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CBSE Questions for Class 12 Engineering Chemistry Haloalkanes And Haloarenes Quiz 5 - MCQExams.com

In which of the following can CCl bond be easily broken?
  • Chlorobenzene
  • Vinyl chloride
  • Allyl chloride
  • p-Chlorotoluene
The reagents required for the following two-step transformation are?
790839_8a99c939280a4a9f837c60d8485ea0b0.jpg
  • (i) HBr, benzoyl peroxide, (ii) CH3CN
  • (i) HBr, (ii) NaCN
  • (i) Br2; (ii) NaCN
  • (ii) NaBr; (ii) NaCN
Which of the following is most reactive towards the SN1 reaction?
  • A and B reacts at similar rate
Which of the following reaction is used to increase the length of the carbon chain ?
  •  Clemmensen reduction
  • Wolff-Kishner Reduction
  • Wurtz reaction
  • Kolbe’s electrolysis
Which of the following is used in paint removing?
  • CHCl3
  • CH2Cl2
  • CCl4
  • CH3Cl
In chlorination of benzene in presence of FeCl3, function of FeCl3 is :
  • to provide halogen.
  • to form electrophile.
  • resonance stabilisation.
  •  act as a catalyst.
2C6H5Cl+2NaX
In the given reaction X is:
  • toulene
  • biphenyl
  • phenyl ethane
  • 1-chloro-2-phenyl ethane
What is the hybridisation of carbon that is attached to chlorine atom in n-primary alkyl halide?
  • sp3
  • sp2
  • sp
  • sp3d
CH3CH(Cl)CH2CH2CH3 and CH3CH2C(Cl)(CH3)CH3 are both positional and chain isomerism of each other.
  • True
  • False
The reagent used for dehydrohalogenation is ____________.
  • H2O2
  • K2SO4
  • alcoholic KOH
  • none of the above
Alkyl halide reacting with metallic sodium in dry ether solution is called:
  • Friedel-crafts reaction
  • Sandmeyer reaction
  • Wurtz reaction
  • Gabriels reaction
Which of following will give syn-elimination?
  • CH3CH2CH2OCOCH3
  • CH3CH2C|ClHCH3
  • CH3CH2CH2OC||SSCH3
The conversion (Image) Can be effected using
73370.jpg
  • Br2/CCl4
  • Br2/H2O
  • Br2/Fe
  • Br2/benzoylperoxide
IUPAC name of  (CH3)2CHCH2CH2Br  is:
  • 1-Bromopentane
  • 2-Methyl-4-bromobutane
  • 1-Bromo-3-methylbutane
  • 2-Methyl-3-bromobutane
The IUPAC name of the compound CH3CH(CH3)CH2CH2Cl is:
  • 1-chloro-3-methylbutane
  • 2-methyl-4-chlorobutane
  • 2-methyl-1-chlorobutane
  • 1-chloropentane
Which of the following undergoes nucleophilic substitution exclusively by SN1 mechanism?
  • ethyl chloride
  • isopropyl chloride
  • benzyl chloride
  • chlorobenzene
Nature of CX bond is:
  • ionic
  • covalent
  • co-ordinate
  • none of these
Bond order of CX bond is 1 because :
  • Cl achieve noble gas configuration by sharing one electron
  • C not able to form multiple bonds
  • Cl does not have vacant orbitals
  • C achieve noble gas configuration by sharing one electron
The main difference in C - X bond of a haloalkane and a haloarene is 
  • C - X bond in haloalkanes is shorter than haloarenes.
  • In haloalkanes the C attached to halogen in C - X bond is sp3 hybridised while in haloarenes it is sp2 hybridised.
  • C - X bond in haloarenes acquires a double bond character due to higher electronegativity of X than haloalkanes.
  • haloalkanes are less reactive than haloarenes due to difficulty in C - X cleavage in haloalkanes.
What is the correct IUPAC name for
1847553_2a345573c0e041f4b38cef1dbbb4bcf3.png
  • 1-Bromo-2-ethylpropane
  • 1-Bromo-2-ethyl-2-methylethane
  • 1-Bromo-2-methylbutane
  • 2-Methyl-1-bromobutane

