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CBSE Questions for Class 11 Medical Chemistry Chemical Bonding And Molecular Structure Quiz 10 - MCQExams.com

The relatively high boiling point of HF is due to 
  • Hydrogen bonding
  • Covalent bonding
  • Unshared electron pair on F
  • Being a halogen acid
The enolic form of acetone contains:
  • 9 sigma bonds, 1 pi bond and 2 lone pairs
  • 8 sigma bonds, 2 pi bond and 2 lone pairs
  • 10 sigma bonds, 1 pi bond and 1 lone pair
  • 9 sigma bonds, 2 pi bond and 1 lone pair
Which of the following option is correctly matched
  • S3O9 : contains no S-S linkage
  • S2O26 ; contains -O-O-linkage
  • (HPO3)3; contains P-P linkage
  • S2O28 ; contains S-S linkage
Water has high heat of vaporisation due to:
  • Covalent bonding
  • H-bonding
  • Ionic bonding
  • None of the above
Which contains strongest H-bond?
  • OH...S
  • SH...O
  • FH...F
  • FH...O
On the following hydrides which has the lowest boiling point?
  • NH3
  • PH3
  • SbH3
  • AsH3
In which of the following compounds does hydrogen bonding occur?
  • SiH4
  • LiH
  • HI
  • NH3
which of the following statements is false
  • H2PO2, H3PO3,H3PO4 all are tribasic and reducing in nature
  • Among anions, NO3, SO23,SO24,S2O24,H2SO4 , SO23 is basic reducing nature
  • Number of anions SO23,SO24, SO24, and H2SO4,SO23
  • Number of lone pair(s) electrons on Xe atoms in XeF2,XeF4,XeF6 are 3,2,and 1 respectively.
An electrically charged atom or a group of atoms is known as:
  • A meson
  • A proton
  • An ion
  • A cyclotron
Which of the following is not correct
  • A sigma bond is weaker than π bond
  • A sigma bond is stronger than π bond
  • A double bond is stronger than a single bond
  • A double bond is shorter than a single bond
The bond angle of water is 104.5 due to 
  • Repulsion between lone pair and bond pair
  • sp3 hybridization of O
  • Bonding of H2O
  • Higher electronegativity of O
In the sigma bond
  • Sidewise as well as end to end overlap of orbitals take place
  • Sidewise overlap of orbitals take place
  • End to end overlap of orbitals takes place
  • None of the above
In N2 molecule, the atoms are bonded by:
  • One σ and Two π
  • One σ and one π
  • Twoσ and oneπ
  • Three σ bonds.
The number and type of bonds between two carbon atoms in calcium carbide are:
  • One sigma, one pi
  • One sigma, two pi
  • Two sigma, one pi
  • Two sigma, Two pi
The covalency of nitrogen in HNO3 is:
  • 0
  • 3
  • 4
  • 5
Which can be described as a molecule with residual bonding capacity
  • BeCl2
  • NaCl
  • CH4
  • N2
The double bond between the two carbon atoms in ethylene consists of
  • Two sigma bonds at right angles to each other
  • One sigma bond and one pi bond
  • Two pi bonds at right angles to each other
  • Two pi bonds at an angle of 60 to each other
Toluene has 
  • 6σ and 3π bond
  • 9σ and 3π bond
  • 9σ and 6π bond
  • 15σ and 3π bond
Which compound has zero dipole moment?
The number of σ bonds in o-xylene is 
  • 6
  • 9
  • 12
  • 18
In which one of the following changes there are transfer of five electrons
  • MnO4Mn2+
  • CrO24Cr3+
  • MnO24MnO2
  • Cr2O272Cr3+
The type of bonding in HCl molecule is 
  • pure covalent
  • polar covalent
  • highly covalent
  • H bonding
Peroxide bond is present in
  • MgO
  • CaO
  • Li2O
  • BaO2
The number of π bonds in 3-hexyne-1-ene is 
  • 1
  • 2
  • 3
  • 4
Acetylene molecules contain 
  • 5σ bond
  • 4σ bond and 1π bond
  • 3σ and 2π
  • 3σ and 3π
In PO34 ion the formal charge on the oxygen atom of PO bond is
  • +1
  • 1
  • 0.75
  • +0.75
The enolic form of acetone contains 
  • 8σ bonds, 2π bonds and 1 lone pairs
  • 9σ bonds, 1π bonds and 2 lone pairs
  • 9σ bonds, 2π bonds and 1 lone pairs
  • 10σ bonds, 1π bonds and 1 lone pairs
In which of the following combination hybridisation of central atom (*) does not change ?
  • H2O+CO2
  • H3BO3+OH
  • BF3+NH3
  • None of these
Number of S - S bond is H2SnO6 :
  • n
  • (n - 1)
  • (n - 2)
  • (n + 1)
A : tetracyanomethane
B : carbondioxide
C : benzene
D : 1, 3-butadiene
Ratio of σ and π bonds is in order : 
