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CBSE Questions for Class 11 Medical Chemistry Hydrogen Quiz 14 - MCQExams.com
CBSE
Class 11 Medical Chemistry
Hydrogen
Quiz 14
Last traces of water is removed from $$H_2O_2$$ by?
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electrolysis
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crystallisation
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condensation
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evaporation
Select the incorrect statement from the following:
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$$H^{+}$$ can exist as $$H_{9}O_{4}^{+}$$ in water.
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$$H_{2}$$ is thermally stable.
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Ionisation of $$CH_{3}COOH$$ is slower than that of $$CH_{3}COOD$$
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Kinetic isotopic effect is observed when there is retardation in the rate if $$H_{2}O$$ is replaced by $$D_{2}O$$
By which of the following methods, $$H_{2}O_{2}$$ can't be synthesised ?
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Lewis addition of ice cold $$H_{2}SO_{4}$$ on $$BaO_{2}$$
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Addition of ice cold $$H_{2}SO_{4}$$ and $$PbO_{2}$$
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Aerial oxidation of $$2$$-ethyl anthraquinol
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Electrolysis of $$(NH_{4})_{2}SO_{4}$$ at a high current density
Explanation
$$H_{2}SO_{4} + PbO_{2} \rightarrow PbSO_{4} \downarrow + \dfrac{1}{2}O_{2} + H_{2}O$$ ($$PbO_{2}$$ is not peroxy compound)
$$H_{2}SO_{4} + BaO_{2} \rightarrow BaSO_{4} \downarrow + H_{2}O_{2}$$
$$(NH_{4})_{2}SO_{4} \leftrightharpoons 2NH_{4}^{+} + SO_{4}^{2-}$$
At anode : $$2SO_{4}^{2-} \overset{Electrolysis}{\rightarrow} S_{2}O_{8}^{2-} + 2e^{-}$$
Peroxo sulphate on hydrolysis, produces $$H_{2}O_{2}.$$
Hence, Option "B" is the correct answer.
State true or false:
The rapid cooking in pressure cookers is based upon the principle that boiling point of water increases with increase in pressure.
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True
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False
Complete hydrolysis of one mole of peroxydisulphuric acid gives one mole of $$H_2O_2$$ and two moles of
$$H_2SO_4$$.
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True
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False
Explanation
$$\text { Complete hydrolysis of one mole of peroxydisulphuric } \\$$
$$\text { acid gives one mole } \mathrm{H}_{2} \mathrm{O}_{2} \text { & two mole of } \mathrm{H}_{2} \mathrm{SO}_{4} \text { , this } \\$$
$$\text { Process is prepnation of } \mathrm{H}_{2} \mathrm{O}_{2}$$
$$\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{8_{(aa)}} \dfrac{\text { Hydrolysis }}{\longrightarrow} 2 \mathrm{H}_{2} \mathrm{SO}_{4}+\mathrm{H}_{2} \mathrm{O}_{2}(\mathrm{aa})$$
$$\text { Hence, given statement is correct (true). }$$
Water cannot be used to extinguish the petrol fire.
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True
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False
Explanation
Being lighter petrol floats over water. So,
Water cannot be used to extinguish the petrol fire.
Hence, the given statement is True.
Statement - 1: Dihedral angle of $$H_{2}O_{2}$$ in gaseous state is $$90^{\circ}$$.
Statement - 2: Dihedral angle of $$H_{2}O_{2}$$ in solid state is $$111^{\circ}$$.
Are the statements true or false?
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True, True
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True, False
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False, True
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False, False
Explanation
In solid-state, the dihedral angle is smaller because of the presence of hydrogen bonding.
Hence, option (d) is the correct answer.
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