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CBSE Questions for Class 12 Engineering Chemistry Alcohols,Phenols And Ethers Quiz 8 - MCQExams.com

Ethene reacts with Y to produce ethanol.
ethene+Yethanol
What is Y?
  • Hydrogen
  • Oxygen
  • Steam
  • Yeast
But-2-ene, 1,4-diol is converted in two steps through an intermediate X into oxobutanedioic acid.
HOCH2CH=CHCH2OHbut2ene1,4diolstep1xstep2hot,acidifiedKMnO4HO2CCOCH2CO2Hoxobutanedioicacid
What could be the reagent for step 1 and what is the intermediate X?

reagent for step 1X
Acold, acidified KMnO4HOCH2CH2CH(OH)CH3OH
Bhot, acidified K2Cr2O7HO2CCH=CHCO2H
Csteam and concentrated H2SO4HOCH2CH(OH)CH2CH2OH
Dwarm, acidified K2Cr2O7OHCCH(OH)CH2CHO

  • A
  • B
  • C
  • D
What is the major product formed when compound Q is warmed with excess HBr?
1649118_055f3cdde26d438fa0d85ce10f92f973.jpg
An olefin may be converted into alcohol by:
  • B2H6 and H2O2
  • LiAlH4
  • Acidic KMnO4
  • HOCl
Ether which is liquid at room temperature is:
  • C2H5OCH3
  • CH3OCH3
  • C2H5OC2H5
  • None of these
Heating together sodium ethoxide and ethyl chloride will give: 
  • ether
  • ethyl alcohol
  • acetaldehyde
  • acetic acid
State whether the following statement is True or False.
C2H5OH can accept a proton to give protonated, C2H5+OH2, i.e., it can act as an acid.
  • True
  • False
The reaction, (CH3)3COHH2SO4Heat(CH3)2C=CH2, is an example of
  • Sulphonation
  • Decomposition
  • Dehydration
  • Alkylation
State whether the following statement is True or False.
Ethylene can be used for the synthesis of ethyl alcohol.
  • True
  • False
The boiling point of thioether are ________ than those of ethers.
  • higher
  • lower
  • equal
  • nearly same
An equimolar quantities of ethanol and propanol are heated with conc. H2SO4. The products formed is/are: 
  • C2H5OC2H5
  • C3H7OC3H7
  • C2H5OC3H7
  • all of these
The compound(s) which will give propylene on dehydration with conc.H2SO4 at 440\ K is/ are
  • Isobytyl alcohol
  • n-propyl alcohol
  • Isopropyl alcohol
  • n-butyl alcohol
Methyl phenyl ether can be obtained by reacting:
  • phenolate ions and methyl iodide
  • methoxide ion and bromobenzene
  • methanol and phenol
  • bromobenzene and methyl bromide
img, on reaction with CH_3OH in presence of H^+ gives :
1722365_c4100cbf705545dcb92f12264ef71499.JPG
CO+H_2\overset{X(catalyst)}{\underset{300^oC/300 atm}{\rightarrow}}CH_3OH, the catalyst X is?
  • Fe
  • Cr_2O_3/ZnO
  • V_2O_5
  • Al_2O_3
The boiling point of ethanol is higher as compared to the boiling point of diethyl ether though both have the same molecular formula. This is due to:
  • Resonance
  • H-bonding
  • R-group
  • Covalent bonding
Wood spirit if known as?
  • Ethanol
  • Methanol
  • Acetone
  • Benzene
State, whether the following statements are True or False:
Ethers are not affected by atmosphere. 
  • True
  • False
Reaction, \underset{Water gas}{\underbrace{CO+H_2}}+H_2\overset{673K, 300 atm.}{\underset{Cr_2O_3-ZnO}{\rightarrow}}? may be used for manufacture of:
  • HCHO
  • CH_3COOH
  • HCOOH
  • CH_3OH
State, whether the following statements are True or False:
C_2HSOC_2H5 is a linear molecule having zero dipole moment.
  • True
  • False
The only alcohol that can be prepared by the indirect hydration of alkene is:
  • Methyl alcohol
  • Ethyl alcohol
  • Propyl alcohol
  • Isobutyl alcohol
Acid catalysed hydration of alkenes except ethene leads to the formation of.
  • Primary alcohol
  • Secondary or tertiary alcohol
  • Mixture of primary and secondary alcohols
  • Mixture of secondary and tertiary alcohols
Among the following compounds which can be dehydrated very easily?
  • CH_3CH_2CH_2CH_2CH_2OH
An organic compound 'X' on treatment with acidified K_2Cr_2O_7 gives a compound 'Y' which reacts with I_2 and Na_2CO_3 to form tri-iodomethane. The compound 'X' is?