Match the isomers given in column I with their names given in column II and mark the appropriate choice.
1847402_586aeae9c3fa489b97c68e8f54459554.PNG
  • (A)(iii),(B)(i),(C)(iv),(D)(ii)
  • (A)(iv),(B)(iii),(C)(ii),(D)(i)
  • (A)(i),(B)(ii),(C)(iii),(D)(iv)
  • (A)(ii),(B)(iii),(C)(iv),(D)(i)
Identify the products  X and Y formed in the following reaction:
CH3CH2CH=CHCH3+HClX+Y
In which of the following cases CC bond length will be the longest?
  • CH3CF3
  • FCH2CH2F
  • F2CHCHF2
  • CF3CF3
SN1SN2  product are same in (excluding stereoisomer):
  • PhC|HCH3C|HClCH3
The compound A is :
128354.png
  • none of the above
Choose all alkane that give only one monochloro derivative upon reaction with chlorine in sun light.
Which of the following sequences would yield m-nitro chlorobenzene (Z) from benzene?
  • Benzene Cl2/FeCl3(X)HNO3H2SO4(Z)
  • Benzene H2SO4/HNO3(Z)
  • Benzene H2SO4/HNO3(X)Cl2/FeCl3(Z)
  • All of these
Iso-propyl bromide on Wurtz reaction gives:
  • Hexane
  • Propane
  • 2, 3-dimethylbutane
  • Neo-hexane
2-phenylethylbromide when heated with NaOEt, elimination takes place. No deuterium exchange takes place when the reaction is carried out in C2H5OD solvent. The mechanism will be:
  • E1 elimination
  • E2 elimination
  • E1cB elimination
  • E2 or E1cB
Which one of the following undergoes nucleophilic substitution exclusively by SN1 mechanism? 
  • Benzyl chloride
  • Ethyl chloride
  • Chlorobenzene
  • Isopropyl chloride
On commercial scale, phenol is obtained from chlorobenzene. The chlorobenzene needed for the purpose is prepared by:
  • Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
  • Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
  • Assertion is correct but Reason is incorrect.
  • Both Assertion and Reason are incorrect.
Which of the following halides undergoes nucleophilic substitution most readily? 
  • pH3CC6H4Cl
  • OMeOC6H4Cl
  • pClC6H4Cl
  • C6H5CH(Cl)CH3
Isopropyl bromide on Wurtz reaction gives:
  • hexane
  • propane
  • 2,3-dimethyl butane
  • neo-hexane
Which is the correct increasing order of electronegativity of halides?
  • F,Cl,Br,I
  • I,Br,Cl,F
  • Br,Cl,F,I
  • Cl,Br,I,F
Which of the following is used for metal cleaning and finishing?
  • CHCl3
  • CHI3
  • CH2Cl2
  • C6H6
C6H13Br+OHC6H13OH+Br is an example of:
  • Nucleophilic addition
  • Nucleophilic substitution
  • Electrophilic addition
  • Electrophilic substitution
  • Free radical substitution
The IUPAC name of haloalkane is always written as a ______ word. 
  • single
  • double
  • triple
  • none of these
Heating many alkyl chlorides or bromides in water effects their conversion into alcohol through a SN1 reaction. Order each of the following sets of compounds with respect to solvolytic reactivity.
127989.png
  • i>ii>iii
  • ii>i>iii
  • iii>ii>i
  • iii>i>ii
The ability of rotation of plane polarized light either towards right or left is called as:
  • optical activity
  • chirality
  • superimposibility
  • non superimposibility
Which of the following haloalkanes is most reactive?
  • 1-chloropropane
  • 1-bromopropane
  • 2-chloropropane
  • 2-bromopropane
In the dehydrohalogenation of ethyl chloride, which of the following change occurs?
  • sp2 carbon converts to sp3 carbon
  • sp2 carbon converts to sp carbon
  • sp3 carbon converts to sp carbon
  • sp3 carbon converts to sp2 carbon
Consider the following anions.

When attached to sp3hybridized carbon, their leaving group ability in nucleophilic substitution reaction decreases in the order :
989659_bf5196f5041e4a80b94e5c4555167660.png
  • I>II>III>IV
  • I>II>IV>III
  • IV>I>II>III
  • IV>III>II>I
Product (B) is :
989614_903f5bc51bd041278c09a1459d6acddb.png
  • None of these
Arrange the following alkyl halides in decreasing order of the rate of β-elimination reaction with  alcoholic KOH.

CH3CH2CH2Br(i)   CH3CHCH2Br | CH3(ii) CH3CH2CHCH3|Br(iii)
  • (ii)>(iii)>(i)
  • (iii)>(i)>(ii)
  • (i)>(ii)>(iii)
  • (ii)>(i)>(i)
Ortho and para hydrogen differ in 
  • atomic number
  • mass number
  • electron spin in two atoms
  • nuclear spin of two atoms
Follows
1265393_ad08b9a02e71437b80e828f04d96db85.png
  • E2 mechanism
  • ϵ1 mechanism
  • S1N mechanism
  • S2N mechanism
Select whether the following combinations of reactants will react by substitution (SN1orSN2 mechanism), elimination (E1orE2 mechanism).
(CH3)3COHHBr48%inH2O250C
  • SN1
  • SN2
  • E1
  • E2
SN1 characteristic would be exhibited in the hydrolysis of;
  • Chlorobenzene
  • 1-chloronapthalene
  • propenyl chloride
  • 2-chloro-1-propene
Which of the following is an example of alkyl halide?
  • pchlorotoluene
  • Chloro methane
  • Allyl chloride
  • Benzyl chloride
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