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CBSE Questions for Class 12 Engineering Chemistry Haloalkanes And Haloarenes Quiz 8 - MCQExams.com

Which is the correct increasing order of bond dissociation enthalpy of CX bond?
  • CF,CCl,CBr,CI
  • CI,CF,CCl,CBr
  • CCl,CF,CBr,CI
  • CI,CBr,CCl,CF
CH3CH2BrAlco.KOHΔBHBrCNa/etherD the compound D is
  • ethane
  • propane
  • n-butane
  • n-pentane
The reaction of 1bromo3chlorocyclobutane with metallic sodium in dioxane gives:
Which of the following is allylic halide?
  • (1-Bromoethyl) benzene
  • Benzyl chloride
  • 1-Bromo benzene
  • 3-Chloro cyclohex-1-ene
Which of the following cycloalkane gives open chain compound when it reacts with bromine?
  • Cyclopropane
  • Cyclopentane
  • Cyclohexane
  • Cyclo-octane
C6H6+Cl2(excess)Anhy.Alcl3dark,coldP
Product, P is:
  • C6H5Cl
  • C6H4Cl2
  • C6H6Cl6
  • C6Cl6
Which of the following is the correct order for strength of CX bond ?
  • CH3F<CH3Cl<CH3Br<CH3I
  • CH3F>CH3Cl>CH3Br>CH3I
  • CH3I>CH3F>CH3Cl>CH3Br
  • CH3Cl>CH3Br>CH3F>CH3I
On mixing alkane with chlorine and irradiating with ultraviolet light, it forms only one monochloro alkane. The alkane is: 
  • propane
  • pentane
  • isopentane
  • neopentane
Which of the following cannot undergo E2 reaction?
  • None of these
The correct order of reactivity of the halides,
(I) ethyl chloride; (II) isopropyl chloride and (III) benzyl chloride in SN1 reaction is:
  • I>II>III
  • III>II>I
  • II>I>III
  • I>III>II

The products formed in the reaction is(are):

  • ethane, propane
  • butane
  • phrpane
  • ethane, propane, butane
The major product is:
691605_f513af273aea4c5193c6672e00c42b4b.png
The treatment of R3MgX with ethyl formate leads to the formation of:
  • RCHO
  • CH3CH2OR
  • RCHOHC2H5
  • C2H5OH
The compound 
C7H83Cl2/XBr2/FeYZn/HClZ
The compound Z is :
  • m-bromotoluene
  • p-bromotoluene
  • o-bromotoluene
  • 2, 4, 6-trichlorotoluene
.
712220_5bc04504a8f541c08d87ab98325328f3.png
Arrange the following alkyl chlorides in order of decreasing reactivity in a SN1 reaction.
(I) isopropyl bromide 
(II) propyl bromide
(III) tert-butyl bromide
(IV) methyl bromide 
  • (III) > (I) > (II) > (IV)
  • (I) > (III) > (IV) > (II)
  • (IV) > (III) > (II) > (I)
  • (I) > (II) > (III) > (IV)
The best yield of given product can be obtained by using which set of reactants X and Y respectively
789203_704744daf5fa414581a0723f9de84ca5.PNG
  • PhLi+ Neopentyl chloride
  • PhMgBr+ Neopentyl bromide
  • tBu+MgBr+ Benzyl bromide
  • Benzylchloride+ t-Butyl chloride
CH3.CH2OCH3|CH.CH2.CH2CH2Cl
The correct IUPAC name of the given compound is:
  • 2-ethoxy-5-chloropentane
  • 1-chloro-4-ethoxy-4-methylbutane
  • 1-chloro-4-ethoxypentane
  • ethyl-1-chloropentylether
The product formed in the reaction is:
758884_b0344af8561d4c70a2ea120cd9721e88.png
  • (BrCH2)3CCH2CH2C(CH2Br)3
Which of the following will be most reactive for SN1 reaction?
  • (CH3)3CCl
  • (CH3)2CHCl
  • (CH3)2NCH2Cl
  • (CH3)3CBr
Which does not have conjugate system?
  • CH2=CHCl
  • CH2=CHCHO
  • CH3CH=CH2
During the course of an SN1 reaction, the intermediate species formed is:
  • a carbocation
  • a free radical
  • a carbanion
  • an intermediate complex
Which one of the following is best catalyst for the reaction shown below ?
CH3(CH2)8CH2BrKCNbenzeneCH3(CH2)8CH2CN
Which of the following compounds is optically active?
Among the following, the optically inactive compound is :
Specific rotation is the rotation produced by 1g of material in 1ml of liquid in a 1 dm tube. Which of the following molecules have largest value of specific rotation? (Hint : Molecular mass increasing).
The IUPAC name of (CH3)2CHCH2CH2Br is ?
  • 1-bromopentane
  • 1-bromo-3-methylbutane
  • 2-methyl-4-bromobutane
  • 2-methyl-3-bromopropane
Arrange the following alkyl halides in decreasing order of the rate of β- elimination reaction with alcoholic KOH.
CH3CH2CH2BrCH3CH|CH3CH2BrCH3CH2CH|BrCH3
(i)                                                   (ii)                                                     (iii)
  • (ii)>(iii)>(i)
  • (iii)>(ii)>(i)
  • (i)>(ii)>(iii)
  • (ii)>(i)>(iii)
The IUPAC name of tertiary butyl chloride is ?
  • 2-chloro-2-methylpropane
  • 3-chlorobutane
  • 4-chlorobutane
  • 1, 2-chloro-3-methylpropane.
The reaction of Sodium methoxide with {R}_{2}CHX is:
  • {SN}^{1}
  • {SN}^{2}
  • Elimination
  • Substitution
The reaction proceeds with 98% racemisation. The reaction may follow:

