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CBSE Questions for Class 12 Medical Chemistry Aldehydes, Ketones And Carboxylic Acids Quiz 11 - MCQExams.com

RCH2CH2OH can be converted to RCH2CH2COOH. The correct sequence of reagents is:
  • PBr3,KCN,H3O+
  • PBr3,KCN,H2
  • KCN,H+
  • HCN,PBr3,H+
Oxidation of cyclohexene in presence of acidic potassium permanganate leads to.
  • Glutaric acid
  • Adipic acid
  • Pimelic acid
  • Succinic acid
Which of the following compound upon oxidation gives isophthalic acid?
  • p-Xylene
  • m-Xylene
  • o-Xylene
  • m-Cresol
Trichloroacetaldehyde, CCl3CHO reacts with chlorobenzene in presence of sulphuric acid and produces:
Which of the following is not a final product obtained by cross aldol condensation of ethanal and propanal?
  • 3-Methyl-but-2-enal
  • 2-Methyl-pent-2-enal
  • But-2-enal
  • Pent-2-enal
Which is the main functional group in Acrolein?
  • Aldehyde
  • Alkene
  • Nitrile
  • Ester
In the given reaction sequence :
874674_72dd80759179427cb0fae2b660a546ee.png
Among the following sets of reactants, which one produces anisole?
  • CH3CHO;RMgX
  • C6H5OH;NaOH;CH3I
  • C6H5OH;neutral FeCl5
  • C6H5CH3;CH3COCl;AlCl3
Identify the structure of M in the following sequence of reactions.
876713_ebc1943bf87c4161b1c985aef5948083.png
What is the formula of Acrolein?
  • CH2=CHCHO
  • CH2=CHCN
  • CH2=CNCOOH
  • CH2=CHCONH2
Which will undergo Friedel-Crafts alkylation reaction?
Which of the following reaction end with the same product?
876873_e36d55b19d704f67a54ca455cfd4170b.JPG
  • a, b, c
  • a, c
  • b, c
  • a, b
Which is the correct method of synthesising acetamide from acetone?
  • CH3COCH3Pd/BaSO4CH3CHONH3CH3CH2NH2H2OCH3CONH2
  • CH3COCH3I2NaOHCH3COONaH+NH3CH3COONH4ΔCH3CONH2
  • CH3COCH3CrO3CH3COOHNH3CH3CONH2
  • CH3COCH3I2NaOHCH3COOHHClCH3COClNH3CH3CONH2
The final product (Y) in the following sequence of chemical reaction is:
CH3OHCu300oCXNaOHY+CH3OH
  • an alkene
  • a carboxylic acid
  • an aldehyde
  • sodium salt of carboxylic acid
The addition of HCN to carbonyl compounds is an example of:
  • nucleophilic addition
  • electrophilic addition
  • free radical addition
  • electromeric addition
Acetic acid is obtained when:
  • methyl alcohol is oxidised with potassium permanganate
  • calcium acetate is distilled in the presence of calcium formate
  • acetaldehyde is oxidised with potassium dichromate and sulphuric acid
  • glycerol is heated with sulphuric acid
CH3CH=CHCHOOH/H2OΔ
The major product which can be isolated from this reaction is:
  • CH3COOH
  • CH3CHO
  • CH3CH2OH
Which of the following would be the best synthesis of 2,2dimethyl propanoic acid?
When a nucleophile encounters a ketone, the site of attack is:
  • the carbon atom of the carbonyl
  • the oxygen atom of the carbonyl
  • both the carbon and oxygen atoms, with equal probability
  • no attack occurs as ketones do not react with nucleophiles
Ph2CHO||CHaqueousacid(A)81%+enol2%+aldehyde17%
Product (A) of given reaction will be.
  • PhC|Ph=CHO
  • Ph2CHOH|CH2
  • Ph2CHOH|CHOH
  • Ph2CHO||CCH3
Identify (X), (Y) and (Z) in the given reaction.
CH3CHOK2Cr2O7H2SO4(X)PCl5(Y)C6H6anh.AlCl3(Z) :
  • (X)=HCOOH,(Y)=COCl2,(Z)=C6H5Cl
  • (X)=CH3COOH,(Y)=CH3COCl,(Z)=C6H5COCH3
  • (X)=CH3COOH,(Y)=CH3CH2CH2Cl,(Z)=C6H5CH2CH2CH3
  • (X)=CH3COCH3,(Y)=CH3CH(Cl)CH3,(Z)=C6H5COCH3
Which of the following compounds are not oxidized by HIO4?
992778_0feec9175fab49f2b00bf01d54a478e5.png
  • 5,6,7
  • 4,5,6,7
  • 6,7
  • 3,4,5,6,7
Which of the following compounds is most reactive towards nucleophilic addition reactions?
  • CH3O||CCH3
  • CH3O||CH
The reaction of C6H5CH=CHCHO with LiAlH4 gives.
  • C6H5CH2CH2CH2OH
  • C6H5CH=CHCH2OH
  • C6H5CH2CH2CHO
  • C6H5CH2CHOHCH3
Compound(x) in the given reaction is:
991951_d99c9af2734248f8bdaaf5066c4cb2a1.png
  • PhO||CCH3
  • PhO||CH
  • PhCH2O||CH
  • PhCH2O||CCH3
Given the major organic product of the following reaction.
993118_aa49546cca0a4793aa118ef631373f39.png
Complete the reactions with appropriate products.
(i) CH3CHO+NH2OHX
(ii) CH2=CH2+PdCl2+H2OCuCl2Y
(iii) CH3CH2CH2CH2OHCrO3H2SO4Z
  • X=CH3CH=NOH,Y=CH3CHO,Z=CH3CH2CH2COOH
  • X=CH3CH2NH2,Y=CH3CH2CHO,Z=CH3CH2CH2COOH
  • X=CH3CONH2,Y=HCHO,Z=CH3COCH3
  • X=CH3CN,Y=CH3CHO,Z=HCOOH
Consider the following sequence of reactions. The final product (B) is?
995600_e4069b8d175c4726a01a983d08ab88cc.png

