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CBSE Questions for Class 12 Engineering Chemistry The D-And F-Block Elements Quiz 10 - MCQExams.com

Among dblock elements, the most abundant element belongs to :
  • first transition series
  • second transition series
  • third transition series
  • fourth transition series
The correct order of ionic radii of Ce,La,Pm and Yb in +3 oxidation state is:
  • La3+<Pm3+<Ce3+<Yb3+
  • La3+<Ce3+<Pm3+<Yb3+
  • Yb3+<Ce3+<Pm3+<La3+
  • Yb3+<Pm3+<Ce3+<La3+
Transition metals are often paramagnetic owing to 
  • Their high M.P. and B.P
  • The presence of vacant orbitals
  • The presence of one or more unpaired electrons in the system
  • Their being less electropositive than the elements of groups I-A and II-A
Transition elements are coloured
  • Due to small size
  • Due to metallic nature
  • Due to unpaired d - electrons
  • All of these
Which of the following is not the characteristic of transition metals?
  • They are all metals
  • They show variable oxidation states which always differ by two units
  • They are paramagnetic
  • They easily form complex
The property which is not characteristic of transition metals, is: 
  • variable oxidation state
  • tendency to form complex
  • formation of coloured compounds
  • natural radioactivity
The radius of La3+ (atomic number of La=57) is 1.06˚A which one of the following given values will be closest to the radius of Lu3+ (atomic number of Lu=71)?
  • 1.40˚A
  • 1.06˚A
  • 0.85˚A
  • 1.60˚A
Ammonia solution dissolves fairly:
  • Hg2Cl2
  • PbCl2
  • AgI
  • Cu(OH)2
Which one of the following ions is diamagnetic?
  • Cr2+
  • V2+
  • Sc3+
  • Ti3+
Which one of the following complexes is diamagnetic in nature?
  • [Cr(NH3)6]3+
  • [FeF6]3
  • [Co(NH3)6]3+
  • [Fe(H2O)6]2+
A metal ion from the first transition has a magnetic moment (calculated) of 3.87 B.M. How many unpaired electrons are expected to be present in the ion?
  • 1
  • 2
  • 3
  • 4
Verdigris is:
  • basic copper acetate
  • basic lead acetate
  • basic lead
  • none
When excess of SnCl2 is added to a solution of HgCl2, a white precipitate turning to grey is obtained. The grey colour is due to the formation of:
  • Hg2Cl2
  • SnCl4
  • Sn
  • Hg
Which one of the following is paramagnetic in nature ?
  • Ni(CO)4
  • [Ni(CN)4]2
  • [NiCl4]2
  • [Co(NH3)6]3+
The colour of zinc sulphide is:
  • yellow
  • white
  • brown
  • black
Which of the following pairs of ions have same paramagnetic moment?
  • Mn2+,Cu2+
  • Cu2+,Ti3+
  • Ti4+,Cu2+
  • Ti3+,Ni2+
The radius of La3+ is 1.06 oA, which of the following given values will be closest to the radius of Lu3+ (At. no of Lu=71,La=57)?
  • 1.6 Ao
  • 1.4 Ao
  • 1.06 Ao
  • 0.85 Ao
Among d block elements, the most abundant element belongs to the:
  • first transition series
  • second transition series
  • third transition series
  • fourth transition series
Which one of the following ion has a magnetic moment of 5.93 B.M ?
  • Mn2+
  • Fe2+
  • Cr2+
  • V3+
  • Cr3+
Which has maximum paramagnetic character ?
  • [Fe(CN)6]4
  • [Cu(H2O)4]2+
  • [Cu(NH3)4]2+
  • [Mn(H2O)6]2+
Which of the following is not correct?
  • [Fe(CN)6]3 is weakly paramagnetic
  • [Fe(CN)6]4 is strongly paramagnetic
  • [Ni(CN)4]2 is diamagnetic
  • [NiCl4]2 is paramagnetic
Which group contains coloured ions out of
Cu+ Ti4+ Co2+ Fe2+
  • 1,2,3,4
  • 3,4
  • 2,3
  • 1,2
Which of the following pairs of transition metal ions are the stronger oxidising agents in aqueous solution?
  • V2+ and Cr2+
  • Ti2+ and Cr2+
  • Mn3+ and Co3+
  • V2+ and Fe2+
  • Ni2+ and Fe2+
Which of the following statements is wrong  for the transition elements ? 
  • Transition elements are placed from 3rd to 6th period
  • Last electron enters in (n-1) d orbital
  • Exhibits variable valency
  • General electronic configuration is (n-1) d110 ns02
Predict the magnetic nature of A and B.