937569_100101ae2bd245f9b37b28b9f627b43c.PNG
  • S_N1 mechanism
  • S_N2 mechanism
  • E1 mechanism
  • E2 mechanism
Choose the correct answer among the alternatives given :Bromination of methane in presence of sunlight is a:
  • nucleophilic substitution
  • free radical substitution
  • electrophilic substitution
  • nucleophilic addition
Which of the following is not correctly matched with its IUPAC name?
  • CHF_2CBrClF : 1-Bromo-1-chloro-1, 2, 2 -trifluoroethane
  • (CCl_3)_3CCl : 2-(Trichloromethyl)-1,1,1,2,3,3, 3 -heptachioropropane
  • CH_3C(p-ClC_6H_4)_2CH(Br)CH_3 : 2-Bromo-3,3-bis(4-chlorophenyl) butane
  • o-BrC_6H_4CH(CH_3)CH_2CH_3 : 2-Bromo-1-methylpropylbenzene
Choose the correct option from the following:
  • In the electrophilic substitution of toluene with Br_2, iron (III) bromide acts as a Lewis acid.
  • In the reaction of toluene with Cl_2/FeCl_3, ortho and para isomers are easily separated.
  • Similar reaction with iodine is reversible in nature
  • All of these
A compound X with molecular formula C_7H_8 is treated with Cl_2 in presence of FeCl_3. Which of the following compounds are formed during the reaction?
Which of the following is the most reactive towards nucleophilic substitution reaction?
  • ClCH_2-CH=CH_2
  • CH_2=CH-Cl
  • CH_3CH=CH-Cl
  • C_6H_5Cl
The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ________.
  • mixture of (b) and (c)

Choose the correct answer among the alternatives given :

In the following pairs of halogen compounds , which compound undergoes faster S_N1 reaction?

937599_6c8a0fded3b14c4f8a4a7346f61ea0ba.png
Reaction of C_6H_5CH_2Br with aqueous sodium hydroxide follows ___________.
  • S_N1 mechanism
  • S_N2 mechanism
  • Any of the above two depending upon the temperature of reaction
  • Saytzeff rule
Chlorobenzene is formed by reaction of chlorine with benzene in the presence of A1C1_3.Which of the following species attacks the benzene ring in this reaction?
  • C1^-
  • Cl^+
  • AlCl_3
  • [AlCl_4]^-
Which is the correct IUPAC name for,

CH_3-{\underset{C_2H_5}{\underset{|}{CH}}}-CH_2-Br:
  • 1-Bromo-2-ethylpropane.
  • 1-Bromo-2-ethyl-2-methylethane.
  • 1-Bromo-2-methylbutane.
  • 2-Methyl-1-bromobutane.
For the given Question (1,2,3)  consider the following reaction.
Which halogen will give the best yield of a single monohalogenation product ?
988826_7e2fbd3531ee403d881feb5b49d95d2c.PNG
  • F_2
  • Cl_2
  • Br_2
  • I_2
Chloromethane  on treatment with excess of ammonia yields mainly :
  • N, N-dimethylmethanamine
  • N-methylmethanamine (CH_3-NH-CH_3)
  • methanamine (CH_3NH_2)
  • mixture containing all these in equal proportion.
Alkyl halides react with metallic sodium in dry ether producing?
  • Alkanes with same number of carbon atoms
  • Alkanes with double number of carbon atoms
  • Alkenes with triple number of carbon atom
  • Alkenes with same number of carbon atom
What should be the correct IUPAC name for diethylbromomethane?
  • 1 - Bromo- 1, 1 - diethylmethane
  • 3 - Bromopentane
  • 1 - Bromo-1 - ethylpropane
  • 1 - Bromopentane
Which of the following reactants is suitable for preparation of methane and ethane by using one step only?
  • H_2C = CH_2
  • CH_3OH
  • CH_3-Br
  • CH_3-CH_2-OH
Additional of Br_2 to trans-2- butene would give a product which is :
  • achiral
  • racemic
  • meso
  • optically active
Rank in the order of increasing acidic strength:
989427_63e1775a91b94959b8f7da8cb92ff238.PNG
  • A < B < C
  • A < C < B
  • B < A < C
  • B < C < A
Match the column I with column II and with column III.
988890_4811ec6132474d26a6c57f63f624ea98.png
  • a - q - w; b - s - x; c - p - y; d - q - z
  • a - b - x; q - s - z; c - p - w; d - q - x
  • a - q - x; b - s - z; c - p - w; d - q - x
  • a - s - x; b - p - z; c - q - w; d - q - x
\underrightarrow{AgNO_3} (A);
Which statement is incorrect in respect of the above reaction?
988889_5567135824f14c8dbace5e70f2f5c647.PNG
  • Product is aromatic
  • product has high dipole moment
  • Product has less resonance energy
  • Product is soluble in polar-solvent
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