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CBSE Questions for Class 11 Medical Chemistry States Of Matter Gases And Liquids Quiz 9 - MCQExams.com
CBSE
Class 11 Medical Chemistry
States Of Matter Gases And Liquids
Quiz 9
The number of
H
3
O
+
ions present in 10ml of water at
25
∘
C
is:
Report Question
0%
6.023
×
10
−
14
0%
6.023
×
10
14
0%
6.023
×
10
−
19
0%
6.023
×
10
19
Explanation
No. of hydronium ions present in
10
ml water at
25
0
C
.
p
H
=
7
at
25
0
C
[
H
+
]
=
10
−
7
M
No. of moles
=
Concentration
×
Volume
=
(
10
−
7
)
(
10
)
×
10
−
3
=
10
−
9
moles
1 mole has
6.023
×
10
23
ions of hydronium.
⇒
6.023
×
10
23
×
10
−
9
ions in
10
ml water
⇒
6.023
×
10
14
ions are there in
10
ml water at
25
0
C
.
Hence, option B is correct.
The vapour pressure of a solution containing 5 g of a non electrolyte in 100 g of water at a particular temperature is
2985
N
m
−
2
. If the vapour pressure of pure water is
3000
N
m
−
2
, the molecular weight of solute is:
Report Question
0%
60
0%
120
0%
180
0%
380
Explanation
we have formula of
Relative lowering of vapour pressure
which is
P
o
−
P
P
o
=
X
s
o
l
u
t
e
=
n
s
o
l
u
t
e
n
s
o
l
u
t
e
+
n
s
o
l
v
e
n
t
≈
n
s
o
l
u
t
e
n
s
o
l
v
e
n
t
Now, pute the values
3000
−
2985
3000
=
5
M
100
18
15
3000
=
5
×
18
100
×
M
M
=
180
correct answer is C.
The temperature and pressure at which ice, liquid. water and water vapour can exist together are ?
Report Question
0%
0
o
C
,
1
a
t
m
0%
2
o
C
,
4.7
a
t
m
0%
0
o
C
,
4.7
m
m
0%
−
2
o
C
,
4.7
m
m
Explanation
The temperature and pressure at which ice, liquid, water and water vapour exist together at triple point of water.
Triple point of water is
0
∘
C
a
n
d
4.7
m
m
Hence, Option "C" is the correct answer.
Which of the following represents the Avogadro number?
Report Question
0%
Number of molecule present in 1 L of gas at N.T.P
0%
Number of molecule present in 22.4 L of gas at N.T.P
0%
Number of molecule present in 22.4 of gas at 298K and 1 atm pressure
0%
Number of molecule present in one mole of gas at any temp and pressure
Explanation
Avogadro number is defined as the number of gas molecules present in one mole of gas at any pressure and temperature. It's value is
6.023
×
10
23
. So the correct option is D
According to the equipartition principle, each degree of freedom contribute following amount to the translational kinetic energy of molecule: (hence k = Boltzmann constant)
Report Question
0%
1
2
k
T
0%
k
T
0%
3
2
k
T
0%
1
3
k
T
Explanation
According to the equipartition principle, each degree of freedom contributes an amount of
1
2
k
T
to the kinetic energy of the molecule.
The solubility of a specific non-volatile salt is
4
g
in
100
g
of water at
25
∘
C
.
If
2.0
g
,
4.0
g
and
6.0
g
of the salt added of
100
g
of water at
25
∘
C
,
in system
X
,
Y
and
Z
.
The vapour pressure would be in the order:
Report Question
0%
X
<
Y
<
Z
0%
X
>
Y
>
Z
0%
Z
>
X
=
Y
0%
x
>
Y
=
z
A certain number of spherical drops of a liquid of radius r coalesce to form a single drop of radius
R
and volume
V
. If
T
is the surface tension of the liquid, then.
Report Question
0%
Energy =
4
V
T
(
1
r
+
1
R
)
is released
0%
Energy =
3
V
T
(
1
r
−
1
R
)
is absorbed
0%
Energy =
3
V
T
(
1
r
−
1
R
)
is released
0%
Energy is neither released nor absorbed
Explanation
Since intial volume=final volume
Let's say number of drops
=
N
Then energy released
=
T
,
Δ
A
A
i
=
(
4
π
r
2
)
.
n
n
=
number of drops
Total volume
=
n
.
