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CBSE Questions for Class 11 Medical Chemistry Equilibrium Quiz 3 - MCQExams.com

If degree of ionization (α) of a weak electrolyte AB is very less, then α  is
  • directly proportional to the square root of volume of solution
  • inversely proportional to the dilution
  • inversely proportional to the square root of concentration
  • directly proportional to concentration
1M NaCl and 1M HCl are present in an aqueous solution . The solution is:
  • Not a buffer solution with pH <7
  • Not a buffer solution with pH >7
  • A buffer solution with pH <7
  • A buffer solution with pH >7
The solubility of CaF2(Ksp=3.4×1011) in 0.1M solution of NaF would be:
  • 3.4×1012M
  • 3.4×1010M
  • 3.4×109M
  • 3.4×1013M
NH4OH  is weak base but it becomes still weaker in the aqueous solution of :
  • 0.1 M HCl
  • 0.1 M NH4Cl
  • 0.1 M H2SO4
  • 0.1 M CH3COOH
Which of the following mixture is not a buffer solution?
  • 100ml of 0.5 NCH3COOH+ 100 ml of 0.05 N- NaOH
  • 100ml of 0.5 NNH4OH+ 100ml of 0.5 N-HCl
  • 100 ml of 0.5 NNH4OH+ 10 ml of 0.5 NH2SO4.
  • 300 ml of 0.5 NNH4OH+ 200 ml of 0.5 NHNO3
Match List-1 with List-2.
List -1                                                               List-2
A) CH3COONa+CH3COOH     1)Acidic due to cationic hydrolysis 
B) NH4Cl+NH4OH                     2)Basic due to anionic hydrolysis
C) aqueous AlCl3                              3) Basic buffer solution
D) aqueous Na2CO3                         4)Acidic buffer solution
  • A - 1 ; B - 2 ; C - 3 ; D - 4
  • A - 4 ; B - 3 ; C - 1 ; D - 2
  • A - 2 ; B - 3 ; C - 1 ; D - 4
  • A - 4 ; B - 3 ; C - 2 ; D - 1
The Ksp for AgCl is 2.8×1010 at a given temperature. The solubility of AgCl in 0.01 molar HCl solution at this temperature will be :
  • 2.8×1012molL1
  • 2.8×108molL1
  • 5.6×108molL1
  • 2.8×104molL1
A 0.004 M solution of Na2SO4 is isotonic with a 0.010 M solution of glucose at same temperature. The apparent degree of dissociation of Na2SO4 is:
  • 25%
  • 50%
  • 75%
  • 85%
Which of the following mixture will act as buffer?
  • H2CO3+NaOH(3:2moleratio)
  • H2CO3+NaOH(3:4moleratio)
  • NH4OH+HCl(5:4moleratio)
  • NH4OH+HCl(4:5moleratio)
Which of the following statements is/are correct about the ionic product of water?
  • K (equilibrium constant of water) < Kw
  • pK>pKw
  • At 1000C Kw=7.5×1014 (moles/lit)2
  • Ionic product of water at 250Cis1014
Assertion: A mixture of CH_3COOH and CH_3COONH_4 is not a buffer solution.
Reason: An acidic buffer contains the mixture of a weak acid and its salt with a strong base.
  • Both Assertion and Reason are correct and Reason is the correct explanation of Assertion
  • Both Assertion and Reason are correct but Reason is not the correct explanation of Assertion
  • Assertion is correct but Reason is not correct
  • Assertion is not correct but Reason is correct
  • Both Assertion and Reason are not correct
Bleaching powder is used :
  • for bleaching cotton, wood pulp
  • as a disinfectant and germicide
  • for the manufacture of chloroform
  • as a reducing agent in industries
Assertion: pH of blood does not change in spite of taking acidic foods.
Reason: Blood behaves as a buffer solution.
  • Both Assertion and Reason are correct and Reason is the correct explanation of Assertion
  • Both Assertion and Reason are correct but Reason is not the correct explanation of Assertion
  • Assertion is correct but Reason is not correct
  • Assertion is not correct but Reason is correct
  • Both Assertion and Reason are not correct
What is the [OH^-] in the final solution prepared by mixing 20.0\ mL of 0.050\ M HCl with 30.0\; mL of 0.10 \;M\; Ba(OH)_2?
  • 0.12\ M
  • 0.10\ M
  • 0.40\ M
  • 0.0050\ M

The degree of dissociation of an electrolyte depends on:

  • nature of the electrolyte
  • nature of solvent
  • temperature
  • all the above
Assertion: 
The pH of the buffer solution does not change when an acid or a base is added.

