Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne?       

  • NaNH2

  • HCl

  • O2

  • Br2

 +(CH3)3COH X

The product X in the above reaction is -

  •             

  •         
  •            

  •   

The products formed when meta-xylene is treated with Br2 in the presence of FeBr3 are:-                                                                           

  •  

  •  

  •  

  •  

A compound that is formed on passing chlorine through propene at 400°C is -

  • PVC                       

  •   Allyl chloride  

  • Nickel chloride         

  • 1,2-Dichloro ethane

The reactants used in Friedel-Craft's alkylation are -                             

  • C6H6 + NH2

  • C6H6 + CH4

  • C6H6 + CH3Cl

  • C6H6 + CH3COCl

         KOHKMnO4BFeCl3Br2CH+C2H5OHD

The D in the above mentioned reaction is -

 

  •  

  •  

  •  

  •  

Nitrobenzene on reaction with conc. HNO3/H2SO4 at 80-100°C forms -

  • 1,2-Dinitrobenzene

  • 1,3-Dinitrobenzene

  • 1,4-Dinitrobenzene

  • 1,2,4-Trinitrobenzene

In the following reaction,


Product A is-

  •  

  •  

  •  

  •  

The monochlorinated products (excluding stereo-isomers) obtained from the reaction is:

 

  • 7

3-Hexyne can be converted to trans-3-Hexene by the action of:

  •  H2 - Pd/ BaSO4                       

  • Li-Liq. NH3

  •  H2 - Pt O2                               

  •  NaBH4

A compound having the shortest carbon-carbon bond length among the following is -

  • Benzene                                 

  • Ethene

  • Ethyne                                   

  • Ethane

Reaction of HBr with propene in the presence of peroxide gives

  • iso-propyl bromide

  • 3-bromo propane

  • allyl bromide

  • n-propyl bromide

The reaction of toluene with Cl2 in the presence of FeCl3 gives 'X' and reaction in presence of light gives 'Y'. Thus, 'X' and  'Y' are

  • X = benzal chloride, Y= o-chlorotoluene

  • X = m-chlorotoluene, Y= p-chlorotoluene

  • X = o and p-chlorotoluene, Y = trichloromethyl benzene

  • X = benzal chloride, Y = m-chlorotoluene

When acetylene is passed through dil. H2SO4 in presence of HgSO4, the compound formed is

  • ether 

  • ketone

  • acetic acid

  • acetaldehyde

Acetylenic hydrogens are acidic because

  • sigma electron density of C-H bond in acetylene is nearer to carbon which has 50% s-character

  • acetylene has only one hydrogen on each carbon

  • acetylene contains least number of hydrogens among the possible hydrocarbons having two carbons

  • acetylene belong to the class of alkynes with molecular formula CnH2n-2

A compound is treated with NaNH2 to give sodium salt. Identify the compound.

  •  C2H2 

  •  C6H6

  •  C2H6 

  •  C2H4

Ethylene forms ethylene chlorohydrin by the action of:

  • dry chlorine gas

  • dry hydrogen chlorine gas

  • solution of chlorine gas in water

  • dilute hydrochloric acid 

Which alkene on ozonolysis gives CH3CH2CHO and  CH3CCH3       ||       O  ?

  •  CH3CH2CH=CHCH2CH3

  •  CH3CH2CH=CHCH3

  •  

Hydroxylation of propyne in the presence of HgSO4/H2SO4 is initiated by the attack of:

  • carbene 

  • free radical

  • electrophile

  • nucleophile

Ozonolysis of buta-1,3-diene gives:

  • HCHO and glyoxal

  •  CH3CHO and glyoxal

  •  CO2 and glyoxal

  • HCHO + glyoxal + CH3CHO

A mixture of ethane, ethene and ethyne is passed through an ammoniacal AgNO3 solution. The gases that remain unreacted are-

  • Ethane and Ethene 

  • Ethane and Ethyne

  • Ethene and Ethyne 

  • Ethane only

The most suitable reagent among the following that is used to distinguish compound (III) from the rest of the compounds is -

I. CH3-CC-CH3

II. CH3-CH2-CH2-CH3

III. CH3-CH2-CCH

IV. CH3-CH=CH2

  •  Br2/CCl4

  •  Br2/CH3COOH

  • Alk.KMnO4 

  • Ammoniacal AgNO3

Alkene-1 on hydroboration followed with action of H2O2 gives:

  • alkanol-2 

  • alkanol-1

  • alkanal 

  • alkanone

Which of the following is a correct statement regarding the relative acidic character of cyclopropane and propane?

  • Cyclopropane is more acidic than propane

  • Propane is more acidic than cyclopropane

  • Both are equally acidic

  • Bothe are neutral

The reaction, 

C6H6 + CH3ClAlCl3AnhydrousC6H5CH3 + HCl

is an example of:

  • Friedel-Crafts reaction

  • Kolbe's synthesis

  • Wurtz's reaction

  • Grignard synthesis

Ozonolysis of will give:

  •  

  •  OC-CH2-CH3-CH3-CO   |                                  |CH2       CH2        CH2                        

  •   

  • none of the above

2-Methylpropene and But-1-ene can be distinguished by -

  • Baeyer's reagent

  • Ammoniacal AgNO3

  •  Br2 solution 

  •  O3Zn/H2O

An octane number 100 is given to:

  • n-hexane

  • Iso-octane 

  • neo-pentane

  • neo-octane 

Which of the following molecules/species are aromatic in character?

                 

     A                      B                          C                               D

  • B

  • C

  • D

  • A

Xylene on oxidation with acidic KMnO4 gives:

  • Phthalic acid 

  • Isophthalic acid

  • Terephthalic acid

  • All of the above

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