gas denoted by \gamma
Step 4: Coefficient of volume expansion of gas is given by
V={{V}_{0}}(1+\gamma t).......\left( 3 \right)
Substitute the equation (2) in equation (1),
\dfrac{\text{constant}\times T}{V}\times {{T}^{2}}=\text{constant}
\dfrac{{{T}^{3}}}{V}=\text{constant=k}
V=\dfrac{1}{k}{{T}^{3}}={{k}^{1}}{{T}^{3}}.....\left( 4 \right)\text{ }\left( \because {{k}^{1}}=\dfrac{1}{k} \right)
Step 5: Differentiate equation (3) with respect to t
On differentiating with respect to t
\dfrac{dV}{dt}={{V}_{0}}(\gamma .1)
\dfrac{dV}{dt}={{V}_{0}}\gamma .......\left( 5 \right)
Dedifferentiate equation (4) with respect to T,
\dfrac{dV}{dT}={{k}^{1}}3{{T}^{2}}
Put values of {{k}^{1}} from equation (4)
\dfrac{dV}{dT}=\dfrac{V}{{{T}^{3}}}\times 3{{T}^{2}}
\dfrac{dV}{dT}=\dfrac{3V}{T}
\therefore \dfrac{dV}{V}=3\dfrac{dT}{T}
dV=\dfrac{3}{T}VdT......(6)
Volume expansion is given by,
\Delta V=\gamma {{V}_{0}}\Delta T......\left( 7 \right)
Step 6: Compare the equations (6) and (7)
dV=\Delta V
\dfrac{3}{T}VdT = \gamma {{V}_{0}}\Delta T......\left( 7 \right)
\gamma =\dfrac{3}{T}
Hence the coefficient of volume expansion of the gas is \gamma =\dfrac{3}{T}.
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