CBSE Questions for Class 12 Engineering Chemistry Coordination Compounds Quiz 1 - MCQExams.com

On treatment of $$100\, mL$$ of $$0.1\, M$$ solution of $$CoCl_{3}.6H_{2}O$$ with excess $$AgNO_{3};1.2\times 10^{22}$$ ions are precipitated. The complex is :
  • $$\left [ Co\left ( H_{2}O \right )_{3}Cl_{3} \right ].2H_{2}O$$
  • $$\left [ Co\left ( H_{2}O \right )_{6} \right ]Cl_{3}$$
  • $$\left [ Co\left ( H_{2}O \right )_{5}Cl \right ]Cl_{2}.H_{2}O$$
  • $$\left [ Co\left ( H_{2}O \right )_{4}Cl \right ]Cl_{2}.H_{2}O$$
Which of the following complexes is used to be as an anticancer agent?
  • $$mer-[Co(NH_3)_3Cl]$$
  • $$cis-[PtCl_2NH_3)_2]$$
  • $$cis-K_2[Pt Cl_2Br_2]$$
  • $$Na_2CoCl_4$$
Iron carbonyl, $$Fe(CO)_{5}$$ is __________.
  • trinuclear
  • tetranuclear
  • dinuclear
  • mononuclear
The hypothetical complex chloro-diaquatriamminecobalt(III) chloride can be represented as:
  • $$\left[ CoCl{ \left( { NH }_{ 3 } \right) }_{ 3 }{ \left( { H }_{ 2 }O \right) }_{ 2 } \right] { Cl }_{ 2 }$$
  • $$\left[ CoCl{ \left( { NH }_{ 3 } \right) }_{ 3 }{ \left( { H }_{ 2 }O \right) Cl }_{ 3 } \right] $$
  • $$\left[ CoCl{ \left( { NH }_{ 3 } \right) }_{ 3 }{ \left( { H }_{ 2 }O \right) }_{ 2 }Cl \right] $$
  • $$\left[ CoCl{ \left( { NH }_{ 3 } \right) }_{ 3 }{ \left( { H }_{ 2 }O \right) }_{ 3 }{ Cl }_{ 3 } \right] $$
The colour of blood is red due to the presence of:
  • magnesium
  • cytoglobin
  • haemoglobin
  • all of these
The properties of a compound are:
  • Similar to the properties of its constituents
  • Similar to the properties of one of the constituents
  • Different from the properties of its constituents
  • None of these
The brown complex obtained in the detection of nitrate radical is formulated as $$\displaystyle \left[ { Fe\left( { H }_{ 2 }O \right)  }_{ 5 }NO \right] { SO }_{ 4 }$$. What is the oxidation number of $$\displaystyle Fe$$ in this complex?
  • +1
  • +2
  • +3
  • 0
Which of the following compounds will exhibit the highest magnetic moment? 
  • (a)$$[Ti{(NH_3)}_6]^{3+} $$
  • (b)$$[Cr{(NH_3)}_6]^{3+} $$
  • (c)$$[Co{(NH_3)}_6]^{3+} $$
  • (d)$$[Zn{(NH_3)}_6]^{2+} $$
The hybridization of Ag in a $$[Ag(N{ H }_{ 3 }{ ) }_{ 2 }{ ] }^{ (+) }$$ is:-
  • sp
  • $${ sp }^{ 2 }$$
  • $${ sp }^{ 3 }$$
  • $${ dsp }^{ 2 }$$
The cobalt hexammine cation has an atom of cobalt in the centre, surrounded by six molecules of ammonia that are attached to it. The shape of this ion is?
  • Tetrahedral
  • Square
  • Linear
  • Octahedral
Pair of compounds which is planar:
  • $${ \left[ Ni{ \left( CN \right) }_{ 4 } \right] }^{ -4 },{ \left[ Pt{ Cl }_{ 4 } \right] }^{ -2 }$$
  • $${ \left[ Ni{ Cl }_{ 4 } \right] }^{ -2 },{ \left[ Ni{ \left( CN \right) }_{ 4 } \right] }^{ -4 }\quad $$
  • $${ \left[ Ni{ \left( CN \right) }_{ 4 } \right] }^{ -4 },{ \left[ Rh{ \left( CO \right) }_{ 2 }{ \left( P{ Ph }_{ 3 } \right) }_{ 2 } \right] }^{ + }$$
  • $${ \left[ Pt{ Cl }_{ 4 } \right] }^{ -2 },{ \left[ Ni{ \left( CN \right) }_{ 4 } \right] }^{ -4 }$$
Which of the following statement is correct?
  • Energy difference should be more between orbitals which undergo hybridization.
  • Number of hybrid orbitals formed should be same as the number of atomic orbitals involved in hybridization.
  • Hybrid orbitals arrange around the center of the atom unsymmetrically.
  • Hybrid orbitals can form $$\pi$$ bonds.

