CBSE Questions for Class 12 Engineering Chemistry Amines Quiz 5 - MCQExams.com

Among the following compounds, the most basic compounds is:
Among the isomeric amines select the one with the lowest boiling point.
In the given pair identify most acidic compound in $$(A)$$ and $$(B)$$. Most basic in $$(C)$$ and $$(D)$$.
988222_c711038fbc724bb39b750e8dc368746d.PNG
  • $$A - (I),\ B - (II),\ C - (I),\ D - (II)$$
  • $$A - (II),\ B - (I),\ C - (I),\ D - (II)$$
  • $$A - (II),\ B - (II),\ C - (II),\ D - (II)$$
  • $$A - (I),\ B - (II),\ C - (I),\ D - (I)$$
In the given pair of compounds, in which pair second compound has higher boiling point than first compound?
  • $$HO - CH_2 - CH_2 - OH$$ and $$CH_3 - CH_2 - OH$$
In which of the following compound the methylenic hydrogens are the most acidic?
  • $$CH_3COCH_2CH_3$$
  • $$CH_3CH_2COOC_2H_5$$
  • $$CH_3CH_2CH(COOC_2H_5)_2$$
  • $$CH_3COCH_2CN$$
Correct order of basic strength of given amines is:
  • $$\underset{2^o}{Me_2NM} > \underset{1^o}{MeNH_2} > \underset{3^o}{Me_3N > NH_3}$$ (Protic solvent)
  • $$\underset{2^o}{Et_2NH} > \underset{3^o}{Et_3H} > \underset{1^o}{EtNH_2} > NH_3$$ (Protic solvent)
  • $$Me_3N > Me_2NH > Me - NH_2 > NH_3$$ (Gas phase)
  • All are correct
p-aminophenol reacts with one equivalent of acetyl chloride in the presence of pyridine to give mainly.
The amino ketone shown given undergoes a spontaneous cyclization on standing. What is the major product of this intramolecular reaction?
992060_60789c96e0df44efaebea704b76fbb97.png
Which amine yield $$N-$$nitroso amine after treatment with nitrous acid $$(NaNO_2, HCl)?$$
Which of the following arylamines will not form a diazonium salt on reaction with sodium nitrite in hydrochloric acid?
  • m-Ethylaniline
  • p-Aminoacetophenone
  • $$4$$-Chloro-$$2$$-nitroaniline
  • N-Ethyl-$$2$$-methyaniline
Which of the following diazonium salt is relatively stable of $$0-5^o$$C?
  • $$CH_3CH_2N\equiv N\}^{\oplus}Cl^-$$
  • $$CH_3-C(CH_3)_2-N\equiv N\}^{\oplus} Cl^-$$
  • $$CH_3-N\equiv N\}^{\oplus}Cl^-$$
  • $$(CH_3)_3C-N\equiv N\}^{\oplus}Cl^-$$
Which of following is an example of Pinacol-Diazotization?
For the diazonium ions the order of reactivity towards diazo-coupling with phenol in the presence of dilute $$NaOH$$ is:
996078_65c2218293bb418c97b31de90e407eb9.png
  • I $$<$$ IV $$<$$ II $$<$$ III
  • I $$<$$ III $$<$$ IV $$<$$ II
  • III $$<$$ I $$<$$ II $$<$$ IV
  • III $$<$$ I $$<$$ IV $$<$$ II
Diazotization of n-Bu-$$NH_2$$ with $$NaNO_2/HCl$$ gives _________ isomeric butene.
  • $$2$$
  • $$3$$
  • $$4$$
  • $$5$$
Compare the boiling point of the following two amines.
1057717_8f380f3cee364965bd8caefb18835d30.png
  • Boiling point of $$I > II$$
  • Boiling point of $$II > I$$
  • Both should have equal boiling points
  • It can't be predicted

Which is the strongest base?

  • Pyrole
  • Aniline
  • Pyridine
Which of the following statement is not true?
  • $$CH_3CH_2NH_2$$ is ethanamine
  • $$CH_2CH_2OH$$ is an ether
  • Cyclopentane and 2-pentene have a molecular formula of $$C_5H_{10}$$
  • Alkenes an alkynes are unsaturated
Which of the following diazonium salt is relatively stable at $$0-{ 5^0 }^{ }C$$?
