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CBSE Questions for Class 11 Medical Chemistry Chemical Bonding And Molecular Structure Quiz 9 - MCQExams.com

Among the following molecules in increasing order of σ to π bond ratio.
1717823_dfa87f4e6e1b4a6da377f61f9a2915bb.PNG
  • 2<3<4<1
  • 2<4<3<1
  • 3<2<1<4
  • 2<3<1<4
The enolic form of butanone contains?
  • 12σ bonds, 1π bond and 2 lone pairs of electrons
  • 11σ bonds, 1π bond and 2 lone pairs of electrons
  • 12σ bonds, 1π bond and 1 lone pair of electrons
  • 10σ bonds, 2π bonds and 2 lone pairs of electrons
  • 13σ bonds, 1π bonds and 2 lone pairs of electrons
The dipole moment of CH3F is greater than that CH3Cl 
  • True
  • False
In the group the carbonyl carbon is joined to other atoms by:
1719721_c7bc2531597341f2a4228bff7e290d78.PNG
  • two sigma and one pi bond
  • three sigma and one pi bond
  • two sigma and two pi bonds
  • three sigma and two pi bonds
A compound with molecular formula C4H6 may contain.
  • two double bond
  • Two double bonds or a triple bond
  • A triple bond
  • All single bonds
Which cholrine atom is more electronegative in the following ?
  • CH3CI
  • CH3CH2CI
  • (CH3)2CHCI
  • CH3CH2C|Cl(CH3)2
Find the incorrect match.
  • Al2Cl6 : 3C4e bond is present
  • Al2(CH3)6 : All carbon atoms are sp3 - hybridized
  • I2Cl6 : Nonplanar
  • Al2Br6 : Nonpolar
dx2y2 orbital is involved in which of the following hybridization?
  • sp3d (sq. pyramidal)
  • dsp2
  • sp3d2
  • sp3d3
Which of the following does not contain three electron bond?
  • ClO2
  • CO2
  • O2
  • NO
Which of the following molecule/ion has a zero dipole moment?
  • ClF3
  • ICl2
  • SF4
  • None of these
Which is/are not correct for B2H6 structure ?
  • It has 4BH terminal bonds and two 3C2e bonds
  • It has six BH terminal bonds and one 3C2e bond
  • It has four BH terminal bonds two 3C2e bonds and one B-B bond
  • It has interaction between [BH2]+ and [BH4]
Linear combination of two hybridized orbitals, belonging to two atoms and each having one electron, leads to:
  • Sigma-bond
  • Double bound
  • Coordinate covalent bond
  • Pi-bond
Select the correct order :
  • Bond Strength : NO<NO<NO+
  • N-O bond angle : NO+2<NO2<NO3
  • Thermal stability : LiF>NaF>KF>RbF>CsF
  • Hydrated size : Be2+(aq)<Mg2+(aq)<Ca2+(aq)<Sr2+(aq)<Ba2+(aq)
The bond between two identical non metal atoms has a pair of electron
  • unequally shared betweem the two
  • transferred fully from one atom to another
  • with identical spins
  • equally shared between them
The bond between B and C will be 
  • Ionic
  • Covalent
  • Hydrogen
  • Cordiante
Among the following species, identify the isostructural pairs:

NF3, NO3, H3O+, N3H, BF3
  • [NF3, NO3] and [BF3, H3O+]
  • [NF3, N3H] and [NO3, BF3]
  • [NF3, H3O+] and [NO3, BF3]
  • [NF3, H3O+] and [N3H, BF3]
All molecules with polar bonds have dipole moment.
  • True
  • False
Which of the following compounds has a zero dipole moment?
  • 1,1 - dichlorethylene
  • cis -1,2 - dichlorocthylene
  • trans -1,2 - dichloroethylene
  • none of the above
On hybridization of one s- and one p-orbital we get :
  • Two mutually perpendicular orbitals
  • Two orbitals at 1800
  • Four orbitals directed tetrahedrally
  • Three orbitals in a plane
The number of lone pairs of electrons in XeF2,XeF4,XeF6 and XeOF2 are respectively:
  • 3,2,1,2
  • 2,1,1,2
  • 3,2,1,1
  • 3,2,2,2
The number and type of bonds between two carbon atoms in CaC2 are :
  • One σ and one π bond
  • One σ and two π bond
  • One σ and one-half π bond
  • One σ bond
Acetylene molecule contains:
  • 5 sigma bonds
  • 4 sigma and 1πbond
  • 3 sigma and 2πbonds
  • 2 sigma and 3πbonds
A molecule possessing dipole moment is:
  • CH4
  • H2O
  • BF3
  • CO2
The number and type of bonds in C22 in CaC2 are:
  • Two σ bond and one π bond
  • Two σ bond and two π bond
  • One σ bond and two π bond
  • One σ bond and one π bond
The types of bonds present in NH4Cl are:
  • electrovalent, covalent and coordinate
  • only ionic
  • only covalent
  • covalent and coordinate
The type of bond present in CuSO4.5H2O are only.