Transition metals are coloured due to the following electronic transition

  • d - s
  • d - d
  • s - p
  • f - s
Which of the following metal ion is present in Ziegler-Natta catalyst?
  • $$Fe^{2+}$$
  • $$Zr^{4+}$$
  • $$Rh^{+}$$
  • $$Ti^{4+}$$
The correct IUPAC name of $$Mn_{3}(CO)_{12}$$ is:
  • mangesedodecylcarbonyl(0)
  • dodecacarbonylmanganate(0)
  • dodecacarbonylmanganic(II)
  • dodecacarbonyltrimanganese(0)
The number of isomers exhibited by $$\left [ Cr\left ( NH_{3} \right )_{3}Cl_{3} \right ]$$ is:
  • 2
  • 3
  • 4
  • 5
Which of the following will give $$Fe^{3+}$$ ions in the solution?
  • $$[Fe(CN)_{6}]^{3-}$$
  • $$[Fe(CN)_{6}]^{4-}$$
  • $$NH_{4}(SO_{4})_2.FeSO_{4}.6H_{2}O$$
  • $$Fe_{2}(SO_{4})_{3}$$
Hybridisation involves:
  • addition of an electron pair
  • combination and redistribution of atomic orbitals
  • removal of an electron pair
  • separation of orbitals
Co-ordination compounds are mostly formed by:
  • s-block elements
  • p-block elements
  • d-block elements
  • f-block elements
The chemical formula of iron(III) hexacyanoferrate(II) is:
  • $$Fe\left [ Fe\left ( CN \right )_{6} \right ]$$
  • $$Fe_{3}\left [ Fe\left ( CN \right )_{6} \right ]$$
  • $$Fe_{3}\left [ Fe\left ( CN \right )_{6} \right ]_{4}$$
  • $$Fe_{4}\left [ Fe\left ( CN \right )_{6} \right ]_{3}$$
IUPAC name of $$Na_{3}\left [ Co\left ( ONO \right )_{6} \right ]$$ is:
  • Sodium cobaltinitrite
  • Sodium hexanitritocobaltate (III)
  • Sodium hexanitrocobalt (III)
  • Sodium hexanitritocobaltate (II)

Example for a coordination compound is ____________.

  • $$KCl.MgCl_{2}.6H_{2}O$$
  • $$K_{2}SO_{4}Al_{2}(SO_{3})24H_{2}O$$
  • $$CoCl_{3}.6NH_{3}$$
  • $$FeSO_{4}.(NH_{4})_{2}SO_{4}.6H_{2}O$$

Which is a coordination compund ?

  • Ferrous ammonium sulphate
  • Carnallite
  • Potassium ferrocyanide
  • Gypsum

The primary valence of the metal ion is satisfied by :

  • neutral molecules
  • positive ions
  • negative ions
  • all
Which of the following has the highest molar conductivity?
  • $$[Co(NH_{3})_{6}]Cl_{3}$$
  • $$[Co(NH_{3})_{5}Cl]Cl_{2}$$
  • $$[Co(NH_{3})_{4}Cl_{2}]Cl_{2}$$
  • $$[Co(NH_{3})_{3}Cl_{3}]$$

Transition elements form complexes readily because :

  • Small size of cation
  • Large ionic Charge
  • Vacant d orbitals
  • All the above
According to Werner’s theory of valency, transition metals possess:
  • only one type of valency
  • two types of valencies
  • three types of valencies
  • four types of valencies

During the splitting of degenerate d-orbitals under the influence of ligand the average d-orbital energy

  • remains same
  • increases
  • decreases
  • may increase or decrease

The ionizable valency of Ni in Ni(CO)$$_{4}$$ is __________.

  • 2
  • 4
  • 0
  • 1

The following ion shows colour not due to d-d transistion.

  • $$Cr_{2}O{_{7}}^{2-}$$
  • $$MnO{_{4}}^{-}$$
  • $$CrO{_{4}}^{2-}$$
  • All

The splitting of degenerated d-orbitals takes place into which of the following two sets :

  • $$d_{xy},d_{z^{2}},d_{xz}$$and $$d_{yz},d_{x^{2}-y^{2}}$$
  • $$d_{xy},d_{yz},d_{zx}$$ and $$d_{x^{2}-y^{2}},d_{z^{2}}$$
  • $$d_{xy},d_{x^{2}-y^{2}},d_{z^{2}}$$ and $$d_{yz},d_{xz}$$
  • $$d_{xy},d_{x^{2}-y^{2}},d_{xz}$$ and $$d_{yz},d_{z^{2}}$$

Number of $$Cl^{-}$$  ions satisifying both primary and secondary valency are in $$CoCl_{3}.5NH_{3}$$.

