Explanation
Hint: The basic character of amines is due to the presence of unshared electron pair on the nitrogen atom, which accepts a proton.
Correct Answer: Option B
Explanation of Correct Option:
The presence of electron-donating group −CH3, increases the electron density on the N atom. So p−toluidine is more basic than aniline.
B A
Explanation of incorrect options:
Final Step: The correct answer is option (B).
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