(
4
π
3
r
3
)
=
(
n
.4
π
r
2
)
.
r
3
o
r
,
A
i
=
(
n
.4
π
r
2
)
=
3
V
r
A
f
=
n
.4
π
R
2
=
3
V
R
∴
E
n
e
r
g
y
r
e
l
e
a
s
e
d
=
T
(
3
V
R
−
3
V
r
)
=
3
V
T
(
1
r
−
1
R
)
If volume of
2
moles of a gas at
27
∘
C
is
8.21
L
then pressure of this gas will be.
Report Question
0%
0.6
atm
0%
6
atm
0%
60
atm
0%
600
atm
If
500
m
l
of a gas
A
at
1000
torr, and
1000
m
l
of gas
B
at
800
torr are placed in
2
L
container the final pressure will be -
Report Question
0%
100
torr
0%
650
torr
0%
1800
torr
0%
2400
torr
Explanation
According to Boyle's Law (Modified)
P
1
V
1
+
P
2
V
2
+
.
.
.
.
.
.
.
.
=
P
f
V
f
Given,
P
1
=
1000
;
V
1
=
500
m
L
P
2
=
800
;
V
2
=
1000
m
L
P
f
=
?
;
V
f
=
2000
m
L
⟹
P
1
V
1
+
P
2
V
2
=
P
f
V
f
⟹
(
1000
)
(
500
)
+
(
800
)
(
1000
)
=
(
P
f
)
(
2000
)
⟹
1300
2
=
P
f
⟹
P
f
=
650
t
o
r
r
At
250
o
C
and
1
atmosphere pressure, the vapour density of
P
C
I
5
is
57.9
. What will be the dissociation of
P
C
I
5
−
Report Question
0%
1.00
0%
0.90
0%
0.80
0%
0.65
Explanation
When
20
K
J
of heat is removed from
1.2
k
g
of ice originally at
−
15
C
o
, its new temperature is
Report Question
0%
−
18
C
o
0%
−
23
C
o
0%
−
26
C
o
0%
−
35
C
o
Which of the following sets of variables give a staright line with negative slope when plotted ?
( P = Vapour pressure ; T = Temperature in K)
y- axis x -axis y -axis x-axis
Report Question
0%
P
T
0%
l
o
g
10
P
T
0%
l
o
g
10
P
1
T
0%
l
o
g
10
P
l
o
g
10
1
T
When the temperature of 23ml of dry
C
O
2
gas is changed from
10
∘
to
30
∘
at constant pressure of 760 mm, the volume of gas becomes closest to which one of the following?
Report Question
0%
7.7 ml
0%
21.5 ml
0%
24.6 ml
0%
69 ml
Equation of state of an ideal gas is/are
Report Question
0%
p
V
=
(
1
/
3
)
m
N
0%
p
V
=
n
R
T
0%
p
=
ρ
R
T
/
M
0%
p
=
3
M
k
/
2
V
A liquid will not wet the surface of a solid if the angle of contact is
Report Question
0%
0
∘
0%
45
∘
0%
60
∘
0%
>
90
∘
Explanation
Hint :- Contact angle is the measure of ability of a liquid to wet the surface
Explanation:-
A liquid will not wet the surface of a solid or poor wetting if its angle of contact is more than
90
0
.It means meniscus must be convex.
For example mercury.
Correct option: D
Which of the following is an anti-knocking compound, that has been phased out in many countries so far?
Report Question
0%
Lead tetrachloride
0%
Tetra Ethyl Lead
0%
Ethyl
tetrachloride
0%
None of these
Explanation
Given :
Which of the following is an anti-knocking compound, that has been phased out in many countries so far?
Solution :
An anti-knocking agent is a chemical compound that, when added to gasoline, raises the octane value of the gasoline.
Tetra Ethyl Lead
is an anti-knocking compound, that has been phased out in many countries so far.
