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CBSE Questions for Class 12 Engineering Chemistry Amines Quiz 5 - MCQExams.com

Among the following compounds, the most basic compounds is:
Among the isomeric amines select the one with the lowest boiling point.
In the given pair identify most acidic compound in (A) and (B). Most basic in (C) and (D).
988222_c711038fbc724bb39b750e8dc368746d.PNG
  • A(I), B(II), C(I), D(II)
  • A(II), B(I), C(I), D(II)
  • A(II), B(II), C(II), D(II)
  • A(I), B(II), C(I), D(I)
In the given pair of compounds, in which pair second compound has higher boiling point than first compound?
  • HOCH2CH2OH and CH3CH2OH
In which of the following compound the methylenic hydrogens are the most acidic?
  • CH3COCH2CH3
  • CH3CH2COOC2H5
  • CH3CH2CH(COOC2H5)2
  • CH3COCH2CN
Correct order of basic strength of given amines is:
  • Me2NM2o>MeNH21o>Me3N>NH33o (Protic solvent)
  • Et2NH2o>Et3H3o>EtNH21o>NH3 (Protic solvent)
  • Me3N>Me2NH>MeNH2>NH3 (Gas phase)
  • All are correct
p-aminophenol reacts with one equivalent of acetyl chloride in the presence of pyridine to give mainly.
The amino ketone shown given undergoes a spontaneous cyclization on standing. What is the major product of this intramolecular reaction?
992060_60789c96e0df44efaebea704b76fbb97.png
Which amine yield N-nitroso amine after treatment with nitrous acid (NaNO_2, HCl)?
Which of the following arylamines will not form a diazonium salt on reaction with sodium nitrite in hydrochloric acid?
  • m-Ethylaniline
  • p-Aminoacetophenone
  • 4-Chloro-2-nitroaniline
  • N-Ethyl-2-methyaniline
Which of the following diazonium salt is relatively stable of 0-5^oC?
  • CH_3CH_2N\equiv N\}^{\oplus}Cl^-
  • CH_3-C(CH_3)_2-N\equiv N\}^{\oplus} Cl^-
  • CH_3-N\equiv N\}^{\oplus}Cl^-
  • (CH_3)_3C-N\equiv N\}^{\oplus}Cl^-
Which of following is an example of Pinacol-Diazotization?
For the diazonium ions the order of reactivity towards diazo-coupling with phenol in the presence of dilute NaOH is:
996078_65c2218293bb418c97b31de90e407eb9.png
  • I < IV < II < III
  • I < III < IV < II
  • III < I < II < IV
  • III < I < IV < II
Diazotization of n-Bu-NH_2 with NaNO_2/HCl gives _________ isomeric butene.
  • 2
  • 3
  • 4
  • 5
Compare the boiling point of the following two amines.
1057717_8f380f3cee364965bd8caefb18835d30.png
  • Boiling point of I > II
  • Boiling point of II > I
  • Both should have equal boiling points
  • It can't be predicted

Which is the strongest base?

  • Pyrole
  • Aniline
  • Pyridine
Which of the following statement is not true?
  • CH_3CH_2NH_2 is ethanamine
  • CH_2CH_2OH is an ether
  • Cyclopentane and 2-pentene have a molecular formula of C_5H_{10}
  • Alkenes an alkynes are unsaturated
Which of the following diazonium salt is relatively stable at 0-{ 5^0 }^{ }C?
  • { CH }_{ 3 }-N\equiv N{ \} }^{ \oplus }C{ l }^{ - }
  • { \left( { CH }_{ 3 } \right) }_{ 2 }CH-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }
  • { C }_{ 6 }{ H }_{ 5 }-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }
  • { \left( { CH }_{ 3 } \right) }_{ 3 }C-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }
What product is formed on heating two molecules of urea?
  • Uric Acid
  • Biuret
  • Nitrogen
  • Carbon dioxide
The most basic among the following is:
  • { H }_{ 3 }C-{ NH }_{ 2 }
  • { CH }_{ 3 }-{ CH }_{ 2 }-NH_2
  • { H }_{ 3 }C-NH-{ CH }_{ 3 }
  • { H }_{ 3 }C-{ CH }(CH_3)-NH_2
H-COOH > Ph-COOH > CH_{3}-COOH (acidic nature)CF_{3}-COOH > CCI_{3}-COOH > CH_{2}-COOH (Acidic nature)N- methylmethanamine > methanamine > N, N- dimethylmethanamine (Basic nature in aqueous phase)N,N- diethlethanamine > N-ethylethanamine > Ethanamine (Basic nature in aqueous phase)Then the correct order is:
  • i,ii,iv
  • ii,iii,iv
  • i,ii,iii
  • i,ii,iii,iv
What is the major organic product of the following reaction?
{ CH }_{ 3 }{ CH }_{ 2 }{ NHCH }_{ 2 }{ CH }_{ 3 }\longrightarrow ?
1070105_d1918afaa25e4590a5269c82f867241e.png
Which is most basic in aqueous solution?
  • { CH }_{ 3 }-{ NH }_{ 2 }
  • { (CH }_{ 3 }{ ) }_{ 2 }{ NH }
  • { (CH }_{ 3 }{ ) }_{ 3 }N
  • ph-{ NH }_{ 2 }
Which of the following is most basic ?
Select the basic strength order of following molecules.
1070928_0e0ec00c5905430e881f78bd70858db0.png
  • III > II > I
  • II > III > I
  • I > III > II
  • III > I > II
Which of the following conditions is most suitable for the above reaction?