  • $${ CH }_{ 3 }-N\equiv N{ \} }^{ \oplus }C{ l }^{ - }$$
  • $${ \left( { CH }_{ 3 } \right) }_{ 2 }CH-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }$$
  • $${ C }_{ 6 }{ H }_{ 5 }-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }$$
  • $${ \left( { CH }_{ 3 } \right) }_{ 3 }C-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }$$
What product is formed on heating two molecules of urea?
  • Uric Acid
  • Biuret
  • Nitrogen
  • Carbon dioxide
The most basic among the following is:
  • $${ H }_{ 3 }C-{ NH }_{ 2 }$$
  • $${ CH }_{ 3 }-{ CH }_{ 2 }-NH_2$$
  • $${ H }_{ 3 }C-NH-{ CH }_{ 3 }$$
  • $${ H }_{ 3 }C-{ CH }(CH_3)-NH_2$$
$$H-COOH > Ph-COOH > CH_{3}-COOH$$ (acidic nature)$$CF_{3}-COOH > CCI_{3}-COOH > CH_{2}-COOH$$ (Acidic nature)$$N- methylmethanamine > methanamine > N, N- dimethylmethanamine $$ (Basic nature in aqueous phase)$$N,N- diethlethanamine > N-ethylethanamine > Ethanamine $$ (Basic nature in aqueous phase)Then the correct order is:
  • $$i,ii,iv$$
  • $$ii,iii,iv$$
  • $$i,ii,iii$$
  • $$i,ii,iii,iv$$
What is the major organic product of the following reaction?
$$ { CH }_{ 3 }{ CH }_{ 2 }{ NHCH }_{ 2 }{ CH }_{ 3 }\longrightarrow $$?
1070105_d1918afaa25e4590a5269c82f867241e.png
Which is most basic in aqueous solution?
  • $${ CH }_{ 3 }-{ NH }_{ 2 }$$
  • $${ (CH }_{ 3 }{ ) }_{ 2 }{ NH }$$
  • $${ (CH }_{ 3 }{ ) }_{ 3 }N$$
  • $$ph-{ NH }_{ 2 }$$
Which of the following is most basic ?
Select the basic strength order of following molecules.
1070928_0e0ec00c5905430e881f78bd70858db0.png
  • $$III > II > I$$
  • $$II > III > I$$
  • $$I > III > II$$
  • $$III > I > II$$
Which of the following conditions is most suitable for the above reaction?

1071115_d828da0bd83243ebb24258fc06195400.png
  • strongly acidic
  • strongly alkaline
  • Slightly alkaine
  • neutral
Which of the following will accept $$H^{+}$$ from $$NH_{4}^{+}$$ ion?
  • $$CH_{3}-CH_{2}-NH_{2}$$
Decreasing order of basicity of the three isomers of nitro aniline is:
  • $$p-nitroaniline> o-nitroaniline> m-nitroaniline$$
  • $$p-nitroaniline> m-nitroaniline> o-nitroaniline$$
  • $$m-nitroaniline> p-nitroaniline> o-nitroaniline$$
  • $$m-nitroaniline> o-nitroaniline> p-nitroaniline$$
The order of basic strength of the given basic nitrogen atoms is :
1071049_3db7e6ce80674e8c984144ff30a882da.png
  • $$III > II > I > IV$$
  • $$III > I > II > IV$$
  • $$I > III > II > IV$$
  • $$II > III > I > IV$$
The correct sequence regarding base strength of aliphatic amines in aqueous solution is:
  • $${R}_{3}N> {R}_{2}NH> R{NH}_{2}> {NH}_{3}$$
  • $${R}_{2}NH> R{NH}_{2}> {R}_{3}N> {NH}_{3}$$
  • $${R}_{2}NH> {R}_{3}N> R{NH}_{2}> {NH}_{3}$$
  • $$R{NH}_{2}> {R}_{2}NH> {R}_{3}N> {NH}_{3}$$
The increasing order of basicity of the given compounds is:
  • (b)< (a)< (c)< (d)
  • (b)< (a)< (d)< (c)
  • (d)< (b)< (a)< (c)
  • (a)< (b)< (c)< (d)
The correct order of basic strength of the compounds?
1087633_d79c57c1fa2b43c2b1c8a980fc3a9b5e.png
  • $$I > II > III$$
  • $$II > I > III$$
  • $$III > II > I$$
  • $$II > III > I$$
By heating ammonium chloride with two equivalents of formaldehyde it forms:
  • dimethylamine
  • ethylamine
  • methylamine
  • ammonium formate
Which of the following Statements is/are correct?