The Correct Opt = B
At
300
K
, the density of a certain gaseous molecule at 2 bar is double to that of dinitrogen
(
N
2
)
at 4 bar.The molar mass of gaseous molecule is:
Report Question
0%
224
g
m
o
l
−
1
0%
112
g
m
o
l
−
1
0%
56
g
m
o
l
−
1
0%
28
g
m
o
l
−
1
A container has
S
O
2
gas at
2
a
t
m
pressure in a vessel of
V
L
capacity, if no. of moles of
S
O
2
are doubled in the same container at the same temperature and volume. Calculate new pressure in the container.
Report Question
0%
1
a
t
m
0%
4
a
t
m
0%
2
a
t
m
0%
8
a
t
m
A solution
X
of
A
and
B
contains
30
mole
%
of
A
& is in equilibrium with its vapour that contains
40
mole
%
of
B
. The ratio of
V
.
P
of pure,
A
and
B
will be?
Report Question
0%
2
:
7
0%
7
:
2
0%
3
:
4
0%
4
:
3
The vapour pressure of water at
20
0
C
is 17.54 mm. When 20 g of non-ionic, substance is dissolved in 100 g of water, the vapour pressure is lowered by 0.30 mm.What is the molecular weight of the substances.
Report Question
0%
210.2
0%
208.16
0%
215.2
0%
200.8
Consider the following statements
a. Kinetic energy of a molecule is zero at
0
0
C
.
b. A gas in a closed container will exert much higher pressure due to gravity at the bottom than at the top
c. Between collisions, the molecules move in straight lines with constant velocities.
Choose the incorrect statement(s)
Report Question
0%
a, b & c
0%
a & b
0%
b & c
0%
a & c
One gram molecule of any gas at
N
T
P
occupies
22.4
L
. This fact was derived from:
Report Question
0%
Dalton's theory
0%
Avogardro's hypothesis
0%
Berzelius hypothesis
0%
Law of gaseous volume
Explanation
According to Avogadro's law, 1 mole of every gas occupies 22.4L at
N
T
P
.
From ideal gas equation,
P
V
=
n
R
T
. . . . . . .(1)
At
N
T
P
,
T
=
273
K
P
=
1
a
t
m
n
=
1
R
=
0.0821
a
t
m
L
/
K
m
o
l
from equation (1),
V
=
n
R
T
P
V
=
1
×
0.0821
×
273
1
=
22.4
L
The correct option is B.
The sample of neon gas heated from 300 K to 390 K, percentage increases in K.E is:
Report Question
0%
10
%
0%
20
%
0%
30
%
0%
40
%
Explanation
Kinetic energy of gas is given by
K
.
E
=
3
2
n
R
T
therefore, kinetic energy is directly proportional to temperature.
so, if we find out percentage change in temperature , we can get percentage change in kinetic energy .
percentage change in temperature
=
Δ
T
T
=
390
−
300
90
×
100
=
90
300
×
100
=
30
%
hence, percentage change in kinetic energy of neon gas is 30%
273
m
l
of a gas at STP was taken to
27
o
C
and
600
m
m
pressure. The final volume of the gas would be:
Report Question
0%
273 mL
0%
300 mL
0%
380 mL
0%
586 mL
Explanation
We know that, for constant no. of moles of gas,
P
1
V
1
T
1
=
P
2
V
2
T
2
Given,
initial conditions,
P
1
=
760
m
m
(STP)
V
1
=
273
m
L
T
1
=
273
K
(STP)
Final conditions,
P
=
600
m
m
T
=
300
K
Thus,
V
2
=
P
1
V
1
T
1
×
T
2
P
2
=
760
×
273
×
300
273
×
600
=
380
m
L
Hence, option C is correct.
Equal amounts of two gases of molecular mass 4 and 40 are mixed. the pressure of the mixture is 1.1 atm. The partial pressure of the light gas in this mixture is :
Report Question
0%
0.55 atm
0%
0.11 atm,
0%
1 atm
0%
o.12 atm
Explanation
Assume 40 g each of two gases is present.
The number of moles of lighter gas are
40
4
=
10
.
The number of moles of heavier gas are
40
40
=
1
.
The mole fraction of the lighter gas is
10
10
+
1
=
0.9090
.
The partial pressure of the lighter gas is
0.9090
×
1.1
=
1
a
t
m
.
