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CBSE Questions for Class 12 Engineering Chemistry The D-And F-Block Elements Quiz 10 - MCQExams.com

Among dblock elements, the most abundant element belongs to :
  • first transition series
  • second transition series
  • third transition series
  • fourth transition series
The correct order of ionic radii of Ce,La,Pm and Yb in +3 oxidation state is:
  • La3+<Pm3+<Ce3+<Yb3+
  • La3+<Ce3+<Pm3+<Yb3+
  • Yb3+<Ce3+<Pm3+<La3+
  • Yb3+<Pm3+<Ce3+<La3+
Transition metals are often paramagnetic owing to 
  • Their high M.P. and B.P
  • The presence of vacant orbitals
  • The presence of one or more unpaired electrons in the system
  • Their being less electropositive than the elements of groups I-A and II-A
Transition elements are coloured
  • Due to small size
  • Due to metallic nature
  • Due to unpaired d - electrons
  • All of these
Which of the following is not the characteristic of transition metals?
  • They are all metals
  • They show variable oxidation states which always differ by two units
  • They are paramagnetic
  • They easily form complex
The property which is not characteristic of transition metals, is: 
  • variable oxidation state
  • tendency to form complex
  • formation of coloured compounds
  • natural radioactivity
The radius of La3+ (atomic number of La=57) is 1.06A˚ which one of the following given values will be closest to the radius of Lu^{3+} (atomic number of Lu = 71)?
  • 1.40 \mathring{A}
  • 1.06 \mathring{A}
  • 0.85 \mathring{A}
  • 1.60 \mathring{A}
Ammonia solution dissolves fairly:
  • Hg_2Cl_2
  • PbCl_2
  • AgI
  • Cu(OH)_2
Which one of the following ions is diamagnetic?
  • Cr^{2+}
  • V^{2+}
  • Sc^{3+}
  • Ti^{3+}
Which one of the following complexes is diamagnetic in nature?
  • [Cr(NH_3)_6]^{3+}
  • [FeF_6]^{3-}
  • [Co(NH_3)_6]^{3+}
  • [Fe(H_2O)_6]^{2+}
A metal ion from the first transition has a magnetic moment (calculated) of 3.87\ B.M. How many unpaired electrons are expected to be present in the ion?
  • 1
  • 2
  • 3
  • 4
Verdigris is:
  • basic copper acetate
  • basic lead acetate
  • basic lead
  • none
When excess of SnCl_2 is added to a solution of HgCl_2, a white precipitate turning to grey is obtained. The grey colour is due to the formation of:
  • Hg_2Cl_2
  • SnCl_4
  • Sn
  • Hg
Which one of the following is paramagnetic in nature ?
  • Ni(CO)_4
  • [Ni(CN)_4]^{2-}
  • [NiCl_4]^{2-}
  • [Co(NH_3)_6]^{3+}
The colour of zinc sulphide is:
  • yellow
  • white
  • brown
  • black
Which of the following pairs of ions have same paramagnetic moment?
  • Mn^{2+}, Cu^{2+}
  • Cu^{2+}, Ti^{3+}
  • Ti^{4+}, Cu^{2+}
  • Ti^{3+}, Ni^{2+}
The radius of La^{3+} is 1.06\ \overset {o}{A}, which of the following given values will be closest to the radius of Lu^{3+} (At. no of Lu=71, La=57)?
  • 1.6 \ {A}^{o}
  • 1.4\ {A}^{o}
  • 1.06\ {A}^{o}
  • 0.85 \ {A}^{o}
Among d- block elements, the most abundant element belongs to the:
  • first transition series
  • second transition series
  • third transition series
  • fourth transition series
Which one of the following ion has a magnetic moment of 5.93\ B.M ?
  • Mn^{2+}
  • Fe^{2+}
  • Cr^{2+}
  • V^{3+}
  • Cr^{3+}
Which has maximum paramagnetic character ?
  • [Fe(CN)_6]^{4-}
  • [Cu(H_2O)_4]^{2+}
  • [Cu(NH_3)_4]^{2+}
  • [Mn(H_2O)_6]^{2+}
Which of the following is not correct?
  • [Fe(CN)_6]^{3-} is weakly paramagnetic
  • [Fe(CN)_6]^{4-} is strongly paramagnetic
  • [Ni(CN)_4]^{2-} is diamagnetic
  • [NiCl_4]^{2-} is paramagnetic
Which group contains coloured ions out of
Cu^+\ Ti^{4+}\ Co^{2+}\ Fe^{2+}
  • 1,2,3,4
  • 3,4
  • 2,3
  • 1,2
Which of the following pairs of transition metal ions are the stronger oxidising agents in aqueous solution?
  • V^{2+} and Cr^{2+}
  • Ti^{2+} and Cr^{2+}
  • Mn^{3+} and Co^{3+}
  • V^{2+} and Fe^{2+}
  • Ni^{2+} and Fe^{2+}
Which of the following statements is wrong  for the transition elements ? 
  • Transition elements are placed from 3^{rd} to 6^{th} period
  • Last electron enters in (n-1) d orbital
  • Exhibits variable valency
  • General electronic configuration is (n-1) d^{1-10} n s^{0-2}
Predict the magnetic nature of A and B.
