The compound formed when malonic ester reacts with urea is:

  • cinnamic acid

  • butyric acid

  • barbituric acid

  • crotonic acid

The type of isomerism shown by C6H5CN and C6H5NC is:

  • Position

  • Functional

  • enantiomer

  • Tautomerism

Compound that will undergo Hoffmann reaction is-

  •  RCONHCH3

  •  RCOONH4

  •  RCONH2

  •  RCONHOH

The reagent needed to convert acetamide into methyl amine is -

  • NaOH/ Br2

  • Sodalime

  • Hot conc. H2SO4

  • PCl5


The above reaction is an example of....

  • Intermolecular C-N coupling

  • Intramolecular C-N coupling
  • Intermolecular N-N coupling
  • Intramolecular N-N coupling

The hydrochlorides of amines form double salt with: 

  • PtCl4

  • AuCl3

  • both (a) and (b)

  • none of these

Which of the following can not be formed by Gabriel phthalimide synthesis:-

  •  

  •  

  •  (CH3)2CH-NH2

  • C2H5NH2

  •  

  •  Ph-CH2-NH2

  •  

  •  Ph-NC

An amine gives a solid compound that is insoluble in alkali with benzene sulphonyl chloride.

The amine is -

  •  CH3-CH2-NH2

  •  CH3-NH-CH2-CH3

  •  (CH3)3N

  •  C6H5-NH2

The compound A and B respectively are

  • 1
  • 2
  • 3
  • 4

The compound 'B' is-

  •  

  •  

  •  

  •  

Hydrolysis of alkyl isocyanide yields -

  • Primary Amine

  • Tertiary Amine

  • Alcohol

  • Aldehyde


The major product (A) formed in the above mentioned reaction is -

  •  

  •  

  •  

  • None of the above

Which of the following is hydrolyzed to give secondary amine?

 

  •   Alkyl cyanide

  •   HCON\CH3/CH3

  •   Nitroparaffins

  •   Acidamide

Ethylamine reacts with nitrosyl chloride (NOCl) to form:

  • ethyl chloride

  • ethyl alcohol

  • ethyl nitrite

  • nitroethane

Name the end product in the following series of reactions,

CH3COOH NH3ABP2O5C:

  • CH4 

  • CH3OH

  • acetonitrile 

  • ammonium acetate

An organic compound A on reduction gives compound B which on reaction with chloroform and potassium hydroxide forms C. The compound C on catalytic reduction gives N-methylaniline. The compound A is                                                               

  • Nitrobenzene

  • Nitromethane

  • Methylamine

  • Aniline

Acetamide and ethyl amine can be distinguished by reacting with             

  • aq. HCl and heat

  • aq. NaOH and heat

  • acidified KMnO4

  • bromine water

Which of the following compound gives dye test

  • Aniline               

  • Methylamine                 

  • Diphenylamine                 

  • Ethylamine

CH3CH2ClNaCNXNi/H2YAcetic anhydrideZ

In the above reaction sequence, Z is                                  

  • CH3CH2CH2NHCOCH3

  • CH3CH2CH2NH2

  • CH3CH2CH2CONHCH3

  • CH3CH2CH2CONHCOCH3

Predict the product,                               

 

  •  

  •  

  •  

  •  

Aniline in a set of reactions yield the following products                                                   

The structure of the product D would be -

  • C6H5CH2OH

  • C6H5CH2NH2

  • C6H5NHCH2CH3

  • C6H5NHOH

Intermediates formed during the reaction of RCONH2 with Br2 and KOH are -                               

  • RCONHBr and RNCO

  • RNHCOBr and RNCO

  • RNHBr and RCONHBr

  • RCONBr2

In a reaction of aniline a colored product C was obtained.

The structure of C would be

  •  

  •  

  •  

  •  

Product Q in the above reaction is             

  •   

  •   

  •   

  •   

 

C in the above-mentioned reaction is -

  •            

  •  

  •      

  •  

Aniline when diazotised in cold and then treated with dimethylaniline, gives a coloured product. Its structure would be :                                                                                 

  •  

  •  

  •  

What is the end product in the following sequences of operations;

AcetamideP2O5A4HB ?

  • CH3NH                             

  • C2H5NH2

  • CH3CN                                   

  •   CH3COONH4

 are ........... isomers.

  • Chain

  • functional

  • position

  • all of these

Primary nitroalkanes on hydrolysis give:

  •  RCOOH + NH2OH

  •  RCOOH

  • NH2OH

  •  RCOR

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