Mole fraction of A vapours above the solution in mixture of A and B (
X
A
=
0.4
)will be
[Given :
P
0
A
=
100
m
m
H
g
a
n
d
P
0
B
=
200
m
m
H
g
]
Report Question
0%
0.4
0%
0.8
0%
0.25
0%
none of these
If there unreactive gases having partial pressure
P
A
,
P
B
and
P
C
and there moles are
1
,
2
and
3
respectively then their total pressure will be :
Report Question
0%
P
=
P
A
+
P
B
+
P
C
0%
P
=
P
A
+
P
B
+
P
C
6
0%
P
=
√
P
A
+
P
B
+
P
C
3
0%
None of these
Explanation
According to Dalton's law of partial pressure,
Total pressure = sum of partial pressures of individual gases
P
t
o
t
a
l
=
P
a
+
P
b
+
P
c
Therefore, option A is correct.
6 g of urea is dissolved in 90 g of boiling water.The vapour preasure of the solution is:
Report Question
0%
744.8
m
m
0%
758
m
m
0%
761
m
m
0%
760
m
m
The conversion of oxygen to ozone occurs to the extent of 15% the mass of ozone that can be prepared from 67.2 L of oxygen at 1 atm and 273 K will be:
Report Question
0%
14.4 gm
0%
96 gm
0%
640 gm
0%
64 gm
Explanation
3
O
2
→
2
O
3
As per stoichiometric equation,
3
×
22.4
L
of oxygen is converted to
2
×
22.4
L
of ozone. But given 15 % of oxygen is converted to ozone.
That means 67.2 L of oxygen used
15
100
×
67.2
×
2
3
=
6.72
L
ozone is produced.
The mass of ozone present in
22.4
L
=
48
g
10.08
L
of ozone means
=
48
22.4
×
6.72
=
14.4
g
An
α
- particle is projected towards the following nucleus with same kinetic energy in different experiment the distance of closet approach is maximum for
Report Question
0%
Na(Z=11)
0%
Ca(Z=20)
0%
Ag (Z=47)
0%
Au (Z=79)
Explanation
K.E
=
1
4
π
ε
0
q
1
q
2
r
q
1
= change on
1
s
t
particle
q
2
= charge on second particle
r
= distance between them or distance of closet approach
Assume
q
1
charge on alpha particle
=
α
q
q
2
= charge on nuclei given in question
r
=
1
4
π
ε
0
q
1
q
2
K
.
E
K.E is same for all nuclei. But
q
2
is maximum for gold
(
+
79
)
. Hence
r
will be maximum for gold.
The vapour pressure of two liquids are
15000
and
30000
in a unit. When equimolar solution of liquids is.. The the mole fraction of A and B in vapour phase will be:
Report Question
0%
2
3
,
1
3
0%
1
3
,
2
3
0%
1
2
,
1
2
0%
1
4
,
3
4
Rain drops acquire spherical shape due to
Report Question
0%
viscosity
0%
surface tension
0%
friction
0%
elasticity
Explanation
The Surface tension pulls the surface of the drop equally at all points thus produces the spherical shape having the minimum surface area
The reflective lowering of sapour pressure of a solution containing
6
g
of urea dissolved in
90
g
of water is ?
Report Question
0%
0.0196
0%
0.05
0%
1.50
0%
0.01
Which is not correct in terms of kinetic theory of gases-
Report Question
0%
Gases are made up of small particles called molecules
0%
The molecules are in random motion
0%
When molecules collide, they lose energy
0%
When the gas is heated, the molecules moves faster
Explanation
Gases are made up of small particles called molecules is a postulate of kinetic theory of gases, rest all are assumptions of kinetic theory of gases.
Hence, Option "A" is the correct answer.
A box of
1
L
capacity is divided into two equal compartments by a thin partition which are filled with
2
g
H
2
and
16
g
C
H
4
respectively. The pressure in each compartment is recorded as
P
atm. The total pressure when partition is removed will be:
Report Question
0%
P
0%
2
P
0%
P
/
2
0%
P
/
4
The vapour pressure of a solution at
100
o
C
containing
3
g
of cane sugar in
70
g
of water? (vapour pressure of water at
100
o
C
=
760
m
m
of
H
g
) is)
Report Question
0%
758
m
m
of
H
g
0%
730.36
m
m
of
H
g
0%
400
m
m
of
H
g
0%
700
m
m
of
H
g
The volume of a gas is held constant while its temperature is raised. The pressure of the gas exerts on the walls of the container increases because:
Report Question
0%
The masses of the molecules increases
0%
Each molecule loses more kinetic energy when it strikes the wall
0%
The molecules collide with the wall with relatively greater momentum
0%
The molecules strikes the walls more often
Explanation
Volume is kept constant and temperature increased.
