Power alcohol is a mixture of petrol and alcohol in the ratio:
1:4
4:1
2:1
1:2
The formula for allyl alcohol is-
CH3-CH=CHOH
CH2=CHCH2OH
HOCH2CH2CH3
None of the above.
The -OH group of an alcohol or the -COOH group of a carboxylic acid on can be replaced
by -Cl using
phosphorus pentachloride
hypochlorous acid
chlorine
hydrochloric acid
p-nitrophenol is stronger acid than phenol because nitro group is:
Electron withdrawing
Electron donating
Basic
Acidic
The most acidic compound among the following is-
ClCH2 - CH2OH
Which of the following has highest boiling point?
Benzene
Phenol
Toluene
Ethyl benzene
Tautomerism is not exhibited by-
The correct order of the acidic strength among for the above compounds is -
I>II>III
III>I>II
II>III>I
I>III>II
The boiling point of ethanol is higher than that of dimethyl ether due to presence of-
The compound B formed in the following sequence of reactions,
CH3CH2CH2OH→PCl5A→Alc.NaOHB will be:
Propyne
Propene
Propanal
Propane
Ethyl alcohol is denatured by:
Methanol and formic acid
KCN
CH3OH and C6H6
CH3OH and pyridine
Chlorobenzene reacts with Mg in dry ether to give a compound (A) which further reacts
with ethanol to yield
phenol
benzene
ethyl benzene
phenyl ether
can be repared from williamson's synthesis using
and C6H5CH2ONa
C6H5CH2Cl and
and C6H5ONa
All of these
Methanol and ethanol can be distinguished by the following:
CH3MgBr + Cyclopentanone →H2OA →HBrB→Mg/etherC→H3OHCHOD,
The product 'D' in the above-mentioned reaction is-
The reaction that does not give benzoic acid as the major product is-
→K2Cr2O7
→iiH3O+iNaOCl
→PCC
→KMnO4/H+
Consider the following alcohols,
I.
II.
III.
IV.
Ease of dehydration of above alcohols will be in the order of-
The number of moles of HI consumed in above reaction is -
1
2
3
4
R-CH2-CH2OH can be converted into RCH2CH2COOH. The correct sequence of reagents is:
PBr3, KCN, H+
PBr3, KCN, H2
KCN, H+
HCN, PBr3, H+
The strongest acid among the following aromatic compounds is -
p-Chlorophenol
p-Nitrophenol
m-Nitrophenol
o- Nitrophenol
→AcetoneCH33CO3AlX
The product (x) of this reaction is
The major product in the acid catalysed dehydration of would be
Which of the following reactions will give 2° chiral alcohol as one or more of major organic products?
The major product of the following reaction sequence will be
→(1)PhCOCl / Pyridine →(2)CH3COCl /AlCl3→(3)Zn-Hg /HCl/∆ →(4)Br2 /Fe
In the following reactions X, Y and Z are respectively :
An aromatic compound A (C8H10O) gives following tests with the given reagents.
The structure of 'A' is -
Compound Y, C7H8O is insoluble in water, dil HCI and aqueous NaHCO3. It dissolves in dilute NaOH. When Y is treated with bromine water it is converted rapidly into a compound of formula C7H5OBr3. The structure of Y is -
Compounds I and II can be distinguished by using reagent
(I)
(II)
NaNO2/HCl
Br2/H2O
HCl/ZnCl2 (anhydrous)
Cu2Cl2 + NH4OH
i.
ii.
iii.
The correct order of dehydration of compounds (i), (ii) and (iii) by conc. H2SO4 is-
(i)>(iii)>(ii)
(i)>(ii)>(iii)
(ii)>(i)>(iii)
(ii)>(iii)>(i)
Product (x) will be:
(a)
(b)
(c)
(d)
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