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CBSE Questions for Class 11 Medical Chemistry Chemical Bonding And Molecular Structure Quiz 6 - MCQExams.com

The bond length in CO is 1.128˙A. What will be the bond length of CO in Fe(CO)5?
  • 1.158˙A
  • 1.128˙A
  • 1.078˙A
  • 1.118˙A
Which of the following compound has zero dipole moment?
  • 1,1 Dichloro ethylene
  • Cis1,2 dichoroethylene
  • Trans1,2dichoroethylene
  • Both 2 and 3
Order of the bond strength of CH bonds involving sp, sp2 and sp3 hybridized carbon atoms is:
  • sp>sp2>sp3
  • sp3>sp2>sp
  • sp2>sp3>sp
  • sp2>sp>sp3
The magnetic moment of a complex ion is 2.83BM. The complex ion is
  • [V(H2O)6]3+
  • [Cr(H2O)6]3+
  • [Cu(CN)4]2
  • [MnCl4]2
Which has maximum dipole moment?
Which of the following does not contain co-ordinate bond?
  • +PH4
  • NO2
  • O3
  • CO23
Which of the following has zero dipole moment?
1044126_17a9bc3ae77740388d7fa67991f763c4.png
  • I & II
  • II & III
  • II & IV
  • III & IV
In covalency:
  • Electrons are transferred
  • Electrons are equally shared
  • The electron of one atom are shared between two atoms
  • None of the above
Which among the following have zero dipole moment?
  • cis-C2H2Cl2
  • trans-C2H2Cl2
  • PCl3
  • 2Pentene
The molecule which has zero dipole moment is:
  • CH2Cl2
  • BF3
  • NF3
  • ClO2
Which of the following molecule is having shortest bond length of CO bond?
  • CH3OH
  • H2CO
  • CO
  • Na2CO3
The correct order of CN bond length in the given compounds is :
P:CH3CNQ:HNCOR:CH3CONH2
  • P>Q>R
  • P=Q=R
  • R>Q>P
  • R>P>Q
Among KO2,AIO2,BaO2 and NO+2, unpaired electron is present in :
  • NO+2andBaO2
  • KO2andAIO2
  • KO2 only
  • BaO2 only
Which of the following molecules has dipole moment greater than zero?
  • 3-3-Diethylpentane
  • trans-2-pentene
  • 2,2,3,3-tetramethyl butane
  • Neopentane
Among the alkaline earth metals, the element forming predominantly covalent compound is :
  • Be
  • Mg
  • Sr
  • Ca
Which statement is correct :-
  • All the compounds having polar bonds, have dipole moment
  • SO2 is non-polar
  • H2O molecule is non polar, having polar bonds
  • PH3 is polar molecule having non polar bonds
Which of the following is the strongest bond?
  • NaCl
  • CsCl
  • Both (A) and (B)
  • None of these
Which of the following compounds has dipole moment approximately equal to that of chlorobenzene?
  • o-dichlorobenzene
  • m-dichlorobenzene
  • p-dichlorobenzene
  • p-chloronitrobenzene
Which of the following pair of molecules posses have permanent dipole moment?
  • NO2andCO2
  • NO2andO3
  • SiF4andCO2
  • SiF4andNO2
Number of σ and π bonds in C2 molecule is/are:
  • 1σ and 1π
  • 1σ and 2π
  • 2π only
  • 1σ and 3π
Select correct statement (s) regarding σ and πbonds.
  • σ bond lies on the line joining the nuclei of bonded atoms
  • π electron cloud lies on either side to the line joining the nuclei of bonded atoms
  • (2pπ3dπ) pi-bond is stronger than (2pπ3dπ) pi-bond.
  • σbond has primary effect of decide direction of covalent bond, while πbond has no primary effect in direction of bond
Arrange the compounds in decreasing order of their dipole moment.
1068602_1fd42aedbd2d470690ec3ae43e0e79e1.PNG
  • IV> III> I> II
  • IV> I> III> II
  • I> III> IV> II
  • I> IV> III> II
Dipole moment diff.in e unity is HF>HCl>HBr>HI
  • True
  • False
Numbers of σ and pi bonds in C2 molecule is/are:
  • 1σ and 1π
  • 1σ and 2π
  • 2π only
  • 1σ and 3π
Which of the following compounds has dipole moment approximately equal to half of chlorobenzene?