We have relation,
P
V
=
n
R
T
P
∝
T
Volume constant
So,
P
∝
T
pressure increases as temperature increases.
As we know the speed or average molecular speed depend on temperature.
As temperature increases molecules collide with wall with greater force or momentum.
Also temperature increases, molecular vibrations increases. So molecule will strike with wall more often.
So option C and D.
A is incorrect because there is no change in masses of molecule when we increase temperature.
The vapour pressure of pure
C
H
C
l
3
and
C
H
2
C
l
2
are
200
and
41.5
a
t
m
respectively. The weight of
C
H
C
l
3
and
C
H
2
C
l
2
are respectively
11.9
g
and
17
g
m
. The vapour pressure of solution will be
Report Question
0%
80.5
0%
79.5
0%
94.3
0%
105.5
Explanation
P
C
H
C
l
3
0
=
200
a
t
m
P
C
H
3
C
l
2
0
=
41.5
a
t
m
n
=
11.9
119
n
=
17
85
=
.1
=
.2
P
T
=
P
0
A
X
A
+
P
0
B
X
B
=
200
x
0.1
.3
+
41.5
×
0.2
.3
=
94.33
.
A pre-weighed vessel was filled with oxygen at
N
T
P
and weighed. It was then evacuated, filled with
S
O
2
at the same temperature and pressure and again weighed. The weight of oxygen is ______________.
Report Question
0%
the same as that of
S
O
2
0%
1
2
that of
S
O
2
0%
twice that of
S
O
2
0%
1
4
that of
S
O
2
Explanation
At constant temperature and pressure, an equal volume of gas contains an equal number of moles.
∴
Moles of
O
2
=
Moles of
S
O
2
1
m
o
l
e
O
2
=
32
g
1
m
o
l
e
S
O
2
=
64
g
∴
w
t
of
O
2
=
1
2
that of
S
O
2
Option
B
is correct.
If water vapor comprises 3.5 percent of an air parcel whose total pressure is 1,000 mb, the water vapor pressure would be:
Report Question
0%
1,035 mb
0%
35 mb
0%
350 mb
0%
965 mb
The vapour pressure of pure
M
and
N
are
700
mm of
H
g
and
450
m
m
of
H
g
respectively.which of the following option is correct?
Given :
X
N
,
X
M
- mole fraction of
N
and
M
in liquid phase
Y
N
,
Y
M
= mole fraction of
N
and
M
in vapour phase.
Report Question
0%
X
M
−
X
N
>
Y
M
−
Y
N
0%
X
M
X
N
>
Y
M
Y
N
0%
X
M
X
N
<
Y
M
Y
N
0%
X
M
X
N
=
Y
M
Y
N
Explanation
Solution:- (C)
X
M
X
N
<
Y
M
Y
N
Mole fraction of more voltatile component increase in vapour phase, i.e.,
P
o
N
<
P
o
M
On increasing the altitude at constant temperature, vapour pressure of liquid
Report Question
0%
increases
0%
decreases
0%
remains the same
0%
depends upon climate
Explanation
Vapour pressure
is a
temperature
dependent phenomena and it does not change unless
temperature
is changed.
On increasing altitude
, the outside
pressure
decreases and to maintain that the rate of evaporation and condensation also changes which keeps
vapour pressure constant
. So answer is option C.
A closed vessel contains equal number of nitrogen and oxygen molecules at a pressure of
p
m
m
. If nitrogen is removed from the system then the pressure will be:
Report Question
0%
p
0%
2
p
0%
p
/
2
0%
p
2
Explanation
At constant
V
,
P
∝
n
∴
if no. of moles is halved then pressure will also reduce to
p
/
2
.
Option C is correct.
