CBSE Questions for Class 12 Medical Chemistry Organic Compounds Containing Nitrogen Quiz 6 - MCQExams.com

Which is most basic in aqueous solution?
  • $${ CH }_{ 3 }-{ NH }_{ 2 }$$
  • $${ (CH }_{ 3 }{ ) }_{ 2 }{ NH }$$
  • $${ (CH }_{ 3 }{ ) }_{ 3 }N$$
  • $$ph-{ NH }_{ 2 }$$
Which of the following is most basic ?
Which of the following diazonium salt is relatively stable at $$0-{ 5^0 }^{ }C$$?
  • $${ CH }_{ 3 }-N\equiv N{ \} }^{ \oplus }C{ l }^{ - }$$
  • $${ \left( { CH }_{ 3 } \right) }_{ 2 }CH-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }$$
  • $${ C }_{ 6 }{ H }_{ 5 }-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }$$
  • $${ \left( { CH }_{ 3 } \right) }_{ 3 }C-N\equiv N{ \} }^{ \oplus }{ Cl }^{ - }$$
Select the basic strength order of following molecules.
1070928_0e0ec00c5905430e881f78bd70858db0.png
  • $$III > II > I$$
  • $$II > III > I$$
  • $$I > III > II$$
  • $$III > I > II$$
Which of the following conditions is most suitable for the above reaction?

1071115_d828da0bd83243ebb24258fc06195400.png
  • strongly acidic
  • strongly alkaline
  • Slightly alkaine
  • neutral
Which of the following will accept $$H^{+}$$ from $$NH_{4}^{+}$$ ion?
  • $$CH_{3}-CH_{2}-NH_{2}$$
$$H-COOH > Ph-COOH > CH_{3}-COOH$$ (acidic nature)$$CF_{3}-COOH > CCI_{3}-COOH > CH_{2}-COOH$$ (Acidic nature)$$N- methylmethanamine > methanamine > N, N- dimethylmethanamine $$ (Basic nature in aqueous phase)$$N,N- diethlethanamine > N-ethylethanamine > Ethanamine $$ (Basic nature in aqueous phase)Then the correct order is:
  • $$i,ii,iv$$
  • $$ii,iii,iv$$
  • $$i,ii,iii$$
  • $$i,ii,iii,iv$$
Decreasing order of basicity of the three isomers of nitro aniline is:
  • $$p-nitroaniline> o-nitroaniline> m-nitroaniline$$
  • $$p-nitroaniline> m-nitroaniline> o-nitroaniline$$
  • $$m-nitroaniline> p-nitroaniline> o-nitroaniline$$
  • $$m-nitroaniline> o-nitroaniline> p-nitroaniline$$
The order of basic strength of the given basic nitrogen atoms is :
1071049_3db7e6ce80674e8c984144ff30a882da.png
  • $$III > II > I > IV$$
  • $$III > I > II > IV$$
  • $$I > III > II > IV$$
  • $$II > III > I > IV$$
What is the major organic product of the following reaction?
$$ { CH }_{ 3 }{ CH }_{ 2 }{ NHCH }_{ 2 }{ CH }_{ 3 }\longrightarrow $$?
1070105_d1918afaa25e4590a5269c82f867241e.png
The correct sequence regarding base strength of aliphatic amines in aqueous solution is:
  • $${R}_{3}N> {R}_{2}NH> R{NH}_{2}> {NH}_{3}$$
  • $${R}_{2}NH> R{NH}_{2}> {R}_{3}N> {NH}_{3}$$
  • $${R}_{2}NH> {R}_{3}N> R{NH}_{2}> {NH}_{3}$$
  • $$R{NH}_{2}> {R}_{2}NH> {R}_{3}N> {NH}_{3}$$
The correct order of basic strength of the compounds?
1087633_d79c57c1fa2b43c2b1c8a980fc3a9b5e.png
  • $$I > II > III$$
  • $$II > I > III$$
  • $$III > II > I$$
  • $$II > III > I$$
The product 'Y' in the following reaction sequence is:
1306418_f79caca4c9014bcaadf0daced28627e0.PNG
Which of the following Statements is/are correct?
  • $$(SiH_3)_3N $$ is weaker base than $$(CH_3)_3N$$.