  • A = B < C < D
  • A = B < D < C
  • A = B = C= D
  • C < D < A < B
In which of the following cases C-C bond length will be highest?
  • CH3CF3
  • FCH2CH2F
  • F2CHCHF2
  • CF3CF3
A diatomic molecule has a dipole moment of 1.2 D. If the bond length is 1.0×108 cm, what fraction of charge does exist each atom?
  • 0.1
  • 0.2
  • 0.25
  • 0.3
Correct statement(s) about dipole moment of R3NO and R3PO is/are :
  • dipole moment of R3NO > dipole moment of R3PO
  • dipole moment of R3NO < dipole moment of R3PO
  • Experimental dipole moment of R3PO > theoretical dipole moment of R3PO
  • Experimental dipole moment of R3PO < theoretical dipole moment of R3PO
Which of the following statements is incorrect for sigma and π - bonds formed between two carbon atoms?
  • Sigma - bond is stronger than a π- bond
  • Bond energies of sigma and π- bonds are of the order of 264 kJ/mol and 347 kJ/mol
  • Free rotation of surrounding atoms about a sigma-bond is allowed but not in case of a π- bond
  • Sigma- bond determines the direction between carbon atoms but a π- bond has no primary effect in this regard
How many lone pairs of electrons are in resonance of the given compound?
73017.PNG
  • 4
  • 2
  • 3
  • 6
Which of the following compounds has zero dipole moment?
The total number of lone pairs in chlorate ion is:
  • 8
  • 4
  • 6
  • 2
Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false :
(i) The order of the repulsion between different pair of electrons is lplp>lpbp>bpbp
(ii) In general, as the number of lone pair of electrons on central atom increases, value of bond angle from normal bond angle also increases
(iii) The number of lone pair on O in H2O is 2 while on N in NH3 is 1 
(iv) The structures of xenon fluorides and xenon oxyfluorides could not be explained on the basis of VSEPR theory 
  • TTTF
  • TFTF
  • TFTT
  • TFFF
Which of the following molecular species is/are having π2p as H.O.M.O. (highest occupied molecular orbital):
  • N2
  • O2+2
  • NO+
  • B+2
Select correct statements regarding σ and π-bonds :
  • σ-bond lies on the line joining the nuclei of bonded atoms
  • π-electron cloud lies on either side to the line joining the nuclei of bonded atoms
  • (2pπ3dπ) Pi-bond is stronger than (2pπ3pπ) Pi-bond
  • σ-bond has primary effect to decide direction of covalent bond, which π-bond has no primary effect in direction of bond.
How many sigma bonds are present in a molecule of diethyl either C2H5OC2H5 ?
  • 14
  • 12
  • 8
  • 16
Which of the following molecules has as OO bond?
  • H2S2O8
  • H2S2O7
  • H2SO5
  • H2S2O6
Which of the following has no lone pair of electrons?
  • NO
  • CO
  • NH3
  • O2
How many sigma and pi bonds are present in toluene ?
  • 10σ and 3π bonds
  • 12σ and 3π bonds
  • 15σ and 3π bonds
  • 6σ and 3π bonds
State true or false:
The term chemical bond does not express the existence of strong forces of attraction between the atoms.
  • True
  • False
In NO3 ion, number of bond pair and lone pair of electrons on nitrogen atom are :
  • 2,2
  • 3,2
  • 1,3
  • 4,0
The number of sp2sp2σ bond in given compound is:
73030.PNG
  • 4
  • 5
  • 3
  • 6
The molecule in which an atom is associated with more than 8es is known as hypervalent molecule. All hypervalent molecules must have dπpπ  bonding but the molecule having back bonding need not have always dπpπ bonding.

Which of the following molecule is not having dπpπ bonding?
  • SO2
  • P4O10
  • H2O
  • B3N3H6
The ratio of number of lone pairs in the central atoms of NH3, H2O and XeF2 is:
  • 3:2:1
  • 2:1:3
  • 1:2:3
  • 2:3:1
In the analysis of an organic compound, it was found that it contains 7 carbon atoms, there are two C = C bonds and one CC bond. This compound is a hydrocarbon. Hydrocarbons have only carbon and hydrogen elements. On structural analysis it was found that it is covalent in nature and expected structure is given above. The ratio between the pure and hybrid orbitals is?

25634_710955a49cc441a68370bc918dcbf84c.png
  • 7:10
  • 8:7
  • 5:9
  • 1:2
0:0:2


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