For a solution formed by mixing liquids
L
and
M
, the vapour pressure of
L
plotted against the mole fraction of
M
in solution is shown in the following figure. Here
x
L
and
x
M
represent mole fractions of
L
and
M
respectively in the solution. The correct statement
(
s
)
applicable to this system is
(
a
r
e
)
Report Question
0%
The point
Z
represents vapour pressure of pure liquid
M
and Raoults law is obeyed from
X
L
=
0
to
X
L
=
1
.
0%
Attractive intermolecular interactions between
L
−
L
in pure liquid
L
and
M
−
M
in pure liquid
M
are stronger than those between
L
−
M
when mixed in solution.
0%
The point
Z
represents vapour pressure of pure liquid
M
and Raoults law is obeyed when
X
L
→
0
.
0%
The point
Z
represents vapour pressure of pure liquid L and Raoults law is obeyed when
X
L
→
1
Explanation
We know from Raoult's law,
P
=
P
o
L
x
L
+
P
M
o
x
M
Vapour Pressure of liquid,
P
L
=
P
L
o
x
L
=
P
o
L
(
1
−
x
M
)
at
x
M
→
0
or
x
L
→
1
∴
P
L
=
P
L
o
This follows the graph at point Z
Option D is correct.
The statement B is also correct because the attraction in like molecules are more than that in unlike molecules.
Option B is also correct.
Ans- B, D.
Select the incorrect order of boiling point between the following compounds :
Report Question
0%
N
3
H
<
C
H
3
N
3
0%
M
e
2
S
O
4
<
H
2
S
O
4
0%
M
e
3
B
O
3
<
B
(
O
H
)
3
0%
B
F
3
<
B
I
3
Explanation
→
Boiling point of
H
N
3
>
C
H
3
N
3
as in hydrazoic acid (
H
N
3
) intermolecular H-bonding occurs and its bond energy is higher than weak dipole-dipole interactions present in
C
H
3
N
3
.
→
Boiling point of
B
I
3
is greater than that of
B
F
3
as molecular weight of
B
I
3
is higher than that of
B
F
3
.
→
Due to intermolecular H-bonding in
H
2
S
O
4
its boiling point is higher than
M
e
2
S
O
4
.
→
Similarly due to intermolecular H-bonding in
B
(
O
H
)
3
its boiling point is higher. than that of
M
e
3
B
O
3
.
Which of the given laws of chemical combination is satisfied by the figure?
Report Question
0%
Law of multiple proportion
0%
Gay Lussac's law
0%
Avogadro law
0%
Law of definite proportion
What is air?
Report Question
0%
Stone
0%
Element
0%
Compound
0%
Mixture
Directions: In the following questions, a statement of assertion is followed by a statement of reason. Mark the correct choice as :
Assertion: At equilibrium, vapour phase will be always rich in component which is more volatile.
Reason: The composition of vapour phase in equilibrium with the solution is determined by the partial pressures of the components.
Report Question
0%
If both assertion and reason are true and reason is the correct explanation of assertion.
0%
If both assertion and reason are true but reason is not the correct explanation of assertion.
0%
If assertion is true but reason is false.
0%
If both assertion and reason are false.
1 mole of chlorine and 1 mole of hydrogen were taken in a 10 L evacuated flask along with a little charcoal. The flask was then irradiated with light until the reaction was complete. Subsequently, 5L of water was introduced into the flask and the flask was cooled to
27
o
C
. The pressure exerted by the system is approximately equal to:
[Aqueous tension at
27
o
C
=
26
m
m
]
Report Question
0%
98.5 mm
0%
26 mm
0%
52 mm
0%
76 mm
Explanation
Since,
H
C
l
is highly soluble in water, no gas is present in the flask. The pressure exerted is by water vapour which is equal to aqueous tension i.e., 26 mm at
27
o
C
.
According to the kinetic theory of gases, in an ideal gas, between two successive collisions, a gas molecule travels:
Report Question
0%
in a wavy path
0%
in a straight line path
0%
with an accelerated velocity
0%
in a circular path
Explanation
According to the postulates of kinetic theory of gases, the molecules of a gas move in a straight line between two successive collisions. They change their path only when they suffer collisions with the other molecules or with the walls of the container.
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Practice Class 11 Medical Chemistry Quiz Questions and Answers
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