  • both are diamagnetic
  • A is diamagnetic and B is paramagnetic with one unpaired electrons
  • A is diamagnetic and B is paramagnetic with two unpaired electrons
  • both are paramagnetic
The complex forming tendency of a transition metal depends upon:
  • Availability of a number of vacant d orbitals
  • high ionisation energy
  • small size of cation or high charge density
  • variable oxidation states
The correct order of magnetic moments amongst following complex ions is:
  • [MnCl4]2>[Fe(CN)6]4>[CoCl4]2
  • [Fe(CN)6]4>[MnCl4]2>[CoCl4]2
  • [MnCl4]2>[CoCl4]2>[Fe(CN)6]4
  • [Fe(CN)6]4>[CoCl4]2>[MnCl4]2
In the long form of periodic table, all the non-metals and metalloids are placed with :
  • s-block
  • p-block
  • d-block
  • f-block
Which one of the following complexes is not diamagnetic?
  • [Fe(CN)6]4
  • [Ti(H2O)6]3+
  • [Pt(CN)4]2
  • [Co(NH3)6]3+
The correct increasing order of paramagnetism of
(i) MnSO4.4H2O
(ii) FeSO4.7H2O
(iii) NiSO4.6H2O
(iv) CuSO4.5H2O is:
  • (i)<(ii)<(iii)<(iv)
  • (iv)<(iii)<(i)<(i)
  • (iii)<(iv)<(ii)<(i)
  • (iii)<(iv)<(i)<(ii)
Transition metals form complexes because of:
  • small cation size
  • vacant d orbitals
  • large iconic charge
  • all of these
The ionic radius of 57La3+ is 1.06 oA Which one the  following give values will be closest to the ionic radius  of 71Lu3+ ?
  • 1.06 oA
  • 1.56 oA
  • 0.85 oA
  • 1.35 oA
Which ine of the following statement about lanthanides is false?
  • Lanthanides are sepearated from one another by ion exchange method
  • The ionic radii of trivalent lanthanides steadily increases with increase in atomic number
  • All lanthanides are highly dense metals
  • Most typical oxidation state of lanthanides is +3
The ions from among the following which are colourless are 
(i) Ti4+   (ii) Cu+   (iii) Co3+    (iv) Fe2+
  • i and ii only
  • i, ii and iii
  • iii and iv
  • ii and iii
Which of the following function as catalysts for oxidation of SO2 to SO3 in industrial process for production of H2SO4?
  • TiO2
  • PbO2
  • Pt
  • V2O5
Among the following, the species that is both paramagnetic and coloured is : 
  • [MnO4]2
  • [TiCl6]2
  • [VO4]2
  • CrO2Cl2
Which ionic radius of 57La3+ is 1.06A. which one of the following values will be closest to ionic radius of 71Lu3+. ?
  • 1.06A
  • 1.56A
  • 0.85A
  • 1.35A
Out of all the known elements, the percentage of transitional elements is approximately  
  • 30% 
  • 50% 
  • 60% 
  • 75% 
Atomic number of Cr and Fe are 24 and 26 respectively. Which of the following is paramagnetic with the spin of electron?
  • [Cr(NH3)6]3+
  • [Fe(CO)5]
  • [Fe(CN)6]4
  • [Cr(CO)6]
Which of the following pair of elements cannot form an alloy ?
  • ZnHg
  • FeHg
  • HgCr
  • NaHg
Iron loses magnetic property at 
  • Melting point
  • 1000K
  • Curie point
  • Boiling point
The term platforming is 
  • Platinum painting
  • Flat sheet of platinum
  • Platinum manufacturing
  • Platinum used as a catalyst
Arrange Ce3+,La3+,Pm3+ and Yb3+ in increasing order of their ionic radii
  • Yb3+<Pm3+<Ce3+<La3+
  • Ce3+<Yb3+<Pm3+<La3+
  • Yb3+<Pm3+<La3+<Ce3+
  • Pm3+<La3+<Ce3+<Yb3+
Colour of cobalt chloride solution is
  • pink
  • black
  • colourless
  • green
Which of the following statement(s) is(are) correct with reference to the ferrous and ferric ions?
  • Fe3+gives brown colour with potassium ferricyanide
  • Fe2+ gives blue precipitate with potassium ferricyanide
  • Fe3+gives red colour with potassium thiocyanate
  • Fe2+ gives brown colour with ammonium thiocyanate
Alizarin gives a red colour by mordanting it with the sulphate of a metal. The metal ion involved is 
  • Cr3+
  • Fe3+
  • Al3+
  • Sn2+
If CdI2 is pink in colour, the CdCl2 will be  '________' coloured.
  • yellow
  • red
  • blue
  • cannot be predicted
Which metal absorbs hydrogen?
  • Al
  • Fe
  • Pd
  • K
In the dichromate anion (Cr2O27),
  • all CrO bonds are equivalent
  • 6CrO bonds are equivalent
  • 3CrO bonds are equivalent
  • no bonds in Cr2O27 are equivalent.
Which of the following statements is wrong?
  • Ti4+ and Ag+ are repelled by magnetic field
  • Mn2+ shows maximum magnetic character among the first transition series.
  • Fe2+ is more stable than Mn2+ towards oxidation to +3 state.
  • Cr in Cr2O27 ion involves sp3d2 hybridisation
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