CBSE Questions for Class 12 Engineering Chemistry General Principles And Processes Of Isolation Of Elements Quiz 12 - MCQExams.com

Match the processes with the element for which they are used:
Column-I                                                         Column-II
(P) Bessemerisation                                         (1) Ti
(Q) Van Arkel Method                                     (2) Cast iron
(R) Carbon reduction                                       (3) Sn
(S) Cupellation                                                 (4) Ag
  • $$P - 2, Q - 1, R - 3, S - 4$$
  • $$P - 3, Q - 1, R - 2, S - 4$$
  • $$P - 2, Q - 4, R - 3, S - 1$$
  • $$P - 1, Q - 2, R - 3, S - 4$$
What is the role of aniline or cresol when added in a forth floatation process? 
  • Stabilizer
  • Depressant
  • Wetting agent
  • All of these
the mass of carbon anode consumed (giving only carbon dioxide) in the production of $$270Kg$$ of aluminium metal from bauxite by the Hall's process is: 
$$2Al_2O_3+3C \to 4Al + 3CO_2$$
  • $$180Kg$$
  • $$270Kg$$
  • $$240Kg$$
  • $$90Kg$$
Statement-I Froth Floatation process is based on the different wetting nature of ore and gangue particles
Statement-II Mustard oil is used as a frother in froth floatation 
  • Statement $$I$$ and $$II$$ are correct
  • Both are false
  • Statement $$I$$ is true but $$II$$ is flase
  • Statement $$II$$ is true but $$I$$ is false
Which of the following gives an aldehyde on dry distillation?
  • Calcium formate + Calcium acetate
  • Calcium acetate + Calcium benzoate
  • Calcium acetate
  • Calcium benzoate
In solid $$CuS{ O }_{4  }.5{H  }_{2  }O$$ ,copper is coordinated to number of water molecule:-
  • 5
  • 4
  • 1
  • 2
In electrolysis of $${\text{A}}{{\text{l}}_{\text{2}}}{{\text{O}}_{\text{3}}}$$ by Hall-Heroult process, which of the following statement(s) is/are correct?
  • Cryolite $${\text{N}}{{\text{a}}_{\text{3}}}\left[ {{\text{Al}}{{\text{F}}_{\text{6}}}} \right]\,$$ lowers the meting point of $${\text{A}}{{\text{l}}_{\text{2}}}{{\text{O}}_{\text{3}}}\,$$increases its electrical conductivity.
  • Al is obtained at cathode and probably$$\,{\text{C}}{{\text{O}}_{\text{2}}}$$ at anode
  • Electrolysis is carried out in aqueous solution at anode
  • Anode consist of graphite
Which reduction method is used in commercial extraction of Pb?
  • Aluminium reduction
  • Self Reduction
  • Electrolytic reduction
  • Hydrometallurgical reduction
Which of the following metals occurs in nature principally oxide ores.
  • $$Ca$$
  • $$Co$$
  • $$Cr$$
  • $$Cu$$
The correct statement regarding the given Ellingham diagram is :

1364163_58aa69bbfb164f2fb8c18aaedf5a0ed6.png
  • Coke can't be used for the extraction of Cu from Cu$$

