Explanation
T=−αV3+βV2PVR=−αV2+βV2P=RV(−αV+β)
For maximum pressure
dPdV=0⇒−2αV+β=0⇒V=β2αP=R[−α(β2α)2+β2α×β]P=R[−β24α+β22α]P=Rβ24α
For a given volume, among all the three objects, the sphere has the least surface area and the cube will have the maximum surface area. This is also due to the fact that the volume and mass of all three are the same.
According to Heat theory, the rate of loss of heat is proportional to the surface area of the object. Hence, the rate of cooling will be slowest for the sphere and fastest for the cube.
Thus the correct option is A.
Let V is the volume of the vessel.
Now, let p1 and p2 be the partial pressure, then using gas law:
p1V=m1M1RT
p2V=m2M2RT, p0=p1+p2
p0=(m1M1+m2M2)RTV
V=(m1M1+m2M2)RTp0
∵ρmix=(m1+m2)V
ρmix=(m1+m2)M1M2(m1M2+m2M1)×p0RT
Substituting values,
ρmix=(7+11)×28×44×10−3(7×44+11×28))×1058.3×300
=1.446 per litre
Option A is correct.
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