  • 1
  • 2
  • 3
  • 4

In the presence of strong eletrical field, the following set of orbitals are not degenerate :

  • $$3d_{xy}         and 3d_{z}2$$
  • $$3d_{xy}     and 3d_{yz}$$
  • $$3d_{xy}, 3d_{yz}      and 3d_{zx}$$
  • all the above

1 mole of amino cobalt chloride on treating with an excess of $$AgNO$$$$_{3}$$ solution gives $$2$$ moles of $$AgCl$$ precipitate. The number of $$Cl^-$$ ions which satisfies both primary and secondary valency of cobalt in the complex is:

  • $$2$$
  • $$3$$
  • $$1$$
  • $$0$$
When mole of $$CoCl_{3}.6NH_{3}$$ is treated with excess of AgNO$$_{3}$$ solution. The number of moles of AgCl precipitated is:
  • 3
  • 0
  • 1
  • 2
The primary and secondary valency of $$Co$$ in the octahedral complex $$CoCl_{3}.5NH_{3}$$ are __________.
  • 6 and 3
  • 3 and 6
  • 4 and 3
  • 3 and 5

IUPAC name for the complex $$[Cu(NH_{3})_{4}]SO_{4}$$ is:

  • cupramonium sulphate
  • copper sulphate tetraamonia
  • tetrammine copper (II) sulphate
  • copper amonium (IV) sulphate
The molecular interactions responsible for hydrogen bonding in HF:
  • $$\text{ion induced dipole}$$
  • $$\text{dipole dipole}$$
  • $$\text{dipole induced dipole}$$
  • $$\text{none}$$

An excess of AgNO$$_{3}$$ is added to 100 ml of a 0.1 M solution of dichlorotetraaquachromium (III) chloride. The number of mol of AgCl precipitate would be:

  • 0.001
  • 0.002
  • 0.003
  • 0.01
The correct order of ligands for writing the formula of complex compounds is _________.
  • neutral, anionic, cationic
  • anionic, neutral, cationic
  • anionic, cationic, neutral
  • cationic, neutral, anionic

$$[Co(NH_{3})_{4}(NO_{2})_{2}]Cl$$ exhibits:

  • linkage, ionization and geometrical isomerism
  • ionisation, geometrical and optical isomerism
  • linkage, geometrical and optical isomerism
  • linkage, ionization and optical isomerism
Which of the following is considered to be ananticancer species :

Coordination compounds have great importance in biological systems. In this context which of the following statements is incorrect?

  • Chlorophylls are green pigments in plants and contain calcium
  • Haemoglobin is the red pigment of blood and contains iron
  • Cyanocobalamin is $$B_{12}$$ and contains cobalt
  • Carboxypeptidase-A is an enzyme and contains zinc
Co-ordination compounds have great importance in biological systems. In this context which of the
following statements is incorrect? 
  • Chlorophylls are green pigments in plants and contain calcium
  • Haemoglobin is the red pigments of blood and contains iron
  • Cyanocobalamin is vitamin B12 and contains cobalt
  • Carboxypeptidase-A is an enzyme and contains zinc
Compounds having equal number of hybrid orbitals among the following are:
  • none of these
In which of the compound given below contains more than one kind of hybridization ($$sp,sp^{2}$$, $$sp^{3}$$ ) for carbon:
  • $$CH_{3}CH_{2}CH_{2}CH_{3}$$
  • $$CH_{3}-CH=CH-CH_{3}$$
  • $$CH_{2}=CH-CH=CH_{2}$$
  • $$H-C\equiv C-H$$
Total numbers of hybrid orbitals present in $$CH_{3}-C\equiv CH$$ are:
  • $$8$$
  • $$6$$
  • $$4$$
  • $$2$$

Statement I: The geometrical isomer of the complex $$[M(NH_{3})_{4}Cl_{2}]$$ are optically inactive.

Statement II: Both geometrical isomers of the complex $$[M(NH_{3})_{4}Cl_{2}]$$ possess axis of symmetry

Select the correct option regarding given statements:

  • Statement I is true, Statement II is true,Statement II is a correct explanation of Statement I.
  • Statement I is true, Statement II is true,Statement II is not the correct explanation of statement I
  • Statement I is true, Statement II is false.
  • Statement I is false, Statement II is true.

The neutral complex, diamine dibromo dichloro platinum (IV) is best represented as: 

  • $$[Pt(NH_{3})_{2}Br_{2}Cl_{2}]$$
  • $$[PtCl_{2}Br_{2}(NH_{3})_{2}]$$
  • $$[PtBr_{2}Cl_{2}(NH_{3})_{2}]$$
  • $$[Pt(NH_{3})_{2}Cl_{2}Br_{2}]$$
$$CuSO_{4}$$ when reacts with $$KCN$$ forms $$CuCN$$ which is insoluble in water. It is soluble in excess of $$KCN$$, due to formation of the following complex:
  • $$K_{2}[Cu(CN)_{4}]$$
  • $$K_{3}[Cu(CN)_{4}]$$
  • $$CuCN_{2}$$
  • Cu$$[KCu(CN)_{4}]$$
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