  • Amongst $$Cl-Cl$$, $$N-F$$,$$C-F$$ And $$O-F$$ bond is most polar
  • $$OF_2$$ has higher dipole moment than $$H_2O$$
  • An alchohol is less volatile than other having same molecular formula on account of intermolecular hydrogen bonding
This reaction is example of:
1072180_8485f0a384074cf1bb294bfa08b1a12e.png
  • Intermolecular $$C-N$$ coupling
  • Intramolecular $$C-N$$ coupling
  • Intermolecular $$N-N$$ coupling
  • Intramolecular $$N-N$$ coupling
$$sp^3-$$hybridised nitrogen is present in:
  • $$CH_2 = CH - \overset{\oplus}{N}H_3$$
The increasing order of basicity of the given compounds is:
1073927_d90690457a90496a8b8e9d420e6a3f66.PNG
  • (b)< (a)< (c)< (d)
  • (b)< (a)< (d)< (c)
  • (d)< (b)< (a)< (c)
  • (a)< (b)< (c)< (d)
The correct order of increasing basic nature for the bases $$NH_3,CH_3NH_2$$ and $$(CH_3)_2NH $$ is?
  • $$(CH_3)_2NH < NH_3 < CH_3NH_2$$
  • $$NH_3 < CH_3 NH_2 <(CH3)_2NH $$
  • $$CH_3NH_2 <(CH_3)_2NH < NH_3$$
  • $$CH_3NH_2 < NH_3 < (CH_3)_2NH$$
The end product (Z) of the following reaction is?
1096491_ac867f00062c495ea22db5a8add459a8.PNG
  • A cyanide
  • A carboxylic acis
  • An amine
  • An arene
By heating ammonium chloride with two equivalents of formaldehyde it forms:
  • dimethylamine
  • ethylamine
  • methylamine
  • ammonium formate
Find product in the following reaction is Y. What is Y?
1100535_fd88450c89f34990b372bfda600d479c.png
  • benzamide
  • benzophenone
  • benzoic acid
  • benzaldehyde
$$CH_3Cl \xrightarrow{AgCN} A$$ (major) $$\xrightarrow{H-2O^+} C + D$$ here '$$C$$' is formic acid '$$D$$ is:'
  • $$2^o$$ amine
  • Carboxylic acid
  • Alkyl Cyanide
  • $$1^o$$ amine
Reductive amination of $$A$$ forms:
1097811_af3fe33a33654685b77e78a48b8883c4.png
The reactivities of these ions in azo-coupling reactions will be in the order:
1100443_8f40179905124ff092b740cc339cbae0.png
  • $$3<1<4<2$$
  • $$1<4<2<3$$
  • $$1<2<3<4$$
  • $$3<1<2<4$$
In the above reaction sequence (D) is?
1107986_5b367070c49f40c49a152a1f1737a17b.png
Suitable explanation for the order of basic character, $$(CH_{3})_{3}N < (CH_{3})_{2}NH$$, is:
  • steric hindrance by bulky methyl group
  • higher volatility of $$3^{\circ}$$ amine
  • stability of conjugate acid due to solvation
  • all of these
With which one of the following substrate do diazonium salt reacts to form a colourful compound?
In the reaction
$$Me_{3}N \xrightarrow{BrCN} A \xrightarrow[ii)\Delta]{i)H_{2}O}  B$$. 
B is
  • $$MeNH_{2}$$
  • $$Me_{3}NO$$
  • $$Me_{2}NH$$
  • $$Me_{2}NCOOH$$
The reagents/conditions K, L and M are respectively:
1109164_496a758a6c134969a39e7eb8aaf41dad.PNG
  • $$Ba(OH)_{2}$$, $$KCN$$ and $$CHCl_{3} / NaOH$$ heat, $$H_{3}O^{+}$$
  • $$H_{2}O$$ (boil), $$CO_{2} / KOH$$ and $$Ac_{2}O - AcONa$$, heat
  • Steam ; $$CHCl_{3} / NaOH$$, heat, $$H_{3}O^{+}$$ and $$AC_{2}O - AcONa$$, heat
  • $$Cu_{2}Cl_{2} / HCl$$, $$NaOH$$ / high P and $$CO_{2}|NaOH$$, heat
The correct order of boiling points of the following amines $${ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 },\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH,{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }$$ is :
  • $${ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }>\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }$$
  • $$\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }$$
  • $${ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2} >\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }$$
  • $$\left( { C }_{ 2 }{ H }_{ 5 } \right) _{ 2 }NH>{ C }_{ 4 }{ H }_{ 9 }{ NH }_{ 2 }>{ C }_{ 2 }{ H }_{ 5 }N\left( { CH }_{ 3 } \right) _{ 2 }$$
Which of the following compounds is an imine?