  • Electrovalent and covalent
  • Electrovalent and coordinate covalent
  • Electrovalent,covalent and coordinate covalent
  • Covalent and coordinate covalent
On hybridization of one s-and one p-orbitals, we get:
  • Two mutually perpendicular orbitals
  • Two orbitals at 180o
  • four orbitals directed tetrahedrally
  • Three orbitals in the plane
The hybrid state and oxidation state of two oxygen atoms in H2O2 are respectively:
  • sp2,1
  • sp2,+1
  • sp3,1
  • sp3,+1
The hybridization of I in ICl+2 is :
  • sp
  • sp2
  • sp3
  • dsp2
The hybridisation of oxygen atom in H2O2 is:
  • sp3d
  • sp
  • sp2
  • sp3
  • sp3d2
Which statement(s) is are correct?
  • A sigma bond is stronger than πbond
  • A sigma bond is weaker than πbond
  • Hydrogen bonding is weaker than covalent bonding
  • A triple is weaker than double bond
In which of the following the central atom has maximum number of lone piar of electrons?
  • SF4
  • XeF4
  • ClO3
  • I3
Which of the following statements is true about [Cu(NH3)4]SO4
  • It has coordinate as well as covalent bonds
  • It has only coordinate bonds
  • It has only electrovalent bonds
  • It has electrovalent,covalent as well as coordinate bonds
Which of the following does not have SS linkage?
  • S2O28
  • S2O26
  • S2O25
  • S2O23
The correct order of OO bond length in O2,H2O2 and O3 is:
  • O3>H2O2>O2
  • O2>H2O2>O3
  • O2>O3>H2O2
  • H2O2>O3>O2
Which of the following has the highest value of dipole moment?
  • HCl
  • HF
  • HI
  • HBr
In OF2 molecule, the total number of bond pairs and line pairs of electron present respectively are:
  • 2,6
  • 2,8
  • 2,10
  • 2,9
In which of the following SS link is present?
  • Caro's acid
  • Dithionic acid
  • Thiosulphuric acid
  • Chlorosulphonic acid
Number of lone pairs of electrons on Xe atoms in XeF2,XeF4 and XeF6 moleculaes are respectively :
  • 3, 2 and 1
  • 4, 3 and 2
  • 2, 3 and 1
  • 3, 2 and 0
How many PO bonds and how many lone pairs respectively are present in P4O6 molecule?
  • 12,4
  • 8,8
  • 12,16
  • 12,12
The number of sigma and pi bonds in peroxydisulphuric acid are respectively:
  • 9 and 4
  • 11 and 4
  • 4 and 8
  • 4 and 9
Which of the following bonds is the weakest?
  • SiSi
  • SiO
  • SiCl
  • SiH
The number of lone pairs and the number of SS bonds in S8 molecules are respectively:
  • 8,8
  • 16,8
  • 8,16
  • 8,4
In which of the following ions, there is no SS bond?
  • S2O24
  • S2O26
  • S2O22
  • S2O23
  • S2O27
Which of the following molecules of possess a permanent dipole moment?
  • H2S
  • SO2
  • NH3
  • CS2
In Fe(CO)5, the FeC bond posses:
  • π character only
  • σ character only
  • ionic character only
  • bond π and σ characters
Which of the following ions does not have S-S linkage?
  • S2O28
  • S2O26
  • S2O25
  • S2O23
ML bonds in carbonyl possess:
  • only sigma character
  • only pi (π) character
  • both sigma (σ) and pi (π) characters
  • none of the above
The cation containing maximum number of unpaired electrons is:
  • Co2+
  • Ni2+
  • Fe3+
  • Fe2+
B.P of H2O(100C) and H2S(42C) explained by:
  • Vander Waal's forces
  • Covalent bond
  • Hydrogen bond
  • Ionic bond
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