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CBSE Questions for Class 12 Medical Chemistry Alcohols, Phenols And Ethers Quiz 1 - MCQExams.com
CBSE
Class 12 Medical Chemistry
Alcohols, Phenols And Ethers
Quiz 1
The IUPAC name of
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Identify:
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Which of the following is the best set of reagents to perform the above conversion?
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$$ThO_{2},\Delta $$
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$$H_{3}PO_{4},\Delta $$
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$$conc.H_{2}SO_{4},\Delta $$
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$$Al_{2}O_{3},\Delta $$
Major product of the following reaction is
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The order of melting point of ortho, para, meta-nitrophenol is
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$$o\gt m\gt p$$
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$$p\gt m\gt o$$
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$$m\gt p\gt o$$
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$$p\gt o\gt m$$
The IUPAC name of
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Propene is subjected to acidic hydration and hydroboration oxidation in two different experiments. The products obtained respectively are
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n-propyl alcohol, n-propyl alcohol
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isopropyl alcohol, isopropyl alcohol
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n-propyl alcohol, isopropyl alcohol
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isopropyl alcohol, n-propyl alcohol
What is the major product A?
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What is the reagent used and appropriate temperature required to prepare ethene from ethyl alcohol?
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Dilute $$ H _ { 2 } S O _ { 4 } , 160 ^ { \circ } C $$
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Concentrated $$ H _ { 2 } S O _ { 4 } , 170 ^ { \circ } C $$
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Dilute $$ H C l , 170 ^ { \circ } C $$
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Concentrated $$ H C l , 160 ^ { \circ } C $$
Dehydration of alcohol to alkene involves all the steps, except:-
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combination with proton
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formation of cabonium ion by removal of water molecule
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loss of proton from carbonium ion from the $$ \beta $$-position
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loss of proton from carbonium iron from $$ \alpha $$-position
In which of the following the experimental dipole moment is more than what is expected from theory?
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All of these
The sum of locants of the compound is _________
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10
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8
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9
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7
Which of the following is correct for acidic strength:-
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B and C
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C and D
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B and D
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A,B and C
Examine the following structures:-
$$(A)$$ $$(CH_3)_3C-OH$$
$$(B)$$ $$(CH_3)_3C-NH_2 $$
Which of the following statement is correct ?
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A is tertiary alcohol while $$ B $$ is tertiary amine.
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A is primary alcohol while $$ B $$ is primary amine.
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$$ \mathrm{A} $$ is tertiary alcohol while $$ \mathrm{B} $$ is primary amine.
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A is primary alcohol while $$ B $$ is tertiary amine.
In the following reaction A and B respectively are
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$${ 3 }^{ \circ }$$ and $${ 1 }^{ \circ }$$ alcohols
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$${ 3 }^{ \circ }$$ and $${ 2 }^{ \circ }$$ alcohols
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Both $${ 2 }^{ \circ }$$ alcohols
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$${ 2 }^{ \circ }$$ and $${ 1 }^{ \circ }$$ alcohols
.
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both A and B will form
Which of the following will be the correct product of reaction?
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The major product in the acid catalysed dehydration of 2-pentanol is
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Pent-1-ene
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Pent-2-ene
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Pent-3-ene
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Methylbut-1-ene
$$Compound( Refer \ Image)\xrightarrow [ Conc.{ H }_{ 2 }{ SO }_{ 4 } ]{ \triangle } $$
The major product obtained in the above reaction is:
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Which of the following is most reactive toward acid catalyzed dehydration?
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The IUPAC name of the compound is
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1, 1-Dimethyl-3-cyclohexanol
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1, 1-Dimethyl-3-hydroxycyclohexane
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3,3-Dimethyl-1-cyclohexanol
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3, 3-Dimethyl-1-hydroxycyclohexane
Explanation
Optic C is correct answer
Ethers show dipolar nature due to the presence of ______.
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central C atom
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central O atom
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central N atom
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none of these
Explanation
Ethers have general structural formula R-O-R'. Hence all of them have the C-O bond. We know that the C-O bond is polar due to the difference between the electronegativities of carbon and oxygen. Hence, ethers show dipolar nature.
State, whether the following statements are True or False:
Phenols having electron withdrawing group or groups attached to benzene ring are more acidic than phenol itself.
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True
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False
Explanation
Phenols with electron withdrawing groups are more acidic because of the inductive effect.
State, whether the following statements are True or False:
$$C_2HSOC_2H5$$ is a linear molecule having zero dipole moment.
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True
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False
Cresols are
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Hydroxy toluenes
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Dihydric phenols
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Trihydric phenols
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Trihydric alcohols
Explanation
Cresols are basically Hydroxy toluenes.
