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CBSE Questions for Class 12 Medical Chemistry Aldehydes, Ketones And Carboxylic Acids Quiz 7 - MCQExams.com

RO||CClNaN3conc.H2SO4CH3Cl(1eqvt.)P(Major product)Hence, Product (P) is:
  • RNH2
  • RNHCH3
  • RO||CNHCH3
  • RNHO||CCH3
 The Compound E is:
1116424_4d8de423eeef4bf7adfa984faf8c6887.png
  
1131557_7d04cbb0f977491094c06998e0e033b9.png
C4H8O2 represents:
  • an acid only
  • an ester only
  • an ketone only
  • an acid and an ester also
Product is
1135887_205c421e05094fb486e936d1fc72b11d.PNG
When o-xylene is oxidised with alkaline KMnO4, the product is:
  • Terephthalic acid
  • Phthalic acid
  • Benzoic acid
  •  Salicylic acid
A tripeptide x on partial hydrolysis gave two dipeptides Cys-Gly and Glu-Cys.
Identify the tripeptide,
+NH3CH2CH2COOH|CHC||OGluCysNHCH2SH|CHC||OO
and 
+NH3CH2SH|CHC||OCysGlyNHCH2C||OO
  • Glu-Cys-Gly
  • Gly-Glu-Cys
  • Cys-Gly-Glu
  • Cys-Glu-Gly
Find the output
1135872_4c49f5f030094ead89a58592f9f122fa.png
Which of the following compounds gives an explosive on decarboxylation?
  • 2,4,6trinitrobenzoic acid
  • 2,4dinitrobenzoic acid
  • oaminobenzoic acid
  • ohydroxy benzoic acid
Identify X
1135753_f9a0138e6a2b4fc8b4c5d9126e517cc8.png
Which of the following substituted carboxylic acids has the highest Ka value?
Which of the following is/are more reactive towards nucleophilic addition reactions?
  • CH3COCH3
  • HCHO
  • CH3CHO
  • C2H5CHO
When the reaction of Br2 with acetone is catalysed by hydroxide ion, which of the following are the likely products ?
  • CHBr3 and acetate ion
  • Bromoacentic acid
  • Tribromoacetic acid
  • Acetyl bromide
  
1172696_bc97f71615374eada93e48ff760cb23d.png
What will be the prefix in the following compound ?
HOOC - CH-2 - \overset{\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!\!HOOC - CH_2}{\overset{\!\!\!\!\!|}{CH}} - CH_2 - CH_2 - COOH
  • methycarboxy
  • carboxymethyl
  • carboxyethyl
  • ethylcarboxy
The product "A" in the above reaction is:
1166658_93a3dcac7a324c0cb4ca2a5d0139eff5.png
Hunsdiecker reaction involves the conversion of
  • RCOOAg to RCl using {Cl}_{2}
  • RCOOAg to {(RCO)}_{2}O using RCOCl
  • RCOOAg to RCOOR using {I}_{2}
  • All the above
Compound X produces a carboxylic acid when heated under reflux with acidified potassium dichromate(VI). Compound X does not react with sodium metal.
What could be the identity of compound X?
  • Propanal
  • Propanone
  • Propan-1-ol
  • Propan-2-ol
Find the end product of reaction.
1631510_8c7c0f8e589245638656f0293d3b3c6e.png
What is I and name of reaction?
1587700_1fd21ff5d05e4aa393581b4884d25d12.PNG
  • Aniline, Hoffmann bromamide reaction
  • Sodium benzoate and Cannizaro reaction
  • Phenyl isocyanide and cannizaro
  • Phenyl isocyanide and carbylamine test
Which product is formed when 3-methylpentane-1, 3, 4-triol is heated under reflux with an excess of acidified potassium dichromate(VI)?
  • HO_2CCH_2C(CH_3)(OH)COCH_3
  • HO_2CCH_2COC(OH)(CH_3)_2
  • OHCCH_2C(CH_3)(OH)COCH_3
  • HO_2CCH_2CO(CH_3)COCH_3
 
1631253_df151ce025d14f648d3a7648ae275ff9.PNG
Alcohols, aldehydes and nitriles can each be converted into carboxylic acids. Which descriptions of their conversions into carboxylic acids are correct?

