Explanation
The most abundant element in the earths crust by weight is oxygen.
When calcium nitride reacts with di nitrogen it forms ammonia and calcium hydroxide.
Ca3N2+6H2O→3Ca(OH)2+2NH3.
Preparation of Ammonia:
N2+3H2→2NH3
At high pressure about 200-250 atm, and a moderate temperature of 750K, the reaction takes place. Removal of ammonia is done by liquefaction, In the process, iron is used as a catalyst and molybdenum as a promoter.
When CaNH reacts with hot water it forms NH3,Ca(OH)2.
CaNH+2H2O→Ca(OH)2+NH3.
Manganese dioxide(MnO2) is heated with concentrated HCl to form Cl2
MnO2+4HCl→MnCl2+Cl2+2H2O
HCl in action with potassium permanganate gives C2
2KMnO4+16HCl→2KCl+2MnCl2+8H2O+5Cl2.
Hence option A and C is correct.
The structure of white phosphorus is tetrahedral.Phosphorus or s tetraphosphorus (P_4) exists as molecules made up of four atoms in a tetrahedral structure. The molecule is described as consisting of six single P–P bonds.
Hence option C is correct.
NH_4NO_2 will not give ammonia on heating.It gives NO_2H_2O
NH_4NO_2(s)\rightarrow N_2(g) + 2H_2O(g)
Oxygen florides forms HF,O_2 on hydrolysis.
OF_2 + H_2O\rightarrow O_2 + 2 HF
2O_2F_2 + 2H2O\rightarrow O_2 + 4HF
so oxygen florides do not form forms hypohalous acids.
So the given statement oxygen florides forms oxoacids is wrong.
N-N sigma bond (single bod) is weaker than P-P sigma bond (single bond) due to the small bond length between the nitrogen atoms. The lone pair of electrons of both the atoms nitrogen repel each other making the single bon between N-N weaker than P-P sigma bond.In P-P bond the repulsion between sigma bond and lone pair electrons is less as the size of phosphorous is large.
So statement A is wrong.
Hence option A is correct.
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