Reason: 
Buffer solution consists of a mixture of a weak acid and its salt with a strong base.
  • Both Assertion and Reason are correct and Reason is the correct explanation of Assertion
  • Both Assertion and Reason are correct but Reason is not the correct explanation of Assertion
  • Assertion is correct but Reason is not correct
  • Assertion is not correct but Reason is correct
  • Both Assertion and Reason are not correct

The degree of dissociation of an electrolyte does not depend on:

  • nature of electrolyte
  • catalytic action
  • dilution
  • temperature
Assertion: A buffer solution has a capacity to resist the change in pH value on an addition of a small amount of acid or base to it.
Reason: An aqueous solution of ammonium acetate can act as buffer.
  • Both Assertion and Reason are correct and Reason is the correct explanation of Assertion
  • Both Assertion and Reason are correct but Reason is not the correct explanation of Assertion
  • Assertion is correct but Reason is not correct
  • Assertion is not correct but Reason is correct
  • Both Assertion and Reason are not correct
Buffer solution has the capacity to restore the pH of a solution if some minor changes occur in H^+ concentration.
  • True
  • False
100ml of a buffer of 1M NH_3(aq)\: and\: {1M NH_{4}}^{+}(aq) are placed in two half cells separately. A current of 1.5amp is passed through both half cells for 20min, if electrolysis of only water take place. The pH of :