    _{2}O

    $$
  • At 500$$ ^{\circ} $$C, Coke can be used for the extraction of Zn from ZnO.
  • At 800$$ ^{\circ} $$C, Cu can be used for the extraction of Zn from ZnO.
  • At 1400$$ ^{\circ} $$C, Al can be used for the extraction of Zn from ZnO.
According to Ellingham diagram, the oxidation reaction of carbon to carbon monoxide may be used to reduce which of the following oxides at the lower temperature?
  • $${\text{MgO}}$$
  • $${\text{ZnO}}$$
  • $${\text{A}}{{\text{l}}_{\text{2}}}{{\text{O}}_{\text{2}}}$$
  • $${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$$
Which of the following Ellingham diagram ensures that at temperature $${T_3}$$, $$A$$ can reduce $$CO$$ ,$$B$$ can reduce $$AO$$ ,and $$B$$ can reduces $$CO$$ but $$'A'$$ cannot reduce $$BO$$? (where $$A$$, $$B$$ and $$C$$ are three unknown element ).
Hall-Heroult's process is given by:
  • $$Cr_2O_3 + 2Al \rightarrow Al_2O_3 + 2Cr$$
  • $$Cu^{2+}(aq) + H_2(g) \rightarrow Cu(s) + 2H^+ (aq)$$
  • $$ZnO + C \xrightarrow[]{Coke, 1673K} Zn + CO$$
  • $$2Al_2O_3 + 3C \rightarrow 4Al + 3CO_2$$
An incorrect statement about froth floatation method is:
  • it is used to remove gangue from sulphide ores
  • the mineral particles become wet by oils while gangue particles become wet by water
  • collectors stabilize the froth
  • to separate a mixture of ZnS and PbS depressant used is NaCN
In which of the following chemical leaching is used either in the extraction of metal or in the concentration of ore?
  • Argentite
  • Bauxite
  • Alluvial sand containing gold
  • All of these
A process of heating ore of a metal in excess of air below its melting point is called:
  • Roasting
  • Smelting
  • Calcination
  •  All of these
With respect to an ore, Ellingham diagram helps to predict the feasibility if its:
  • vapour phase refining
  • zone refining
  • electrolysis
  • thermal reduction
Chief ore of Iron is
  • Magnetite
  • Siderite
  • Haematite
  • All of these
Which of the following metal ore is not concentrated by forth flotation method ?
  • Sphalerite
  • Argentite
  • Galena
  • Copper pyrites
Ellingham diagram is used for:
  • Reduction
  • Electrolysis
  • Zone refining
  • Van-Arkel
The sulphide ore for which the froth floatation process is not used commercially is:
  • $$ZnS$$
  • $$CuS$$
  • $$ Ag_2S $$
  • $$PbS$$
The incorrect statement for Ellingham diagram is 
  • its a graphical representation of standard free energy change with temperature
  • the graph of metal oxides generally moves upward with increase in temperature
  • it represents thermodynamic and kinetic feasibility for the process
  • The steep rise in the slope indicates the phase change
The ore having two metal atoms is :
  • hematite
  • galena
  • magnetite
  • copper pyrites
Boron can be obtained by various methods but not by:
  • Pyrolysis of $$BI_3$$ (Van Arkel)
  • Reducing $$BCl_3$$ with $$H_2$$
  • Electrolysis of fused $$BCl_3$$
  • Oxidation of $$B_2O_3$$
The ore having two different metal atoms is:
  • Hematite
  • Galena
  • Magnetite
  • Copper pyrites
Which of the following is incorrect on the basis of the above Ellingham diagram for carbon?
1722924_019a80f4c7134b09b6c0e9d81c30bc27.PNG
  • Up to $$710^0C$$, the reaction of formation of $$CO_2$$ is energetically more favourable, but above $$710^0C$$, the formation of CO is preferred
  • In principle, carbon can be used to reduce any metal oxide at a sufficiently high temperature
  • $$\Delta S (C_{(s)} + \frac{1}{2}O_{2(g)} \rightarrow CO_{(g)} \ < \Delta S (C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)})$$
  • Carbon reduces many oxides at elevated temperature because $$\Delta G^0$$ vs temperature line has a negative slope
The idea of froth floatation method came from a person X and this method is related to the process Y of ores. X and Y, respectively, are: 
  • fisher woman and concentration
  • washer man and reduction
  • washer woman and concentration
  • fisher man and reduction
Tin is not refined by:
  • Liquation
  • Zone refining
  • Poling
  • Any of these
Ag can be obtained from purified Zn-Ag alloy by:
  • Distillation
  • Poling
  • Liquation
  • Reduction
Find out A:
1723272_3a5b8844e6d64afaa00d85689626c9ae.PNG
  • $$Cu_2S$$
  • $$CuFeS_2$$
  • $$FeS_2$$
  • $$Fe_3O_4$$
$$Al_2O_3$$ can be reduced by carbon at a temperature of :
1723341_54aff4c7ad3446d093a3bcb2f8c40e7b.png
  • $$30^0C$$
  • $$500^0C$$
  • $$2000^0C$$
  • $$>2500^0C$$
