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CBSE Questions for Class 11 Medical Chemistry Classification Of Elements And Periodicity In Properties Quiz 12 - MCQExams.com

Which of the following statements is not correct for the element having electronic structure 2,8,8,2?
  • Its valency is 2
  • It is in fourth period
  • It is in group II
  • Its atom forms negative ion
Which of the following elements will have highest ionization energy ?
  • 1s22s22p63s1
  • 1s22s22p63s23p3
  • 1s22s22p63s23p4
  • 1s22s22p63s1
Identify the incorrect match.
NameIUPAC Official Name
a)Unniluniumi)Mendelevium
b)Unniltriumii)Lawrencium
c)Unnilhexiumiii)Seaborgium
d)Unununniumiv)Darmstadtium
  • (b), (ii)
  • (c), (iii)
  • (d), (iv)
  • (a), (i)
State True or False:
The first ionization energy of N is lower than that of oxygen.
  • True
  • False
In group 1 of alkali metals , the ionization potential decreases down the group. therefore , lithium is powerful reducing agents.
  • True
  • False
Which of the following has maximum ionization potential ?
  • Be
  • K
  • Na
  • Mg
The first ionization energy (kJmol1) for H, Li, F, Na has one of the following values : 1681,520,1312,495.Which of these values corresponds to that of hydrogen?
  • 1681
  • 1312
  • 520
  • 495
In which of the following cases, the former change would require lesser energy than the latter?
  • Be+(g)Be2+(g)+e;Be(g)Be+(g)+e
  • Na(g)Na+(g)+e;Cl(g)Cl(g)+e
  • Ag(g)Ag+(g)+e;Au(g)Au+(g)+e
  • O(g)O(g)+e;S(g)S(g)+e
Beryllium and aluminium exhibit many properties which are similar. But, the two elements differ in:
  • maximum covalency in compounds
  • forming polymeric hydrides
  • forming covalent halides
  • exhibiting amphoteric nature in their oxides
Among Al2O3,SiO2,P2O3 and SO2 the correct order of acid strength is:
  • Al2O3<SiO2<SO2<P2O3
  • SiO2<SO2<Al2O3<P2O3
  • SO2<P2O3<SiO2<Al2O3
  • Al2O3<SiO2<P2O3<SO2
IP values and EA values of elements A, B, C and D are given in a tabular form. Identify the strongest oxidizing agent and reducing agent among them.
IP ValueEA Value
A450140
B225700
C300400
D7001035
  • B, D
  • B, A
  • D, A
  • D, B
Pick the correct order of ionization potential values of elements.

(a) C < O < N < F < Ne

(b) He > Ne > Ar > Kr > Xe

(c) Li > Na > K > Rb > Cs

(d) Be < Mg < Ca < Sr < Ba

(e) Na > Mg > Al > Si > P 
  • a, c and e
  • b, c and d
  • a, b and c
  • b, d and c
Suppose a gas mixture of F,Cl,Br and I is irradiated with photons of frequency appropriate to ionize Cl. What ion(s) will be present in the mixture ?
  • F+ only
  • Cl+ only
  • F+,Cl+,Br+ only
  • Cl+,Be+,I+ only
Which of the following statement(s) is(are) correct?
  • The electron affinity for sulphur is more exothermic than that for oxygen
  • Successive ionization energies of an atom always increase
  • First ionization energy of As is greater than that of Se
  • Chlorine has larger atomic size as well as electron affinity than that of fluorine
Consider the following statements.

S1: Fluorine does not form any polyhalide as it has low F - F bond energy
S2: The chlorine has the most negative electron gain enthalpy.
S3: The first ionization potential of N and 0 atoms are 14.6 and 13.6 eV respectively.