  • CH_3OH
  • CH_3COCH_3
  • CH_3CHO
  • CH_3CHOHCH_3
Boiling point of C_2H_5OH is higher as compared to C_2H_5SH on account of:
  • Association
  • Dissociation
  • Low molecular mass
  • None of these
During dehydration of alcohols to alkenes by heating with conc. H_2SO_4, the initiation step is:
  • Elimination of water
  • Formation of an ester
  • Formation of carbocation
  • Protonation of alcohol molecule
Which of the following is soluble in water?
  • CS_2
  • C_2H_5OH
  • CCl_4
  • CHCl_3
The compound which gives the most stable carbonium ion on dehydration is?
  • (CH_3)_2CH-CH_2OH
  • CH_3CH_2CH_2OH
  • CH_3-CH(OH)-CH_2CH_3
  • (CH_3)_3C-OH
The correct order of boiling points for primary (1^o), secondary (2^o) and tertiary alcohol (3^o) is:
  • 1^o > 2^o > 3^o
  • 3^o > 2^o > 1^o
  • 2^o > 1^o > 3^o
  • 2^o > 3^o > 1^o
Isopropyl benzene on air oxidation in the presence of dilute acid gives
  • C_{6}H_{5}COOH
  • C_{6}H_{5}COCH_{3}
  • C_{6}H_{5}CHO
  • C_{6}H_{5}OH
Mark the correct statement:
  • Water gas is used in the manufacture of methyl alcohol.
  • Water gas has the highest calorific value.
  • Water gas burns with luminuous flame.
  • The production of water gas is exothermic process
The alcohols which gives the most stable carbonium ion on dehydration is?
  • (CH_3)_2CHCH_2OH
  • (CH_3)_3C-OH
  • CH_3CH_2CH_2CH_2OH
Which of the following alcohols will dehydrate most rapidly when treated with conc. H_2SO_4?
  • CH_3-CH_2-CH_2-CH_2-OH
Butane-2-ol is:
  • Primary alcohol
  • Secondary alcohol
  • Tertiary alcohol
  • Aldehyde
Cresols are 
  • Hydroxy toluenes
  • Dihydric phenols
  • Trihydric phenols
  • Trihydric alcohols
IUPAC name of tertiary butyl alcohol is
  • Butan-1-ol
  • Butan-2-ol
  • 2-methyl propan-1-ol
  • 2-methyl propan-2-ol
Wood spirit is known as 
  • Methanol
  • Ethanol
  • Acetone
  • Benzene
The IUPAC name of picric acid is
  • 2,4,6-trinitrophenol
  • 2,4,6-trinitrobenzoic acid
  • 4-nitrophenol
  • None of these
The IUPAC name of compound \begin{matrix} \quad \quad O{ CH }_{ 3 } \\ | \\ { CH }_{ 3 }-{ CH }_{ 2 }-CH-{ CH }_{ 2 }-OH \end{matrix} is
  • 2-methoxy-1-butanol
  • 3-methoxy-1-butanol
  • 2-methoxy-1-butanol
  • 1,2-methoxy-butanol
The structural formula of cyclohexanol is
3-pentanol is a:
  • Primary alcohol
  • Secondary alcohol
  • Tertiary alcohol
  • None of these
General formula of primary alcohol is 
  • >CHOH
  • -CH_2OH
Which of the following is phenolic 
  • Phthalic acid
  • Phosphoric acid
  • Picric acid
  • Phenylacetic acid
What is obtained when chlorine is passed in boiling toluene and product is hydrolysed 
  • o-Cresol
  • p-Cresol
  • 2, 4-Dihydroxytoluene
  • Benzyl alcohol
During dehydration of alcohols to alkenes by heating with conc. H_2SO_4 the initiation step is
  • Protonation of alcohol molecule
  • Formation of carbocation
  • Elimination of water
  • Formation of an ester
Boiling point of alcohol is comparatively higher than that corresponding alkane due to:
  • Intermolecular hydrogen bonding
  • Intramolecular hydrogen bonding
  • Volatile nature
  • None of these
Wine (alcoholic beverages) contains:
  • CH_3OH
  • Glycerol
  • C_2H_5OH
  • 2-propanol
The reaction of C_2H_5OH with H_2SO_4 does not give  
  • Ethylene
  • Diethyl ether
  • Acetylene
  • Ethyl hydrogen sulphate
Propan-1-ol can be prepared from propene by alcohol 
  • H_2O/H_2SO_4
  • Hg(OAc)_2/H_2 O followed by NaBH_4
  • B_2H_6 followed by H_2O_2
  • CH_3CO_2H/H_2SO_4
Acetyl bromide reacts with excess of CH_3MgI following by treatment with a saturated of NH_4Cl gives 
  • 2-methyl-2-propanol
  • Acetamide
  • Acetone
  • Acetyl iodide
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