The product of acid hydrolysis of [P] and [Q] can be distinguished by:
1103454_f39cf3018f324f9daaefaac62eb4d194.png
  • Lucas reagent
  • 2,4-DNP
  • Fehling's solution
  • NaHSO3
Product (x) in this reaction is: 
1055373_b50bb660e4c74503971eafb7530c2aa7.png
Above compound is hydrated maximum at which position?
996185_acc283282d7e4601bf2d3aa981690ed6.png
  • 1
  • 2
  • 3
  • equal
Which of the following carboxylic acids undergoes decarboxylation most easily on heating?
  • CH3CH2COOH
Product (D) in above reaction is:
993120_c1529ed34f1b4b798e9f1204b0fd2969.png
Which of the following has lowest pKa value?
The compound (C) is:
1068135_e886fd3ae1a44cc58e305de6ca0de775.png
The IUPAC name of the compound is:
1087930_573c7a3e8ba943fd9b2f3f4aa2e55de8.png
  • 2ethyl3methylcyclohexa1,3diene
  • 2,5dimethylhepta2,6dienoic acid
  • 3bromo2methylbutanoic acid
  • 3bromo2,3dimethylbutanoic acid
The major product in the reaction of α-bromo cyclohexanone with potassium ethoxide is?
Arrange the following compounds in decreasing order of reactivity towards nucleophilic addition reaction:

I) C6H5COCH3
II) CH3COCH3
III) CH3CHO
  • I > II > III
  • III > II > I
  • II > I > III
  • III > I > II

Choose the compound D from the following.
1133105_1a3e845295264c3b81b5921ed8b90444.PNG
In the reaction CH3OH HCOOH, the number of electrons that must be addad to the right is :
  • 4
  • 3
  • 2
  • 1
Which of the following is correct?
  • Aldehydes undergo Cannizzaro's reaction
  • Aldehydes are less susceptible to oxidation than ketones
  • Aldehydes are more susceptible to oxidation than ketones
  • Formaldehyde forms CuO with Fehling's solution
NaOH(aq)
1150607_992968f5db5a4d8ba5ff0443cb4d531f.png
Identify the products(s) obtained in the following reaction
1151925_76f7c13eb81a405ca078ef2235927343.PNG
  • CH3COOH
  • CH3CH2CH2COOH
  • CH3CH2COOH
  • All of these
Possible product of the following reaction is:

CH3CHO+CH3CH2CHO(i)NaOH(ii)Δ
  • CH3CH2CH2OH
  • CH3CH=CH3|CCHO
  • CH3CH2CH=CHCH2OH
  • CH2=CHCHO

The correct IUPAC name of the compound is:
1141529_551054bb13aa4ee188328a38936420cf.PNG
  • 3-amino-6-bromocyclohexane-1-carboxylicacid
  • 2-bromo-5-aminocyclohexane-1-carboxylic acid
  • 5-amino-2-bromocyclohexane-1-carboxylic acid
  • 2-bromo-5-carboxycyclohexanamine
Which of the following will not form acetyl chloride with PCl5
  • MeCOOH
  • MeCOOMe
  • MeCOOCOMe
  • MeCONH2
Cyanohydrin of which of the following gives lactic acid on hydrolysis ?
  • CH3COCH3
  • CH3CHO
  • C6H5CH2CHO
  • HCHO
Product (C) of the reaction is:
1166694_59c8e1b59e4e4bb490860cd7a6c71e30.PNG
Among the following which one is least soluble in water?
  • HCHO
  • CH3CHO
  • CH3CH2CH2CHO
  • CH3CH2CH2CH2CH2CHO
Increasing order of equilibrium constant for the formation of a hydrate is: 
1173465_9f36f0ac42f343148242acfa8ba9c0a0.png
  • i < ii < iii < iv
  • iv < ii < i < iii
  • ii < iv < iii < i
  • iv < ii < iii < i
0:0:3


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