Which of the above statements are correct?
  • S1,S2 and S3
  • S1 and S2
  • S1 and S3
  • S2 and S3
Ionization energy of He+ is 19.6×1018Jatom1. The energy of the first stationary state (n=1) of Li2+ is:
  • 2.2×1015Jatom1
  • 8.82×1017Jatom1
  • 4.41×1016Jatom1
  • 4.41×1017Jatom1
Ionisation energy in group 1A varies in the decreasing order as:
  • Li>Na>K>Cs
  • Na>Li>K>Cs
  • Li>Cs>K>Na
  • K>Cs>Na>Li
The ionisation enthalpy of He+ ion is 19.60×1018J atom1. The ionisation enthalpy of Li2+ ion will be:
  • 84.2×1018Jatom1
  • 44.10×1018Jatom1
  • 63.20×1018Jatom1
  • 21.20×1018Jatom1
  • 2.17×1019Jatom1
Which has maximum ionisation potential?
  • N
  • O
  • O+
  • Na
Considering the trend for ionization energy on the periodic table, which of the following elements has the highest ionization energy?
  • Boron
  • Oxygen
  • Nitrogen
  • Fluorine
Arrange the following elements in terms of increasing first ionization energy:
Ga, Ba, Ru, F, N
  • Ba<Ru<Ga<N<F
  • Ga<Ba<Ru<F<N
  • Ru<Ba<Ga<N<F
  • None of the above
The table above shows the first five ionization energies for a second-period element. Which identifies the element and provides the best explanation?
Ionization Energy (kJ/mol)
First801
Second2,430
Third3,660
Fourth25,000
Fifth32,820
  • Boron, because it has five electrons.
  • Boron, because is has three valence electrons.
  • Nitrogen, because it has five valence electrons.
  • Nitrogen, because it has three electrons in a 2p sublevel.
The most electropositive element is:
  • Na
  • Al
  • F
  • K
A swimmer coming out from a pool is covered with a film of water weighing about 18 g. Calculate the internal energy of vaporisation at 1000 C.

[ ∆ vap H for water at 373 K = 40.66 kJ mol -1 ]
  • 37.55kJmol1
  • 3.67kJmol1
  • 30.67kJmol1
  • 3.567kJmol1
    35.67kJmol
The first (ΔH1) and second (ΔH2) ionisation enthalpies (in kJmol1) and the electron gain enthalpy (ΔegH) (in kJmol1) of the elements I, II, III, IV and V are given below:

ElementΔ1H1Δ1H2ΔegH
I5207300-60
II4193051-48
II16813374-328
IV10081846-295
V23725251+48
The most reactive metal and the least reactive non-metal of  these are respectively.
  • I and V
  • V and II
  • II and V
  • IV and V
An element X has electronic configuration 2, 8,It forms ionic compounds with ions like nitrate, sulphate and phosphate. What will be the formulae of these compounds?
  • X2NO3,X2SO4,X2(PO4)3
  • X2NO3,XSO4,X2(PO4)3
  • XNO3,XSO4,X(PO4)3
  • X(NO3)2,XSO4,X3(PO4)2
If the configuration of Y+ & X is 2s2 2p6 then
  • IP of X=IP of Y
  • EA of X>EA of Y
  • IP of X=IP of Y+
  • IP of X>IP of Y+
In which of the following options order of arrangement does not match with the variation of property indicated against it?
  • Al3+<Mg2+<Na+<F (increasing ionic size)
  • B<C<N<O (increasing first ionisation enthalpy)
  • I<Br<F<Cl (increasing electron gain enthalpy)
  • Li<Na<K<Rb (increasing metallic radius)
The decreasing order of the ionization potential of the following elements is:
  • Ne>Cl>P>S>Al>Mg
  • Ne>Cl>P>S>Mg>Al
  • Ne>Cl>S>P>Mg>Al
  • Ne>Cl>S>P>Al>Mg
Which of the following statement is correct?
  • IP of X(g)> E.A. of X(g)
  • IP of X(g)> IP of X(g)
  • IP of X+(g)> IP of X(g)
  • All are correct
Generally, the first ionisation energy increases along a period, but there are some exceptions. From the given sets which is not an exception: 
  • N and O
  • Na and Mg
  • Mg and AI
  • Be and B
Supposing the energy of the fourth shell for the hydrogen atom is -50 a.u. (arbitrary unit). What would be its ionization potential?
  • 50
  • 800
  • 15.4
  • 20.8
In Cr, 21st electron will enter in which orbital?
  • dxy
  • dyz
  • dzx
  • Any of the above
The electronic configuration of an element is 1s22s22p63s23p3 . The atomic number of the element, which is just below the above element in the periodic table is__
  • 32
  • 33
  • 35
  • 30
The IP2,IP3,IP4 andIP5 of an element are 7.1, 14.3 , 34.5, 46.8, 162.2 eV respectively .The element is likely to be:
  • Na
  • Si
  • F
  • Ca
The second ionization energy is maximum for:
  • boron
  • beryllium
  • magnesium
  • aluminium
All alkali metal superoxides contain the [O2] ion. They are:
  • Paramagnetic
  • Coloured compounds
  • Oxidizing agents
  • All of these
The enthalpy of formation of gaseous N2O and NO at 298 K are 82 and 90 kJ mol1. The enthalpy of reaction:
N2O(g)+12O22NO(g) is
  • -8 kJ
  • 98kJ
  • -74 kJ
  • +8 kJ
In which pair do both atoms have one electron only in an "s" orbital in their ground states?
  • Ca,Sc
  • Cu,Be
  • H,He
  • Li,Cr
Which pair of elements has the same characteristic chemical properties?
  • Z=13,Z=22
  • Z=3,Z=11
  • Z=4,Z=24
  • Z=2,Z=4
In which of the following pairs, the first member has higher first ionization energy ?
  • N,O
  • Cl,Ar
  • Al,Ga
  • B,Be
The set representing the correct order of first ionization potential is:
  • K>Na>Li
  • Ge>Si>C
  • Be>Mg>Ca
  • B>N>C
Match the atomic numbers 19, 15, 8, 4 and 2 with each of the following:                                           
  • 19: A metal of valency one.
  • 15: A solid non-metal of period 3
  • 8: A rare gas
  • 2: A gaseous element with valency 2.
  • 4: An element of group 2.
Two moles of N2 and two moles of H2 are taken in a closed vessel of 5 litres capacity and suitable conditions are provided for the reaction. When the equilibrium is reached, it is found that a half mole of N2is used up. The equilibrium concentration of NH3 is:
  • 0.3 M
  • 0.4 M
  • 0.2 M
  • 0.1 M
If each orbital can hold a maximum of three electrons, the number of elements in 9 th  period of periodic table (long form) are
  • 48
  • 162
  • 50
  • 75
Which one of the following is a correct electronic composition of sodium?
  • 2,8
  • 8,2,1
  • 2,1,8
  • 2,8,1

Which members of each of the following pairs of atoms has higher first ionisation enthalpy and why?

  • Na:K
  • Ar:Cl
  • B:Be
  • O:N
Sodium forms Na+ and not Na2+ because :
  • sodium contains only one electron in outermost shell.
  • first ionization potential is small and the difference in first and second ionization potentials is very large.
  • radius of Na+ is much smaller than of Na2+.
  • None of the above.
The first four ionization potentials (eV) are given for two elements X and Y.Identify them.
X8.29625.14937.92259.298
Y5.31847.2971.6598.88
  • B,Na
  • Na,Be
  • Be,B
  • Na,Mg
For the highlighted element in its X2 form identify the CORRECT electronic configuration.
1591420_f644bdd1593a484d99d6ada8808b7bd9.JPG
  • [Kr]5s24d105p4
  • [Kr]5s25p4
  • [Kr]5s24d105p6
  • [Kr]5s25p6
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