  • $$(SiH_3)_3N $$ is weaker base than $$(CH_3)_3N$$.
  • Amongst $$Cl-Cl$$, $$N-F$$,$$C-F$$ And $$O-F$$ bond is most polar
  • $$OF_2$$ has higher dipole moment than $$H_2O$$
  • An alchohol is less volatile than other having same molecular formula on account of intermolecular hydrogen bonding
$${C}_{4}{H}_{11}N(X)+H{NO}_{2} \rightarrow {C}_{4}{H}_{10}O$$($${3}^{o}$$ alcohol) 
Hence, $$X$$ will not give:
  • carbylamine reaction
  • hoffmann mustard oil reaction
  • diazorium salt (as the intermediate)
  • hofmann's bromamide reaction
$$sp^3-$$hybridised nitrogen is present in:
  • $$CH_2 = CH - \overset{\oplus}{N}H_3$$
The product $$B$$ of the following sequence, would be?
1086349_2201fcbc69204b23b5fc6072a75a38d0.JPG
  • $$I$$
  • $$II$$
  • $$III$$
  • $$IV$$ and $$V$$
The correct order of increasing basic nature for the bases $$NH_3,CH_3NH_2$$ and $$(CH_3)_2NH $$ is?
  • $$(CH_3)_2NH < NH_3 < CH_3NH_2$$
  • $$NH_3 < CH_3 NH_2 <(CH3)_2NH $$
  • $$CH_3NH_2 <(CH_3)_2NH < NH_3$$
  • $$CH_3NH_2 < NH_3 < (CH_3)_2NH$$
The end product (Z) of the following reaction is?
1096491_ac867f00062c495ea22db5a8add459a8.PNG
  • A cyanide
  • A carboxylic acis
  • An amine
  • An arene
Find product in the following reaction is Y. What is Y?
1100535_fd88450c89f34990b372bfda600d479c.png
  • benzamide
  • benzophenone
  • benzoic acid
  • benzaldehyde
$$CH_3Cl \xrightarrow{AgCN} A$$ (major) $$\xrightarrow{H-2O^+} C + D$$ here '$$C$$' is formic acid '$$D$$ is:'
  • $$2^o$$ amine
  • Carboxylic acid
  • Alkyl Cyanide
  • $$1^o$$ amine
Reductive amination of $$A$$ forms:
1097811_af3fe33a33654685b77e78a48b8883c4.png
The correct order of boiling points of the following amines $${ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 },\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH,{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }$$ is :
  • $${ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }>\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }$$
  • $$\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }$$
  • $${ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2} >\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }$$
  • $$\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }$$
Which of the following is the least basic?
  • All are equally basic
In the above reaction sequence (D) is?
1107986_5b367070c49f40c49a152a1f1737a17b.png
Suitable explanation for the order of basic character, $$(CH_{3})_{3}N < (CH_{3})_{2}NH$$, is:
  • steric hindrance by bulky methyl group
  • higher volatility of $$3^{\circ}$$ amine
  • stability of conjugate acid due to solvation
  • all of these
With which one of the following substrate do diazonium salt reacts to form a colourful compound?
In the reaction
$$Me_{3}N \xrightarrow{BrCN} A \xrightarrow[ii)\Delta]{i)H_{2}O}  B$$. 
B is
  • $$MeNH_{2}$$
  • $$Me_{3}NO$$
  • $$Me_{2}NH$$
  • $$Me_{2}NCOOH$$
The reagents/conditions K, L and M are respectively:
1109164_496a758a6c134969a39e7eb8aaf41dad.PNG
  • $$Ba(OH)_{2}$$, $$KCN$$ and $$CHCl_{3} / NaOH$$ heat, $$H_{3}O^{+}$$
  • $$H_{2}O$$ (boil), $$CO_{2} / KOH$$ and $$Ac_{2}O - AcONa$$, heat
  • Steam ; $$CHCl_{3} / NaOH$$, heat, $$H_{3}O^{+}$$ and $$AC_{2}O - AcONa$$, heat
  • $$Cu_{2}Cl_{2} / HCl$$, $$NaOH$$ / high P and $$CO_{2}|NaOH$$, heat
Which of the following compounds is an imine?
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