Hence option A is correct.
IUPAC name of tertiary butyl alcohol is
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Butan-1-ol
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Butan-2-ol
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2-methyl propan-1-ol
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2-methyl propan-2-ol
Explanation
IUPAC name of tertiary butyl alcohol is 2-methylpropan-2-ol.
Wood spirit is known as
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Methanol
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Ethanol
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Acetone
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Benzene
Explanation
Methanol is also referred as wood alcohol or wood spirit or wood naphtha as the earliest method for its preparation was by destructive distillation of wood.
The IUPAC name of picric acid is
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$$2,4,6-$$trinitrophenol
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$$2,4,6-$$trinitrobenzoic acid
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$$4-$$nitrophenol
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None of these
Explanation
The IUPAC name of picric acid is $$2,4,6-$$trinitrophenol.
The $$IUPAC$$ name of compound $$\begin{matrix} \quad \quad O{ CH }_{ 3 } \\ | \\ { CH }_{ 3 }-{ CH }_{ 2 }-CH-{ CH }_{ 2 }-OH \end{matrix}$$ is
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$$2-$$methoxy$$-1-$$butanol
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$$3-$$methoxy$$-1-$$butanol
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$$2-$$methoxy$$-1-$$butanol
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$$1,2-$$methoxy$$-$$butanol
The structural formula of cyclohexanol is
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3-pentanol is a:
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Primary alcohol
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Secondary alcohol
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Tertiary alcohol
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None of these
Explanation
3-pentanol is a secondary alcohol as it is connected to secondary carbon (conected to two carbon atom).
Hence, option $$B$$ is correct.
General formula of primary alcohol is
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$$>CHOH$$
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$$-CH_2OH$$
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Explanation
$$-OH$$ group is attached to primary carbon.
Which of the following is phenolic
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Phthalic acid
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Phosphoric acid
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Picric acid
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Phenylacetic acid
Explanation
Picric acid is phenolic while others are non phenolic
Which one of the following is not a correct statement?
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Phenol is a much weaker acid than benzoic acid
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The reaction of ferric chloride with phenol to give violet colour is characteristic of ethanol group
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Phenol is a stronger acid than ethanol but weaker than benzyl alcohol
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Picric acid does not contain a COOH group.
Explanation
Hence, Option B, C are correct answer.
Find the structure of product.
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Which of the following is not the product of dehydration of above compound?
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Reactivity of given alcohols for acidic dehydration can be explained by ______________
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Carbocation stability
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Product stability
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Carnbanion rearrangement
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Acidic strength of alcohols
In the following reaction the major product is:
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The major product "P" obtained in the given reaction is:
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Among the following the most stable compound is
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cis-1,2-cyclohexanediol
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trans-1,2-cyclohexanediol
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cis-1,3-cyclohexanediol
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trans-1,3-cyclohexanediol
Which has dipole moment?
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p-dimethoxybenzene
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p-dichlorobenzene
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trans 1,2-dichloroethene
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$${ BF }_{ 3 }$$
Correct name of the given compound is
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$$(2R, 3E) 4$$-bromo pentan-$$2$$-ol
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$$(2S, 3E) 4$$-bromo pentan-$$2$$-ol
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$$(2R, 3Z) 4$$-bromo pentan-$$2$$-ol
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$$(2S, 3Z) 4$$-bromo pentan-$$2$$-ol
Five compounds with molecular formula $${ C }_{ 4 }{ H }_{ 8 }{ Br }_{ 2 }$$. How many structures of $$X$$ are possible?
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2
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5
Suppose your blaboratory has only $$C{H_3}OH$$ as organic compound and all the inorganic chemicals are available. How will you synthesize the following alcohols?
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$$C{H_3} - C{H_2} - OH$$
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The correct IUPAC nomenclature for the following alcohol is:
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2-ethyl-2 butanol
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3-methyl-3 pentanol
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3-ethyl-3-methyl-3 pentanol
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1,1 -diethylene
Which of the following is represented by general formula $$C_{n} H_{2n + 2} O$$?
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Alcohols only
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Both alcohols and ethers
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Aldehydes only
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Both aldehydes and ketones
Find the compound '$$Z$$'.
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$$\rm{ CH_2=CH-CH_2-OH }$$
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$$\rm{ CH_3-CH(OH)-CH_3 }$$
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$$\rm{ (CH_3CH_2)CHOH }$$
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$$\rm{ CH_3CH=CH_2 }$$
The major product is:
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Which of the following alcohol will have highest rate of dehydration?
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Which one has minimum $$\%$$ of enol content?
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Practice Class 12 Medical Chemistry Quiz Questions and Answers
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