  • Anode half cell will decrease
  • Cathode half cell will decrease
  • Both half cell will decrease
  • Both half cell remain same
What is the term for the positive and negative ions of a compound breaking apart in solution?
  • Conglomeration
  • Oxidation
  • Dissociation
  • None of the above
A basic buffer consists of a mixture of weak base and its salt with weak acid.
  • True
  • False
Which of the following are present in a dilute aqueous solution of HCl?
  • H_{3}O^{+}+Cl^{-}
  • H_{3}O^{+}+OH^{-}
  • Cl^{-}+OH^{-}
  • Unionised HCl
Which one of the following can be used as an acid-base indicator by a visually impaired student?
  • Litmus
  • Turmeric
  • Vanilla essence
  • Petunia leaves
Mineral acids are stronger acids than carboxylic acids because :
(i) mineral acids are completely ionized.
(ii) carboxylic acids are completely ionized.
(iii) mineral acids are partially ionized.
(iv) carboxylic acids are partially ionized.
  • (i) and (iv)
  • (ii) and (iii)
  • (i) and (ii)
  • (iii) and (iv)
The minimum concentration of Ag^{+} ion at which precipitation of at least one anion starts is:
  • 10^{-8}.
  • 1.41 \times 10^{-6}.
  • 2 \times 10^{-6}.
  • 2 \times 10^{-10}.
Which is not a buffer solution:
  • NH_{4}Cl+NH_{4}OH
  • CH_{3}COOH+CH_{3}COONa
  • CH_{3}COONH_{4}
  • NH_{4}NO_{3}
In a sample of pure water, which one of the following statements is always true at all conditions of temperature and pressure.
  • [OH^-] = 1.0\times10^{-14} M
  • [H_3O^+] = 1.0\times10^{-7} M
  • [OH^-] = 1.0\times10^{-7} M
  • [H_3O^+]=[OH^-]
The pH value of blood does not appreciably change by a small addition of an acid or a base, because the blood
  • is a body fluid
  • can be easily coagulated
  • contains iron as a part of the molecule
  • contains serum protein which acts as buffer
About buffer solution which is correct ?
  • It contains a weak acid and its conjugate base
  • It contains a weak base and its conjugate acid
  • It shows change in pH on adding small amount of acid or base
  • All of the above
The salt which does not react with acid or base is :
  • sodium hydroxide
  • sulphuric acid
  • sodium chloride
  • sodium acetate
Which of the following pairs constitutes a buffer?
  • NaOH and NaCl
  • HNO_{3} and NH_{4}NO_{3}
  • CH_{3}COOH+CH_{3}COONa
  • HNO_{2} and NaNO_{2}
The degree of dissociation of weak electrolyte increases by :
  • increasing the concentration of weak electrolyte solution
  • adding a common ion
  • dissolution in solvent of low dielectric constant
  • adding more amount of solvent into the solution
Le- Chatelier's  principle is applicable to both homogeneous and heterogeneous equilibria.
  • True
  • False
In which of the following salts, cation does not undergo hydrolysis but anion undergoes hydrolysis?
  • BaCO_{3}
  • CaCl_{2}
  • K_{2}CO_{3}
  • NaNO_{3}
The unit of K_w is:
  • mol^2/L^2
  • mol/L^2
  • mol^2/L
  • mol/L
Which of the following combinations will make a buffer solution? 
(i) CH_3COONa\ (2 mol) + HCl\ (1 mol)
(ii) CH_3COOH\ (2 mol) + NaOH\ (1 mol)
(iii) CH_3COOH\ (1 mol) + CH_3COONa\ (1 mol)
  • (iii) 
  • (i), (ii)
  • (ii), (iii)
  • (i), (ii), (iii)
Identify the common property for a chemical reaction at dynamic equilibrium.
  • The measurable properties like concentration, density, colour, pressure etc remain constant at constant temperature.
  • The forward and backward reactions take place with the same rate.
  • It can be achieved from both directions.
  • All the above
Identity the false statements regarding ionic product of water:
  • ionic product of water increases on the addition of acids
  • ionic product of water is constant at a constant temperature
  • ionic product of water at 0^{o}C can have a value of 10^{-11}
  • neutral pH depends on the value of ionic product of water
What is meant by ionic product of water?
  • Concentrations of H^+ ions
  • Concentrations of OH^- ions
  • The product of concentrations of H^+ and OH^- ions
  • None of these
In the reaction : NO_2+CO \leftrightharpoons  NO+ CO_2, the equilibrium state may be recognized by the constancy of color.
  • True
  • False
State True or False.
S^{2-} is the conjugate base of HS^-.
  • True
  • False
The pH of blood is:
  • strongly acidic
  • neutral
  • strongly basic
  • slightly basic
The degree of dissociation of water in a 0.1M aqueous solution of HCl at a certain temperature t\ ^oC is 3.6\times 10^{-15}. The temperature t must be:
[density of water at t\ ^oC=1 gm/ml]
  • < 25^oC
  • =25^oC
  • > 25^oC
  • Insufficient data to predict
Milk of magnesia used as a medicine for treating indigestion is a substance that -
  • Helps in disintegration of food products leading to their facile metabolism.
  • Combines with gastric hydrochloric acid thereby enhancing the latter's efficiency
  • Improves the enzymatic activities inside the stomach.
  • Neutralises excess acidity, providing a buffered medium inside the stomach.
A compound which is called microcosmic salt is:
  • Na_{2}HPO_{4}.2H_{2}O
  • NaH_{2}PO_{4}.H_{2}O
  • Na(NH_{4})HPO_{4}.4H_{2}O
  • Na_{2}(NH_{4})PO_{4}.2H_{2}O
Superphosphate of lime mainly acts as :
  • fungicide
  • disinfectant
  • fertiliser
  • all of the above
Which among the following factors changes the value of ionic product of water?
  • Change in temperature
  • Addition of acid
  • Addition of base
  • Addition of either acid and base.
pK_a for the acid HA is 6. The value of K for the reaction A^-+H_3O^+\rightleftharpoons HA+H_2O is:
  • 1\times 10^{-6}
  • 1\times 10^{8}
  • 1\times 10^{-8}
  • 1\times 10^6
Which of the following salts can produce only two types of radicals?
  • NaKCO_3
  • CaOCl_2
  • NH_4HSO_4
  • Na(NH_4)HPO_4
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