Explanation
Moles of N2=28028=10moles
Assume, moles of CO2=x.
So, average molecular mass of mixture =10×28+x×4410+x =36 (given)
So, x=10 moles
Therefore, weight of CO2=10×44=440 g
Assume mole % of NO2=x
Then, mole % of NO=100−x
So, avg. atomic mass of mixture =x×46+(100−x)×30100 =34 (given)
Hence, x=25 %
We know that 12 g of Carbon=6.023× 1023atoms
So 1 g=6.023 X 102312
6 g of carbon=6×6.023 X 102312
or
=12×6.023 ×1023
This is our new Avogadro's number according to the given conditions.
Or
1 atomic mass unit=1NA=26.023 X 1023
Mass of 1 mole of O2=32× Avogrado′s number×26.023 ×1023
=32×6.023 ×10232×26.023 ×1023
=32g
Hence, there is no change in the mass number of O2.
Option C is correct.
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