Ketones are first oxidation product of:

  • primary alcohols

  • secondary alcohols

  • dilhydric alcohols

  • trihydric alcohols

Alkaline hydrolysis of R2C.Cl2 forms:

  • propanone

  • propane

  • alkanone

  • alkanal

Ketones are prepared by:

  • Clemmensen's reduction

  • Rosenmund's reduction

  • Oppeanauer's oxidation

  • Cannizzaro's reaction

Chlorine does not react with:

  • methanal 

  • CH3CHO

  • propanone

  • C6H5CHO

Both acetaldehyde and ketone react with:

 

  • ammoniacal AgNO3

  • rochelle salt

  • 2,4-dinitro phenylhydrazine

  • all of the above

Aldehydes are produces in atmosphere by:

  • oxidation of secondary alcohols

  • reduction of alkenes

  • reaction of oxygen atoms with hydrocarbons

  • reaction of oxygen atoms with O3

Among acetic acid, phenol and n-hexanol which one of the following compound will react with NaHCO3 solution to give sodium salt and CO2?                                             

  • Acetic acid

  • n-hexanol

  • Acetic acid and phenol

  • Phenol

The reagent used for the separation of acetaldehyde from acetophenone is-

  •   NaHSO3         

  •   C6H5NHNH2           

  •   NH2OH             

  •   NaOH and I2

Iodoform test is not given by

  • 2-pentanone                 

  • ethanol

  • ethanal                         

  • 3-pentanone

Which of the following compounds with molecular formula, C5H10 yields acetone on ozonolysis? 

  • 2-methyl-2-butene

  • 3-methyl-1-butene

  • Cyclopentane

  • 2-methyl-1-butene

Two isomeric ketones 3-Pentanones and 2-pentanone can be distinguished by

  • I2/NaOH only               

  • NaHSO3 only

  • NaCN/HCl                     

  • both of (a) and (b)   

Products of the following reaction                                   

  CH3CC-CH2CH3 (ii) hydrolysis(i) O3 ... are

  • CH3CHO + CH3CH2CHO

  • CH3COOH + CH3COCH3

  • CH3COOH + HOOC-CH2CH3

  • CH3COOH + CO2

Which alkene on ozonolysis gives CH3CH2CHO and CH3COCH3?                                          

  • CH3CH2CH=C<CH3CH3

  • CH3CH2CH=CHCH2CH3

  • CH3CH2CH=CHCH3

  •  CH3-C|=CHCH3           CH3

The major organic product formed from the following reaction

 (ii) LiAlH4  (iii) H2O(i) CH3NH2 ... is

 

  •                    

  •   

  •                  

  •   

Benzoic acid gives benzene on being heated with X and phenol gives benzene on being heated with Y. Therefore, X and Y are respectively                                                              

  • Sodalime and copper

  • Zn dust and NaOH

  • Cu and sodalime

  • Sodalime and zinc dust

Which one of the following on oxidation gives a ketone?                       

  • primary alcohol                     

  • secondary alcohol

  • tertiary alcohol                     

  • All of these

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of α-hydroxy acid. The carbonyl compound is

  • acetaldehyde 

  • acetone

  • diethyl ketone 

  • formaldehyde                              

Consider the following transformations

CH3COOH CaCO3AheatBNaOHI2C The molecular formula of C is                       

  •  CH3-C||IOH-CH3

  •  ICH2-COCH3

  •  CHI3

  •  CH3I

 A and B in the following reactions are KCNHCN/AB

  • A=RR'CH2CN, B=NaOH

  • A=, B=CH3

  • A=, B=CH3

  • A=, B=LiAlH4

The product formed in aldol condensation is                                                                 

  • a beta-hydroxy acid

  • a beta-hydroxy aldehyde or a beta-hydroxy ketone

  • an alpha-hydroxy aldehyde or ketone

  • an alpha, beta unsaturated ester

Consider the following reaction,

PhenolZn-dustXAnhy.AlCl3CH3ClYAlk.KMnO4

The product Z is                            

  • toluene

  • benzaldehyde

  • benzoic acid

  • benzene

Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is called    

  • Clemmenson reduction

  • Cope reduction

  • Dow reduction

  • Wolff-Kishner reduction

Aldol condensation will not take place in

  • HCHO 

  •  CH3CHO

  •  CH3COCH3

  •  CH3CH2CHO


In the above reaction product, 'P' is-                                             

  •  

  •  

  •  

  •  

The -OH group of an alcohol or the -COOH group of a carboxylic acid can be replaced by -Cl using     

  • phosphorus pentachloride

  • hypochlorous acid

  • chlorine

  • hydrochloric acid

An ester is boiled with KOH. The product is cooled and acidified with conc. HCl. A white crystalline acid separates. The ester is

  • methyl acetate 

  • ethyl acetate

  • ethyl formate 

  • ethyl benzoate

The compound formed when malonic acid heated with urea, is                  

  • cinnamic acid

  • butyric acid

  • barbituric acid

  • crotonic acid

What is formed when a primary alcohol undergoes catalytic dehydrogenation?

  • Aldehyde 

  • Ketone 

  • Alkene

  • Acid 

The compound which on reduction with LiAlH4 gives two diffrent alcohols:

  •  CH3COOCH3                         

  •   CH3COOC2H5

  •  CH3COCH3                           

  •   CH3CHO

HCHO and HCOOH are distinguished by treating with:

  • Tollens reagent

  • NaHCO3

  • Fehling's Solution

  • Benedict Solution

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