The strongest hydrogen bond present among the following is-

  •  OHS

  •  SHO

  •  FHF

  •  FHO

Which of the following is the most basic oxide?

  •  Al2O3

  •  Sb2O3

  •  Bi2O3

  •  SeO2

In which of the process, the bond order increases and magnetic behaviour changes?

  • () N2N2+

  • () C2C2+

  • () NONO+

  • () O2O2+

Among the following, which has the maximum hydration energy?

  • OH-

  •  NH4+

  • F-

  • H+

Among the following oxides, which has the maximum lattice energy?

  • MgO
  • CaO
  • SrO
  • BaO

Which of the following pairs of species have similar shapes?

  •  PCl3, NH3

  •  CF4, SF4

  •  PbCl2, CO2

  •  PF5, IF5

Incorrect statement about resonance is :

  • The resonating structures are hypothetical.

  • The unpaired electrons in various resonating structures are same.

  • Hybrid structure is most energetic.

  • Hybrid structure is least energetic.

Which of the following species deviates from the octet rule?

  •  CO32-

  •  H2SO3

  • PCl3

  •  O3

Which of the following species has a bent T-shape?

  • ICl4-

  • PCl3

  • BrF3

  • I3-

In piperidine "N" atom has hybridization:

piperidine

  • sp

  •  sp2

  •  sp3

  •  dsp2

According to molecular orbital theory which of the following lists rank the nitrogen species in terms of increasing bond order ?

  •  N2- < N2 < N22-

  •  N22- < N2- < N2

  •  N2 < N22- <N2-

  •  N2- < N22- < N2

The correct order of increasing bond length of 

C-H, C-O, C-C and C=C is

  • C-C<C=C<C-O<C-H

  • C-O<C-H<C-C<C=C

  • C-H<C-O<C-C<C=C

  • C-H<C=C<C-O<C-C

An element X is placed in group IA of the periodic table because it forms:

  • An oxide which is acid

  • A volatile chloride having formula XCl2

  • An ionic chloride having formula XCl

  • An insoluble chloride XCl4

Which of the following would have a permanent dipole moment ?

  • BF3

  • SiF4

  • SF4

  • XeF4

In the case of alkali metals, the covalent character decreases in the order

  •  MCl > MI > MBr > MF

  •  MF > MCl >  MBr > M

  •  MF > MCl > MI > MBr

  •  MI > MBr > MCl > MF

Which of the following two are isostructural? 

  • XeF2, and IF2-

  • NH3, and BF3

  • CO2, and SiO2

  • PCl5, and IF5

Which one of the following species does not exist?

 

  •  Be2+

  • Be2

  • B2

  • N2

Which one of the following is not paramagnetic ?

  • NO

  •  N2+

  • CO

  •  O2-

In a regular octahedral molecule MX6, the number of X-M-X bonds at 180° is-

  • 3

  • 2

  • 6

  • 4

Which of the following is not isostructural with SiCl4

  • SCl4     

  • SO42-

  •  PO43-

  • NH4+

In which of the following species the central atom has the type of hybridisation which is not the same as that present in the other three ?

  • SF4

  •  I3-

  •  SbCl52-

  • PCl5

Which of the following has   - bonding?

4.CO32-

  •  NO3-

  •  SO32-

  •  BO33-

  • 4

In BrF3 molecule, the lone pairs occupy equatorial positions to minimize:

  • Lone pair-bond pair repulsion.

  • Bond pair-bond pair repulsion.

  • Lone pair-lone pair repulsion and lone pair-bond pair repulsion.

  • Lone pair-lone pair repulsion.

In which one of the following molecules, the central atom said to adopt sp2 hybridisation ?

  • BeF2

  • BF3

  • C2H2

  • NH3

Among the following molecules/ions BF3, NO2-, NH2- , and H2O, the central atom is sp2 hybridized in :  

3. NO2- and H2O

  • NO2and NH2-

  • NH2-  and H2O

  • 4. BFand NO2-

  • 4

Which one of the following is planar ?

  • XeF4

  • XeO4

  • XeO3

  • XeO3F2

In PO43- ion, the formal charge on each oxygen atom and P-O bond order respectively are :

  • -0.75, 0.6

  • -0.75, 1.0

  • -0.75, 1.25

  • -3.1, 1.25

The dielectric constant of H2O is 80. The electrostatic force of attraction between Na+ and Cl- will be

  • reduced to 140 in water than in air

  • reduced to 180 in water than in air

  • will be increased to 80 in water than in air

  • will remain unchanged

Which of the following is isoelectronic? 

  •  CO2, NO2

  •  NO2-, CO2

  •  CN-, CO

  •  SO2, CO2

The correct order of the increasing bond angles in the following triatomic species is : 

2. NO2- < NO2 NO2+

  • NO2-NO2+ < NO2

  • 3. NO2+  < NO2 NO2-

  • 3
  • NO2+ < NO2- < NO2

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