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CBSE Questions for Class 12 Engineering Chemistry Chemical Kinetics Quiz 16 - MCQExams.com

The half-life of 6C14, if its decay constant is 6.31×104 is:
  • 1098 yrs
  • 109.8 yrs
  • 10.98 yrs
  • 1.098 yrs
1516 th of a radioactive sample decays in 40 days half-life of the sample is:
  • 100 days
  • 10 days
  • 1 day
  • loge 2 days
A first-order nuclear reaction is half completed in 45 minutes. How long does it need 99.9% of the reaction to be completed?
  • 5 hours
  • 7.5 hours
  • 10 hours
  • 20 hours
Assertion : Order of the reaction can be zero or fractional.
Reason    : We cannot determine order from the balanced chemical equation.
  • Both assertion and reason are correct and the reason is correct explanation of assertion.
  • Both assertion and reason are correct but reason does not explain assertion.
  • Assertion is correct but reason is incorrect.
  • Both assertion and reason are incorrect.
  • Assertion is incorrect but reason is correct.
Which of the following statement is incorrect ?
  • Unit of rate of disappearance is Ms1
  • Unit of rate of reaction is Ms1
  • Unit of rate constant k depends upon order
  • Unit of k for first order reaction is Ms1
the rate constant for a first order reaction is 2×102min1 the half -life period of reaction is 
  • 69.3min
  • 34.65min
  • 17.37min
  • 3.46min
The activation energy in a chemical reaction is defined as 

  • the difference in energies of reactants and products
  • the sum of energy of reactant and products
  • the difference in energy of intermediate complex with the average of reactants and products
  • the difference in energy of intermediate complex and the average energy of reactants.
Cyclopropane rearranges to form propene
ΔCH3CH=CH2
this follows first order kinetics. the rate constant is 2.714×103sec1the initial concentration of cyclopropane is 0.29Mwhat will be concentration  of cyclopropane after 100 sec ?
  • 0.035M
  • 0.22M
  • 0.145M
  • 0.0018M
Fill up the following with suitable terms.

(i) Activation energy = Threshold energy - _____________
(ii) Half-life period of zero order reaction =_____________
(iii) Average rate of reaction = _____________
(iv) Instantaneous rate of reaction =____________

  • Potential energy ,   0.693k , dxdt , Δ[A]Δt
  • Energy of reactants ,  1k , Δ[A]Δt , dxdt
  • Energy of reaction  ,  logkt , Δ[A]Δt , dxdt
  • Average kinetic energy of reactants ,  a2k , Δ[A]Δt , dxdt
Which of the following is incorrect statement ?
  • Stoichiometry of a reaction tells about the order of the elementary reactions
  • For a zero order reaction, rate and the rate constant are idneitcal.
  • A zero order reaction is controlled by factors other than concentration of reactants
  • A zero order reaction is an elementary reaction
The activation energy of the reaction, A+BC+D+38kcal is 20 kcal, What would be the activation energy of the reaction,
C+DA+B
  • 20kcal
  • 20kcal
  • 18kcal
  • 58kcal
One or more answers is/are correct.
Select the correct statement(s):
  • Every substance that appears in the rate law of reaction must be a reactant or product in that reaction
  • If we know that rate law of a reaction; we can deduce it's mechanism must be elementary
  • If the reaction has rate r=k[A][B]3/2 then reaction may be elementary
  • A zero order reaction must be a complex reaction
An increase in the concentration of the reactants of reaction leads to change in :
  • Heat of reaction
  • Threshold energy
  • Collision frequency
  • Activation energy
When the activation energies of the forward and backward reactions are equal, then:
  • ΔE=0,ΔS=0
  • ΔE=0,ΔG=0
  • ΔS=0,ΔG=0
  • only ΔE=0
0:0:1


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