Loading [MathJax]/jax/element/mml/optable/GeneralPunctuation.js

CBSE Questions for Class 12 Engineering Chemistry Haloalkanes And Haloarenes Quiz 13 - MCQExams.com

When alkyl halide is heated with an aqueous solution of silver nitrite,it gives:
  • Nitroalkane only
  • Alkyl nitrite only
  • Alkyl amine
  • None of these
By Wurtz reaction which of the following will give you n - hexane?
  • 1-chloro propane
  • 2-chloro propane
  • Both of these
  • None of these
In chlorobenzene, Cl group attached to benzene acts as activating ortho-para directing due to:
  • (-I) effect = (+) R effect
  • (-I) effect > (+ R) effect
  • (-I) effect < (+ R) effect
  • (-I) effect < (- R) effect

Product X is :
1289141_233003d382b146ae8409abcb9c07916e.png
The total number of optically compounds formed in the following reaction is:-

1285752_33ff87095fe5418f893b96473a1d7856.png
  • Four
  • Two
  • Six
  • Zero
The major product of the following reaction is:
C6H5CH2CH3|C|BrCH2CH3C2H5ONaC2H5OH
  • C6H5CH2CH3|C|OC2H5CH2CH3
  • C6H5CH=C|CH3CH2CH3
  • C6H5CH2C|CH3=CHCH3
  • C6H5CH2C|CH2CH3=CH2

IUPAC name of (CH3)3CCl is:

  • 1butylchloride
  • 3chlorobutane
  • 2chloro2methylpropane
  • 2butylchloride
The general formula of alkyl halides is:
  • CnH2nX
  • CnH2n+1X
  • CnH2nX2
  • CnH2n1X
Rank the alkyl halides in order of increasing reactivity in E2 reaction.
  • none
Write the product :

C6H5CH2CH=CH2+HBr
  • C6H5CH(Br)CH=CH2
  • C6H5CHCH2CH2(Br)
  • C6H5CH2CH1(Br)CH3
  • none of the above
Which of the following do not form Grignard reagent?
  • CH3F
  • CH3Cl
  • CH3Br
  • CH3I
When Me3COCH3 react with excess of HI gives CH3I and Me3CI. It follows the type of mechanism is:
  • Only SN1
  • Only SN2
  • SN2 and SN1
  • SN1 and SN2
Acetaldehyde undergoes aldol condensation giving β- hydroxyl carbonyl compound,which on dehydration in basic medium giving α,β unsaturated carbonyl compound,this dehydration in basic medium is an example for 
  • E1 elimination
  • E2 elimination
  • E1 cb elimination
  • E1 or E2
C6H5CCL5Cl2FeX
In the above reaction X is
  • None of these
In which of the following compound the electrophile attack on o- and p- position :
Identify the false statement 
  • Chloro benzene with chlorine in presence o AlCl3 gives o and p- di chloro benzene
  • Benzene with acetyl chloride in presence o AlCl3 gives Acetophenone
  • Benzene on onolysis gives three moles of glycol
  • Benzene on chlorination in presence of sunlight forms an addition product which is used as insecticide
Which of the following is not optically active?
  • [Co(en)3]3+
  • [Cr(ox)3]3
  • cis[CoCl2(en)2]+
  • trans[CoCl2(en)2]+

Among the following in which compound Br atom has the highest locant number during IUPAC nomenclature: 
1339034_1be0aad5ef5f44c0afcb7a41b28b1474.png
  • Only (a)
  • Only (b)
  • Only (c)
  • Both (a) and (c)
The major product of the following reaction is:
1365625_ab7cb370103c4f3884802e9fe4287d14.PNG
CH3CH2ClNaCNXNi/H2YAceticanhydrideZ

 Z in the above reaction sequence is 
  • CH3CH2CH2NHCOCH3
  • CH3CH2CH2NH2
  • CH3CH2CH2CONHCH3
  • CH3CH2CH2CONHCOCH3

What is the IUPAC name of the following compound? 
1367104_a733019d5b1049a98acdedfe33de0e1a.PNG
  • 2-Bromo 3- methylpent-3-ene
  • 4-Bromo-3-methylpent-2-ene
  • 3-Bromo-1,2,dimethylbut-1-ene
  • 3-Bromo-3-methyl-1,2-dimethylprop-1-ene
Which one of the following is an optically active?

The major product of the reaction given below is:
1344037_68180855a0ee49a486a1b0d8cfa41174.PNG
The major product obtained on the monobromination with Br2/FeBr3 :
1348039_1dbd8f511cb6490093d910b68a572837.GIF
Which is suitable reagent for Wurtz reaction?
  • Na/ether
  • Na/alcohol
  • Zn/ether
  • Zn/alcohol

Which of the following is most reactive toward AgNO3 or rate of SN1 reaction? 

