Power alcohol is a mixture of petrol and alcohol in the ratio:

  • 1:4

  • 4:1                         

  • 2:1                         

  • 1:2

The formula for allyl alcohol is- 

  • CH3-CH=CHOH                                  

  • CH2=CHCH2OH

  • HOCH2CH2CH3                                     

  • None of the above.

The -OH group of an alcohol or the -COOH group of a carboxylic acid on can be replaced

by -Cl using

  • phosphorus pentachloride

  • hypochlorous acid

  • chlorine

  • hydrochloric acid

p-nitrophenol is stronger acid than phenol because nitro group is:

  • Electron withdrawing                       

  • Electron donating

  • Basic                                             

  • Acidic

The most acidic compound among the following is- 

                    

  •  ClCH2 - CH2OH

  •  

  •  

  •  

Which of the following has highest boiling point?

  • Benzene                         

  • Phenol

  • Toluene                           

  • Ethyl benzene

Tautomerism is not exhibited by-

  •  
  •  
  •  
  •  

The correct order of the acidic strength among for the above compounds is -

  • I>II>III                           

  • III>I>II

  • II>III>I                           

  • I>III>II

The boiling point of ethanol is higher than that of dimethyl ether due to presence of-                                            

  • H-bonding in ethanol
  • H-bonding in dimethyl ether
  • -CH3 group in ethanol
  • -CH3 group in dimethyl ether

The compound B formed in the following sequence of reactions,

CH3CH2CH2OHPCl5AAlc.NaOHB will be:

  • Propyne                                 

  • Propene

  • Propanal                                 

  • Propane

Ethyl alcohol is denatured by:

  • Methanol and formic acid

  • KCN

  • CH3OH and C6H6

  • CH3OH and pyridine

Chlorobenzene reacts with Mg in dry ether to give a compound (A) which further reacts

with ethanol to yield     

  • phenol                               

  • benzene

  • ethyl benzene                     

  • phenyl ether

 can be repared from williamson's synthesis using

  •   and C6H5CH2ONa

  •  C6H5CH2Cl and 

  •  and C6H5ONa 

  • All of these

Methanol and ethanol can be distinguished by the following:

  • By reaction with metallic sodium
  • By reaction with caustic soda
  • By heating with iodine and washing soda
  • By heating with zinc and inorganic mineral acid

CH3MgBr + Cyclopentanone H2OHBrBMg/etherCH3OHCHOD,

The product 'D' in the above-mentioned reaction is-

  •  

  •  

  •  

The reaction that does not give benzoic acid as the major product is-

  •  K2Cr2O7

  •  iiH3O+iNaOCl

  •  PCC

  •   KMnO4/H+

Consider the following alcohols,

I. 

II. 

III. 

IV. 

Ease of dehydration of above alcohols will be in the order of-

  • I < II < III < IV 
  •  I > II > III > IV
  • III  < II < I < IV
  • II < III < IV < I

The number of  moles of HI consumed in above reaction is -

  • 1

  • 2

  • 3

  • 4

R-CH2-CH2OH can be converted into RCH2CH2COOH. The correct sequence of reagents is: 

  • PBr3, KCN, H

  • PBr3, KCN, H2     

  •  KCN, H+

  • HCN, PBr3, H+

The strongest acid among the following aromatic compounds is -

  • p-Chlorophenol

  • p-Nitrophenol

  • m-Nitrophenol

  • o- Nitrophenol

AcetoneCH33CO3AlX

The product (x) of this reaction is 

  •  

  •  

  •  

  •  

The major product in the acid catalysed dehydration of  would be

  •  

  •  

  •  

  •  

Which of the following reactions will give 2° chiral alcohol as one or more of major organic products?


(1) 
(2)
(3)
(4)None
  • 1
  • 2
  • 3
  • 4

The major product of the following reaction sequence will be

(1)PhCOCl / Pyridine    (2)CH3COCl /AlCl3(3)Zn-Hg /HCl/       (4)Br2 /Fe

1. 
2.
3.
4.
  • 1
  • 2
  • 3
  • 4

In the following reactions X, Y and Z are respectively :

 XYZ
(1) 
(2)
(3)
(4)
  • 1
  • 2
  • 3
  • 4

An aromatic compound A (C8H10O) gives following tests with the given reagents.

The structure of  'A' is -

1.  
2.
3.
4.
  • 1
  • 2
  • 3
  • 4

Compound Y,  C7H8O is insoluble in water, dil HCI and aqueous NaHCO3. It dissolves in dilute NaOH. When Y is treated with bromine water it is converted rapidly into a compound of formula C7H5OBr3.  The structure of Y is -

1.  
2.
3.
4.
  • 1
  • 2
  • 3
  • 4

Compounds I and II can be distinguished by using reagent

(I)

(II)

  4–Amino–2–methlbut–3–en–2–ol    4–Amino–2,2–dimethylbut–3–yn–1–ol  
  • NaNO2/HCl

  • Br2/H2O

  • HCl/ZnCl2 (anhydrous)

  • Cu2Cl2 + NH4OH

i.  

ii. 

iii.  

The correct order of dehydration of compounds (i), (ii) and (iii) by conc. H2SO4 is-

  • (i)>(iii)>(ii)                                             

  • (i)>(ii)>(iii)

  • (ii)>(i)>(iii)                                             

  • (ii)>(iii)>(i)

Product (x) will be:

(a) 

(b) 

(c) 

(d) 

  • 1
  • 2
  • 3
  • 4
0:0:1


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