$${ C }_{ 3 }{ H }_{ 9 }N$$ represents
  • primary amine
  • secondary amine
  • tertiary amine
  • all of these
The correct order of basicity of the above compounds is:
1115396_6004376d9e8343b0aa4228f35d041adb.png
  • II > I > IIl > IV
  • I > III > II > IV
  • III > I > II > IV
  • I > II > III > IV
Basic nature order of the given compounds is
(a) $$CH_3 - CH = \ddot{N}H $$
(b) $$CH_2= CH - CH = CH -NH_2$$
(c) $$CH_3 -NH - CH_3$$
  • c>a>b
  • a>b>c
  • a>c>b
  • c=a=b
Arrange these compounds in decreasing order of basic strength?
1114581_90f0ec234b934b01a690d491880c13c2.png
  • i > ii > iii > iv
  • ii > iii > i > iv
  • iv > i > iii > ii
  • iv > i > ii > iii
Which of the following is the strongest base?
The decreasing order of the basic character at $$a, b, c, d$$ in the compound:
1114769_e2d98678b84f42e3839a19d8a722ee27.png
  • $$a > c > b > d$$
  • $$d > c > b > a$$
  • $$c > b > d > a$$
  • $$b > c > d > a$$
Arrange the following in order of decreasing basic strength.
1114381_d4de35da2fc34ff2bb059f6704e59fff.png
  • IV > I > II > III
  • IV > I > III > II
  • IV > II > I > III
  • I > II > III > IV
Which of the following is weak base than aniline ?
What is strong base?
An organic compound (A) $$C_9H_{13}N$$ dissolves in dil. HCI and releases $$N_2$$ with $$HNO_2$$ giving an optically active alcohol. Alcohol on oxidation gives dicarboxylic acid, which on heating form anhydride. The organic compound 'A' is :-
The relative basics strenghts of $$NH_{3},CH_{3}NH_{2}$$ and $$NF_{3}$$ are in the order:
  • $$CH_{3}NH_{2} > NH_{3}>NF_3$$
  • $$NF_{3} > CH_{3}NH_{2} > NH_{3}$$
  • $$NH_{3} > CH_{3}NH_{2} > NF_{3}$$
  • $$NF_{3} > CH_{3}NH_{2} = NH_{3}$$
Acetic anhydride with ammonia gives the product:
  • $$ CH_{3}CONH_{2} $$
  • $$ CH_{3}CONHCH_{3} $$
  • $$ CH_{3}CN$$
  • $$ CH_{3}COONH_{4} $$
What will be the final product of the given reaction?
1128733_60f3a693a0854ddba4d6a0b8e6dfa8c8.png
which compound is Prepare propan -I- amine from?
  • Butaniteuie
  • I-Nitropropane
  • Propanamide
  • Butanamide
The major product of the reaction is:
1117541_912c38a07f1b4cf7b242e51183769a8c.GIF
Adrenaline and ephedrine contain:
  • $${1}^{o}$$ amino group
  • $${2}^{o}$$ amino group
  • $${3}^{o}$$ amino group
  • quaternary amino group
Sanger's reagent is used for the identification of:
  • N-thermal of peptide chain
  • C-terminal of a peptide chain
  • side chain of amino acids
  • number of amino acids in peptide chain
Among the following which is not correct?
  • P methyl benzyl carbonyl is more stable than ethyl benzyl carbonyl
  • Aniline is more basic than pyridine
  • Cyclopentadienyl anion is more stable than cyclopentadienyl Carbo cation
  • K of Ethene 1 ol is more than that of propene 2 en 1 ol
$${C}_{6}{H}_{5}-{NO}_{2}\xrightarrow [  ]{ Fe/HCl }  A\xrightarrow [ H{ NO }_{ 3 } ]{ 273K }  B\xrightarrow [  ]{ { C }_{ 6 }{ H }_{ 5 }OH } C$$, $$C$$ is
0:0:1


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