Which of the following combinations is correctly matched?

What is the IUPAC name of the given compound?
1389642_0f689bad87114b728e0e115160ba357b.png
  • 1chloro cyclohex1ene
  • 2chloro cyclohex2ene
  • 3chloro cyclohex1ene
  • 4chloro cyclohex3ene
 +HBr Product :
1369387_6fc4a57e3ecc4ed39d16225141e53f20.png
Which of the following compounds will give yellow precipitate on shaking with aqueous solution of NaOH followed by the addition of AgNO3 solution?
Find the major product of the following reaction 
1393061_5fde0c52ee894093857df78375be685a.png
Among the following the compounds which can undergo an SN1 reaction in an aqueous solution, are: 
1688418_4e64c80bee37444caf93ec69808d0168.png
  • I and IV only
  • II and IV only
  • II and III only
  • II, III and IV only
CH3Br+NuCH3Nu+Br
The decreasing order of the rate of the above reaction with
nucleophile (Nu)Ato D is
[Nu:(A)PhO,(B)AcO,(C)HO,(D)CH3O]
  • D>C>A>B
  • D>C>B>A
  • A >B >C>D
  • B >D>C>A
SN1 mechanism for the hydrolysos of an alkyl halide involves the formation of intermediate:
  • Free radical
  • Carbocation
  • Carbanion
  • none of these
 1-Bromopropane and 2-bromopropane on treatment with sodium in presence of ether gives: 
  • n-hexane
  • 2,3-dimethylbutane
  • 2-methylpentane
  • a mixture of all these different alkanes '
Secondary butyl chloride on boiling with alcoholic potash gives: 
  • only 1- butene
  • only 2- butene
  • isobutylene
  • a mixture of 1-butene and 2- butene
Which of the following alkyl halide is hydrolysed by S1N mechanism? 
  • (CH3)3CX
  • CH3CH2X
  • CH3CH2CH2X
  • (CH3)2CHX
Which one of the following compounds is stable? 
  • CH3CH(OH)2
  • (CH3)2C(OH)2
  • CCl3CH(OH)2
  • None of these
Which of the following is optically active?
  • Butane
  • 4-Methyl heptane
  • 3-Methyl heptane
  • 2-Methyl heptane
Tert. butyl chloride preferably undergoes hydrolysis by: 
  • SN1 mechanism
  • SN2 mechanism
  • Any of (A) and (B)
  • None of these
Which of the following is liquid at room temperature?
  • CH_3I
  • CH_3Br
  • C_2H_5CI
  • CH_3F
Which of the following alkyl halides is hydrolysed by S_N 1 mechanism?
  • CH_3 Cl
  • CH_3 CH_2 Cl
  • CH_3 CH_2 CH_2 Cl
  • (CH_3)_3 CCl
The catalyst used in the preparation of an alkyl chloride by the action of dry HCl on alcohol is:
  • Anhydrous AlCl_3
  • FeCl_3
  • Anhydrous ZnCl_2
  • Cu
 Which of the following will be least reactive in nucleophilic substitution? 
  • CH_3CH_2CH_2Cl
  • (CH_3)_3 C-Cl
  • CH_3-CHClCH_3
  • H_2C =CHCH_2Cl
  • H_2C=CHCl
An ethereal solution of alkyl halide is heated with sodium metal. The reaction is known as: 
  • Frankland's reaction
  • Sandmeyer's reaction
  • Wurtz-Fittig reaction
  • Wurtz reaction
The hydrolysis of (CH_3)_3 C- Cl aqueous NaOH follows S_N1 mechanism.
  • True
  • False
(X) +KCN  \longrightarrow CH_3CN \quad  \xrightarrow {2H_2/Ni} CH_3CH_2NH_2 what is (X) ?
  • CH_3CH_2Cl
  • CH_3Cl
  • CH_3CH_2CH_2Cl
  • (CH_3)_2CHCl
Which of the following is the least reactive towards
nucleophile? 
  • CH_3CH_2Cl
  • CH_3Cl
  • H_2C=CH=CH_2Cl
  • C_6H_5Cl
  • CH_3CH(Cl)CH_3
Identify the correct order of reactivity in electrophilic substitution reaction of the following compounds.
1718044_0aa506ba3adf468797de565d9ad5ab86.PNG
  • I > II > III > IV
  • IV > III > II > I
  • II > I > III > IV
  • II > III > I > IV
Here P is / are:
1748017_15b21359ed2c4ff0a8635d810b244264.png
  • All of these
0:0:2


Answered Not Answered Not Visited Correct : 0 Incorrect : 0

Practice Class 12 Engineering Chemistry Quiz Questions and Answers