alcoholsaldehydesnitriles
Ahydrolysishydrolysishydrolysis
Bhydrolysishydrolysisoxidation
Coxidationoxidationhydrolysis
Doxidationoxidationoxidation
  • A
  • B
  • C
  • D
What are the suitable reagent for following conversion
  • Br_2/FeBr_3, KMnO_4, HNO_3 / H_2SO_4
  • KMnO_4, Br_2/ FeBr_3, HNO_3
  • HNO_3, Br_2 / FeBr_3, KMnO_4
  • HNO_3, KMnO_4, Br_2 / FeBr_3
The correct product of the following reaction is: 
1611926_f7e95fc7f2424a588d01567ca0167249.png
Which of the following is isobutyric acid?
  • {CH}_{3}{CH}_{2}{CH}_{2}COOH
  • {({CH}_{3})}_{2}CHCOOH
  • {CH}_{3}{CH}_{2}COOH
  • (C_2H_5)CH(CH_3)COOH
The general formula {C}_{n}{H}_{2n}{O}_{2} could be for open chain:
  • diols
  • diketones
  • carboxylic acids
  • dialdehydes
 Which one of the following statements is wrong?
  • Aldehydes and ketones are good reducing agents
  • Aldehydes and ketones are polar compounds
  • Aldehydes are more reactive than ketones
  • Aldehydes and ketones are reduced to alcohols
{CH}_{3}CH_{2}I\xrightarrow [  ]{ KCN } \xrightarrow [ \Delta  ]{ { H }_{ 2 }O }
here the end product would be:
  • 2-cyanorpopanoic acid
  • ethane-1,1-dicarboxylic acid
  • 2-methyl ethanoic acid
  • propanoic acid
Aldehydes are more reactive than ketones. 
  • True
  • False
Which of the following has the highest p{K}_{a} value?
Aldehydes are sweet smelling while ketones have pungent smell. 
  • True
  • False
Carbonyl compounds undergo nucleophilic addition.
  • True
  • False
Which of the following as the lowest p{K}_{a} value?
State, whether the following statements are True or False:
Benzamide on treatment with NaOH and Br_{2} forms benzoic acid.
  • True
  • False
Which of these does not contain -COOH group?
  • Aspirin
  • Benzoic acid
  • Picric acid
  • Salicylic acid
The compound is used as
1725033_5a46a226207e4c7f9722377ccae89d4e.jpg
  • Antiseptic
  • Antibiotic
  • Analgesic
  • Pesticide
Which of the following has lowest pK_{a} value?
 Soaps can be classified as:
  • carbohydrates
  • ethers
  • salts of fatty acids
  • none of these
The IUPAC name of the following compound is

\begin{matrix} HOOC & - & { CH }_{ 2 } & - & CH & - & { CH }_{ 2 } & - & { CH }_{ 2 } & - & COOH \\  &  &  &  & | &  &  &  &  &  &  \\  &  &  &  & COOH &  &  &  &  &  &  \end{matrix}
  • 2-(Carboxy methyl)-pentane-1,5-dioic acid
  • 3-Carboxy hexane-1,6-dioic acid
  • Butane-1,2,4-tricarboxylic acid
  • 4-Carboxy hexane-1,6-dioic acid
  • 1,2 dicarboxypentanoic acid
The general formula for monocarboxylic acids is
  • C_nH_nCOOH
  • C_nH_{2n+1}COOH
  • C_nH_{2n-1}COOH
  • C_nH_{2n}O_2
Write the IUPAC name of CH_3CH_2COOH.
  • Ethyl formic acid
  • Ethyl carboxylic acid
  • Ethane methanoic acid
  • Propanoic acid
Which one is called ethanoic acid 
  • HCOOH
  • CH_3COOH
  • CH_3CH_2COOH
  • CH_3CH_2CH_2COOH
The IUPAC name of succinic acid is
  • 1,4-butanedioic acid
  • Dimethyl-2-acid
  • 1,2-dimethyldioic acid
  • None of these
Which of the following statement is correct about tropolone?
1757896_c6f1a7b7f8914570bf8eb40d250286fa.PNG
  • Tropolone has more stability and aromatic character than tropolone.
  • Tropolone has higher dipole moment than tropone.
  • Tropolone has lower boiling point than tropone.
The typical reactions of aldehydes is :
  • Electrophilic addition
  • Nucleophilic substitution
  • Nucleophilic addition
  • Nucleophilic elimination
When toluene is treated with KMnO_{4}, what is produced ?
  • Benzene
  • Chlorobenzene
  • Benzaldehyde
  • Benzoic acid
The above reaction is 
1764709_fb84db5132284b3486f85632a1f3f802.png
  • Electrophilic substitution
  • Electrophilic addition
  • Nucleophilic addition
  • Nucleophilic substitution
Order of reactivity is
  • Acid Chloride > Acid Anhydride > Ester > Amide. 
  • Acid Chloride > Amide > Acid Anhydride > Ester 
  • Amide > Acid Anhydride > Ester > Acid Chloride
  • Ester > Acid Chloride > Acid Anhydride >  Amide. 
By aerial oxidation, which one of the following gives phthalic acid
  • Naphthalene
  • Banzene
  • Mesitylene
  • Toluene
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