Zn-Ag alloy formed in the upper layer of molten lead is skimmed off from the surface of the molten lead by perforated ladles. This alloy contains lead as impurity. This impurity of Pb is removed by:
  • Distillation process
  • Cupellation
  • Liquation
  • Bett's electrolysis
Select the correct statement(s):
  • When tempreture is raised, a point will be reached where the graph crosses the $$\Delta G = 0$$ line. Below this tempreture, the free energy of formation of the oxide is negative, so the oxide is stable.
  • When temperature is raised, a point will be reached where the graph crosses the $$\Delta G = 0$$ line. Above this tempreture, the free energy of formation of the oxide is positive, and the oxide becomes unstable, and should decompose into the metal and dioxygen
  • Theoretically, all oxides can be decomposed to give the metal and dioxygen if a sufficiently high tempreture can be attained.
  • Theoretically, all oxides cannot be decomposed to give the metal and dioxygen of a sufficiently high tempreture can be attained
Select the correct statment(s):
  • In hydrometallurgy, Zn is used as oxidizing agent in the purification of Ag from $$[Ag(CN)_2)]^{\ominus}$$
  • When pine oil or eucalyptus oil is added into the water, it lowers down the surface tension by which froth is formed.
  • Sodium ethyl xanthate is used as collector
  • Basic copper carbonate or $$PbSO_4$$ is concentrated by forth floatation method by using an activator.
Which metal is generally found in native state?
  • $$Cu$$
  • $$Au$$
  • $$Al$$
  • $$Fe$$
In the extraction of aluminium by Hall-Heroult process, purified $$Al_2O_3$$ is mixed with $$CaF_2$$ to:
  • Lower the melting point of $$Al_2O_3$$
  • Increase the conductivity of molten mixture
  • Reduce $$Al^{3+}$$ into Al(s)
  • Acts as catalyst
In a mixture of $$PbS, ZnS, $$ and $$FeS$$, each component is separated from the other by using the reagents in which of the following sequence in the froth floatation process?
  • Potsassium ethyl xanthate, $$KCN, NaOH$$, copper sulphate, acid
  • $$KCN, CuSO_4,$$ acid
  • Potassium ethyl xanthate, $$KCN$$
  • None of these
During the process of electrolytic refining of copper, some metals present as impurity settle as 'anode mud'. These are:
  • Fe and Ni
  • Ag and Au
  • Pb and Zn
  • Sn and Ag
The ore that is concentrated by forth floatation process is:
  • cinnabar
  • bauxite
  • malachite
  • zincite
Froth floatation process is based on : 
  • Specific gravity of the ore particles
  • Magnetic properties of the ore particles
  • Wetting properties of the ore particles
  • Electric properties of the ore particles
The impurities present in the mineral are called : 
  • flux
  • gangue
  • alloy
  • slag
Which of the following ores is not concentrated by froth floatation process?
  • Copper pyrites
  • Pentlandite
  • Pyrolusite
  • Zinc blende
Select the correct statement:
  • Dolomite is the ore of zinc
  • Galena is the ore of mercury
  • Pyrolusite is the ore of iron
  • Cassiterite is the ore of tin
A mineral is called ore if:
  • The metal present in the mineral is costly
  • A metal can be extracted from it
  • A metal can be extracted profitably from it
  • A metal cannot be extracted from it
Radium is obtained from:
  • pitchblende
  • haematite
  • monazite
  • none of these
$$Al_2O_3$$ formation from aluminium and oxygen involves evolution of a large quantity of heat, which makes aluminium use in
  • deoxidiser
  • confectionary
  • indoor photography
  • thermite welding
Among the following incorrect statements is:
  • Argantite and cuprite are oxide ores
  • Calamine and azurite are carbonates
  • Zinc blends and pyrites are sulphides
  • Malachite and azurite are ores of copper
One of the natural minerals of sodium is tincal. Its formula is:
  • $$Na_{2}CO_{3}.10H_{2}O$$
  • $$NaNO_{3}$$
  • $$Na_{2}B_{4}O_{7}.10H_{2}O$$
  • $$NaCl$$
Potassium nitrate is called:
  • Mohr's salt
  • Indian saltpetre
  • Gypsum
  • Chile saltpetre
Which of the following pairs are not correctly matched with respect to the extraction of metals from their ores
  • Leaching process - Silver and gold from their native ores.
  • Self reduction - Copper and mercury from their sulphide ores.
  • Carbon/carbonmonoxide reduction - Iron and zinc from their oxide ores.
  • Electrolytic reduction - Aluminium and tin from their oxide ores.
0:0:1


Answered Not Answered Not Visited Correct : 0 Incorrect : 0

Practice Class 12 Engineering Chemistry Quiz Questions and Answers