1071115_d828da0bd83243ebb24258fc06195400.png
  • strongly acidic
  • strongly alkaline
  • Slightly alkaine
  • neutral
Which of the following will accept H^{+} from NH_{4}^{+} ion?
  • CH_{3}-CH_{2}-NH_{2}
Decreasing order of basicity of the three isomers of nitro aniline is:
  • p-nitroaniline> o-nitroaniline> m-nitroaniline
  • p-nitroaniline> m-nitroaniline> o-nitroaniline
  • m-nitroaniline> p-nitroaniline> o-nitroaniline
  • m-nitroaniline> o-nitroaniline> p-nitroaniline
The order of basic strength of the given basic nitrogen atoms is :
1071049_3db7e6ce80674e8c984144ff30a882da.png
  • III > II > I > IV
  • III > I > II > IV
  • I > III > II > IV
  • II > III > I > IV
The correct sequence regarding base strength of aliphatic amines in aqueous solution is:
  • {R}_{3}N> {R}_{2}NH> R{NH}_{2}> {NH}_{3}
  • {R}_{2}NH> R{NH}_{2}> {R}_{3}N> {NH}_{3}
  • {R}_{2}NH> {R}_{3}N> R{NH}_{2}> {NH}_{3}
  • R{NH}_{2}> {R}_{2}NH> {R}_{3}N> {NH}_{3}
The increasing order of basicity of the given compounds is:
  • (b)< (a)< (c)< (d)
  • (b)< (a)< (d)< (c)
  • (d)< (b)< (a)< (c)
  • (a)< (b)< (c)< (d)
The correct order of basic strength of the compounds?
1087633_d79c57c1fa2b43c2b1c8a980fc3a9b5e.png
  • I > II > III
  • II > I > III
  • III > II > I
  • II > III > I
By heating ammonium chloride with two equivalents of formaldehyde it forms:
  • dimethylamine
  • ethylamine
  • methylamine
  • ammonium formate
Which of the following Statements is/are correct?
  • (SiH_3)_3N is weaker base than (CH_3)_3N.
  • Amongst Cl-Cl, N-F,C-F And O-F bond is most polar
  • OF_2 has higher dipole moment than H_2O
  • An alchohol is less volatile than other having same molecular formula on account of intermolecular hydrogen bonding
{C}_{4}{H}_{11}N(X)+H{NO}_{2} \rightarrow {C}_{4}{H}_{10}O({3}^{o} alcohol) 
Hence, X will not give:
  • carbylamine reaction
  • hoffmann mustard oil reaction
  • diazorium salt (as the intermediate)
  • hofmann's bromamide reaction
sp^3-hybridised nitrogen is present in:
  • CH_2 = CH - \overset{\oplus}{N}H_3
The product B of the following sequence, would be?
1086349_2201fcbc69204b23b5fc6072a75a38d0.JPG
  • I
  • II
  • III
  • IV and V
The correct order of increasing basic nature for the bases NH_3,CH_3NH_2 and (CH_3)_2NH is?
  • (CH_3)_2NH < NH_3 < CH_3NH_2
  • NH_3 < CH_3 NH_2 <(CH3)_2NH
  • CH_3NH_2 <(CH_3)_2NH < NH_3
  • CH_3NH_2 < NH_3 < (CH_3)_2NH
The end product (Z) of the following reaction is?
1096491_ac867f00062c495ea22db5a8add459a8.PNG
  • A cyanide
  • A carboxylic acis
  • An amine
  • An arene
Find product in the following reaction is Y. What is Y?
1100535_fd88450c89f34990b372bfda600d479c.png
  • benzamide
  • benzophenone
  • benzoic acid
  • benzaldehyde
CH_3Cl \xrightarrow{AgCN} A (major) \xrightarrow{H-2O^+} C + D here 'C' is formic acid 'D is:'
  • 2^o amine
  • Carboxylic acid
  • Alkyl Cyanide
  • 1^o amine
Reductive amination of A forms:
1097811_af3fe33a33654685b77e78a48b8883c4.png
The correct order of boiling points of the following amines { C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 },\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH,{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 } is :
  • { C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }>\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }
  • \left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }
  • { C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2} >\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }
  • \left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }
Which of the following is the least basic?
  • All are equally basic
In the above reaction sequence (D) is?
1107986_5b367070c49f40c49a152a1f1737a17b.png
Suitable explanation for the order of basic character, (CH_{3})_{3}N < (CH_{3})_{2}NH, is:
  • steric hindrance by bulky methyl group
  • higher volatility of 3^{\circ} amine
  • stability of conjugate acid due to solvation
  • all of these
With which one of the following substrate do diazonium salt reacts to form a colourful compound?
In the reaction
Me_{3}N \xrightarrow{BrCN} A \xrightarrow[ii)\Delta]{i)H_{2}O}  B
B is
  • MeNH_{2}
  • Me_{3}NO
  • Me_{2}NH
  • Me_{2}NCOOH
The reagents/conditions K, L and M are respectively:
1109164_496a758a6c134969a39e7eb8aaf41dad.PNG
  • Ba(OH)_{2}, KCN and CHCl_{3} / NaOH heat, H_{3}O^{+}
  • H_{2}O (boil), CO_{2} / KOH and Ac_{2}O - AcONa, heat
  • Steam ; CHCl_{3} / NaOH, heat, H_{3}O^{+} and AC_{2}O - AcONa, heat
  • Cu_{2}Cl_{2} / HCl, NaOH / high P and CO_{2}|NaOH, heat
Which of the following compounds is an imine?
0:0:1


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