  • both are diamagnetic
  • A is diamagnetic and B is paramagnetic with one unpaired electrons
  • A is diamagnetic and B is paramagnetic with two unpaired electrons
  • both are paramagnetic
The complex forming tendency of a transition metal depends upon:
  • Availability of a number of vacant d- orbitals
  • high ionisation energy
  • small size of cation or high charge density
  • variable oxidation states
The correct order of magnetic moments amongst following complex ions is:
  • [MnCl_4]^{2-} > [Fe(CN)_6]^{4-} > [CoCl_4]^{2-}
  • [Fe(CN)_6]^{4-} > [MnCl_4]^{2-} > [CoCl_4]^{2-}
  • [MnCl_4]^{2-} > [CoCl_4]^{2-} > [Fe(CN)_6]^{4-}
  • [Fe(CN)_6]^{4-} > [CoCl_4]^{2-} > [MnCl_4]^{2-}
In the long form of periodic table, all the non-metals and metalloids are placed with :
  • s-block
  • p-block
  • d-block
  • f-block
Which one of the following complexes is not diamagnetic?
  • [Fe(CN)_6]^{4-}
  • [Ti(H_2O)_6]^{3+}
  • [Pt(CN)_4]^{2-}
  • [Co(NH_3)_6]^{3+}
The correct increasing order of paramagnetism of
(i)\ MnSO_4.  4H_2O
(ii)\ FeSO_4.  7H_2O
(iii)\ NiSO_4.  6H_2O
(iv)\ CuSO_4.  5H_2O is:
  • (i) < (ii) < (iii) < (iv)
  • (iv) < (iii) < (i) < (i)
  • (iii) < (iv) < (ii) < (i)
  • (iii) < (iv) < (i) < (ii)
Transition metals form complexes because of:
  • small cation size
  • vacant d- orbitals
  • large iconic charge
  • all of these
The ionic radius of  _{57}La^{3+} is 1.06 \overset oA Which one the  following give values will be closest to the ionic radius  of  _{71}Lu^{3+} ?
  • 1.06 \overset oA
  • 1.56 \overset oA
  • 0.85 \overset oA
  • 1.35 \overset oA
Which ine of the following statement about lanthanides is false?
  • Lanthanides are sepearated from one another by ion exchange method
  • The ionic radii of trivalent lanthanides steadily increases with increase in atomic number
  • All lanthanides are highly dense metals
  • Most typical oxidation state of lanthanides is +3
The ions from among the following which are colourless are 
(i) Ti^{4+}   (ii) Cu^{+}   (iii) Co^{3+}    (iv) Fe^{2+}
  • i and ii only
  • i, ii and iii
  • iii and iv
  • ii and iii
Which of the following function as catalysts for oxidation of SO_2 to SO_3 in industrial process for production of H_2SO_4?
  • TiO_2
  • PbO_2
  • Pt
  • V_2O_5
Among the following, the species that is both paramagnetic and coloured is : 
  • \left [ MnO_{4} \right ]^{2-}
  • \left [ TiCl_{6} \right ]^{2-}
  • \left [ VO_{4} \right ]^{2-}
  • CrO_{2}Cl_{2}
Which ionic radius of {_{57}{La^{3+}}} is 1.06A. which one of the following values will be closest to ionic radius of {_{71}{Lu^{3+}}}. ?
  • 1.06A
  • 1.56A
  • 0.85A
  • 1.35A
Out of all the known elements, the percentage of transitional elements is approximately  
  • 30\% 
  • 50\% 
  • 60\% 
  • 75\% 
Atomic number of Cr and Fe are 24 and 26 respectively. Which of the following is paramagnetic with the spin of electron?
  • [ Cr(NH_3)_6]^{3+}
  • [Fe(CO)_5]
  • [ Fe (CN)_6]^{4-}
  • [ Cr(CO)_6 ]
Which of the following pair of elements cannot form an alloy ?
  • Zn - Hg
  • Fe - Hg
  • Hg - Cr 
  • Na - Hg
Iron loses magnetic property at 
  • Melting point
  • 1000K
  • Curie point
  • Boiling point
The term platforming is 
  • Platinum painting
  • Flat sheet of platinum
  • Platinum manufacturing
  • Platinum used as a catalyst
Arrange Ce^{3+} , La^{3+} ,Pm^{3+} and Yb^{3+} in increasing order of their ionic radii
  • Yb^{3+} < Pm^{3+} < Ce^{3+} < La^{3+}
  • Ce^{3+} < Yb^{3+} < Pm^{3+} < La^{3+}
  • Yb^{3+} < Pm^{3+} < La^{3+} < Ce^{3+}
  • Pm^{3+} < La^{3+} < Ce^{3+} < Yb^{3+}
Colour of cobalt chloride solution is
  • pink
  • black
  • colourless
  • green
Which of the following statement(s) is(are) correct with reference to the ferrous and ferric ions?
  • Fe^{3+} gives brown colour with potassium ferricyanide
  • Fe^{2+} gives blue precipitate with potassium ferricyanide
  • Fe^{3+} gives red colour with potassium thiocyanate
  • Fe^{2+} gives brown colour with ammonium thiocyanate
Alizarin gives a red colour by mordanting it with the sulphate of a metal. The metal ion involved is 
  • Cr^{3+}
  • Fe^{3+}
  • Al^{3+}
  • Sn^{2+}
If CdI_2 is pink in colour, the CdCl_2 will be  '________' coloured.
  • yellow
  • red
  • blue
  • cannot be predicted
Which metal absorbs hydrogen?
  • Al
  • Fe
  • Pd
  • K
In the dichromate anion (Cr_{2}O_{7}^{2-}),
  • all Cr - O bonds are equivalent
  • 6 \,Cr - O bonds are equivalent
  • 3 \,Cr - O bonds are equivalent
  • no bonds in Cr_{2}O_{7}^{2-} are equivalent.
Which of the following statements is wrong?
  • Ti^{4+} and Ag^{+} are repelled by magnetic field
  • Mn^{2+} shows maximum magnetic character among the first transition series.
  • Fe^{2+} is more stable than Mn^{2+} towards oxidation to +3 state.
  • Cr in Cr_{2}O_{7}^{2-} ion involves sp^{3}d^{2} hybridisation
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