The dehydration of neo-pentanol gives mainly-

  •  

  •  

  •  

  • Nne of the above

Which one of the following on oxidation gives a ketone?                   

  • Primary alcohol                     

  • Secondary alcohol
  • Tertiary alcohol                     

  • All of these

In the following sequence the product (C) is: 

CH3CHOPdH2 (A) Na(B) CH3I(C)

  • alcohol                                 

  • ether
  • alkene                                 

  • none of these

Proof spirit contains about:

  • 48% alcohol by mass

  • 10% alcohol by mass

  • 5% alcohol by mass

  • 90% alcohol by mass

The correct order of solubility of 1°,2° and 3° alcohol in water is-

  • 3°>2°>1° 

  • 1°>2°>3°

  • 3°>1°>2°

  • None of the above

Which of the following is an alkoxide?

  •  

  •  

  •  

  •  

The value of C-O-C angle in ether molecule is :

  • 180°                                     

  • 150° 

  • 90°                                       

  • 110°

Ethyl alcohol is also known as:

  • spirit of wine                         

  • methyl carbinol

  • grain alcohol                           

  • all of these

The products formed in the following reaction, C6H5-O-CH3 + HI Heat are-

  • C6H5OH and CH3

  • C6H5I and CH3OH

  • C6H5CH3 and HOI

  • C6H6 and CH3OI

The formula of phenoxy benzene is-

  • C6H5C6H5                             

  • C6H5-O-C6H5

  • C6H5-O-C6H6                         

  • None of the above

CHCHO3/NAOHXZn/CH3COOHY is: 

  • CH2OH-CH2OH 

  • CH3CH2OH 

  • CH3COOH 

  • CH3OH

Which of the following reacts with water

  • CHCl3                                     

  • CCl4

  • CCl3CHO                               

  • CH2ClCH2Cl

The order of decreasing acidic character of cyclohexanol (I), acetic acid (II), 2,4,6-trinitrophenol (III), and phenol (IV),is -                                                     

  • III>II>IV>I 

  • II>III>I>IV

  • II>III>IV>I 

  •   III>IV>II>I

Picric acid and benzoic acid can be distinguished by:

  • Aqueous NaHCO3                   

  • Aqueous NaOH

  • Aqueous FeCl3                       

  •   Aqueous Na2CO3  

CH3CH2ClNaCNNi/H2YAcetic anhydrideZ

In the above reaction sequence, Z is

  • CH3CH2CH2NHCOCH3

  • CH3CH2CH2NH2

  • CH3CH2CH2CONHCH3

  • CH3CH2CH2CONHCOCH3

The commonly used dehydrating agent in the preparation of an ester is :

  • P2O5                                   

  • Anhydride CaCl2

  • Anhydride AlCl3                     

  • Conc. H2SO4

Oxidation of allylic alcohol, (CH2=CH-CH2OH) gives a mixture of oxalic acid and formic acid. If this oxidation is done in presence of bromine. One would expect only:

  • Oxalic acid

  • Formic acid

  • Succinic acid

  • Acrylic acid

Consider the following reaction, 

Ethanol PBr3XAlc.KOHY(ii)H2O, heat(i) H2SO4, room temperatureZ

The product Z is

  • CH2=CH2

  • CH3CH2OCH2CH3

  • CH3CH2OSO3H

  • CH3CH2OH

Which of the following are known as mercaptans?

  • Thio-alcohols                         

  • Thio-ethers

  • Thio-aldehydes                     

  • Thio-acids

Glycol condenses with ketones to give:

  • Cyclic acetals                   

  • Cyclic ketals
  • Acetaldehyde                   
  • oxalic acid

Salol is used as:

  • antiseptic                               

  • antipyretic

  • both 1. and 2.                     

  • none of these

CH3-CH2-CH2OH 160-180°Cconc. H2SO4 X Br2 Y 2. NaNH21. Alc. KOH Z

Z in the above reaction is -

 

 

 

 

  •  

  •  

  •  

  •  

Ethyl propanoate on reduction with LiAlH4 yields:

  • Methanol

  • Ethanol and Propanol

  • Propane

  • Mixture of ethanol and methanol

The most acidic alcohol among the following is -

  • Methanol                               

  • Ethanol

  • Isopropyl alcohol                     

  • t-Butyl alcohol

Consider the following reaction,

PhenolZn-dustXAnhy.AlCl3CH3ClYAlk.KMnO4Z                                     

The product Z is

  • toluene

  • benzaldehyde

  • benzoic acid

  • benzene

The product in the reaction is:

C2H5OH P+I2AEtherMgBHCHOCH2OD

  • propanal                           

  • butanal

  • n-butanol                         

  •   n-propanol

The compund that reacts fastest with Lucas reagent (at room temperature) is -

  • Butan-1-ol

  • Butan-2-ol

  • 2-Methyl propan-1-ol

  • 2-Methyl propan-2-ol

An alcohol that give CH3COOH and CH3CH2COOH upon oxidation is:

  • CH3CH2CH2OH

  • (CH3)2C(OH)CH2CH3

  • CH3(CH2)2CHOH

  • CH3CH(OH)CH2CH2CH3

R-CHO + H2 RCH2OH,

The catalyst used in the above reaction is -

  • Ni                                         

  • Pd

  • Pt                                         

  • All of above.

Methyl alcohol on oxidation with acidified K2Cr2O7 gives:

  • CH3COCH3                           

  • CH3CHO

  • HCOOH                                   

  • CH3COOH

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