  • odicholorobenzene
  • mdicholorobenzene
  • pdicholorobenzene
  • pcholoronitrobenzene
Which (have) zero value of dipole moment?
  • XeF4
  • CHCl3
  • CO2

The number of CC sigma bonds present in the given compound:
1084916_85bbf5a67687453cae3038960965c2ed.png
  • 16
  • 14
  • 18
  • 11
SS bond is present in:
  • α(SO3)n
  • γ(S3O9)
  • H2S2O3
  • H2S2O8
Which compound has non-zero dipole moment?
The correct order of increasing bond length of CH, CO, CC and C=C is :
  • CH < CO < CC < C=C
  • CH < C=C < CO < CC
  • CC < C=C < CO < CH
  • CO < CH < CC < C=C
Which of the following molecule does not possess a permanent dipole moment?
  • CS2
  • SO23
  • H2S
  • SO2
Select the molecule that has one pi bond?
  • CH=CH
  • CH2=CHCHO
  • CH3CH=CH2
  • CH3CH=CHCOOH
Which of the following is not correct?
  • A sigma bond is weaker than π bond
  • A sigma bond is stronger than π bond
  • A double bond is stronger than a single bond
  • A double bond is shorter than a single bond
A: Tetracyanomethane 
B: Carbondioxide 
C: Benzene
C: 1,3butadiene
Ratio of σ and π
  • in A and B are equal
  • in C and D are equal
  • is same in A, B, C, and D
  • in B and D are equal
From the given list of compounds whose proton bonding is highest?
  • H2O
  • H2S
  • NH3
  • PH3
Which of the following has the maximum value of dipole moment?
In which of the following molecules, bonding is not taking place in excited state:
  • CH4
  • BF3
  • IF7
  • PCl3
The molecular that will have dipole moment IS ZERO
  • 2,2-Dimethylpropane
  • Cis-2-butane
  • Trans-2-pentene
  • 2,2,3,3-Tereathylpentane
Peroxide linkage is present in :
  • H2O
  • BaO2
  • OF2
  • H2SO4
The correct order of decreasing bond length of C=C in the above compounds is:
1101589_565d433c9c344c92b6110d0b7ca2f73f.png
  • II>I>IV>III
  • III>II>I>IV
  • IV>II>I>III
  • none of the above
In which of the following dimer empty atomic orbital of central atom of monomer does not involve in hybridisation?
  • Ga2H6
  • Al2Br6
  • Be2H4
  • Cl2O6
The dipole moment of a bond AB is 5 D and its bond distance is 150 pm. The percentage ionic charactor of this bond is?
  • 78.5%
  • 83%
  • 24%
  • 69.5%
A diatomic molecule has a dipole moment of 1.2D. If the bond distance is 1.0A˚, fraction of an electronic charge on each atom is:
  • 10\%
  • 20\%
  • 25\%
  • 50\%
Which of the following pair of molecules will have permanent dipole moments for both members?
  • SiF_{4}and NO_{2}
  • CO_{2} and NO_{2}
  • CO_{2} and O_{3}
  • SiF_{4} and CO_{2}
Which of the following has zero dipole moment?
  • BF_3
  • BeClBr
  • CH_2Cl_2
  • COS
If dipole moment of HI is 0.38D and bond length of HI is 1.6 AA, then percentage covalent characted in HI bond is?
  • 4.95 \%
  • 5.9 \%
  • 95.05 \%
  • 47.5 %
The structural formula of a compound is CH_3-CH=C=CH_2. The type pf hybridization at the four carbon atoms from left to right is?
  • sp^2, sp, sp^2, sp^3
  • sp^2, sp^3, sp^2, sp
  • sp^3, sp^2, sp, sp^2
  • sp^3, sp^2, sp^2, sp^2
The Hybridisation and magnetic behavior of complex [Ni(CO)_{4}] is
  • dsp^{2}, paramagnetic
  • dsp^{2}, diamagnetic
  • sp^{3}, paramagnetic
  • sp^{3}, diamagnetic
The dipole moment of HBr is 0.78\ \times 10^{-18} esu cm and interatomic spacing is 1.41\ \mathring {A} The \% ionic character of HBr is?
  • 7.5
  • 11.
  • 15
  • 27
Which of the following molecule stabilizes by removal of electron?
  • C_2
  • O_2
  • N_2
  • H_2
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