Ethylene oxide when treated with Grignard reagent yields :

  • secondary alcohol

  • tertiary alcohol

  • cyclopropyl alcohol

  • primary alcohol

The heating of phenylmethyl ethers with HI produces-

  • Iodobenzene

  • Phenol

  • Benzene

  • Ethyl chloride

The most acidic compound among the following is -

Identify A and predict the type of reaction 
    

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Compound A, C8H10O is found to react with NaOI (produced by reacting Y with NaOH) and yields a yellow precipitate with a characteristic smell. A and Y are respectively-

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The compound A on treatment with Na gives B, and with PCl5 gives C. B and C react together to give diethyl ether.

A, B and C are respectively-

  • C2H5OH, C2H6, C2H5Cl

  • C2H5OH, C2H5Cl, C2H5ONa

  • C2H5Cl, C2H6, C2H5OH

  • C2H5OH, C2H5ONa ,C2H5Cl


The above-mentioned reaction can be classified as-
  • Alcohol formation reaction
  • Dehydration reaction
  • Williamson alcohol synthesis reaction
  • Williamson ether synthesis reaction

Which of the following reaction(s) can be used for the preparation of alkyl halides? 
I. CH3CH2OH+HClanh. ZnCl2 
II.CH3CH2OH+HCl 
III.CH33COH+HCl 
IV.CH32CHOH+HClanh. ZnCl2

  • I, III and IV

  • I and II

  • Only IV

  • III and IV

Which of the following is not the product of dehydration of  ?

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The reaction, 
CH3-C||CH3CH3-ONa+CH3CH2Cl-NaCl CH3-C||CH3CH3-O-CH2-CH3 
is called

 

  • Williamson synthesis
  • Williamson continuous etherification process
  • Etard reaction
  • Gatterman-Koch reaction

Ether among the following will produce methyl alcohol on treatment with hot concentrated Hl -

  •  CH3-CH2-CH|CH3-O-CH3

  •  CH3-C||CH3CH3-O-CH3

  •  CH3-CH|CH3-CH2-O-CH3

  • CH3 – CH2 – CH2 – CH2 – O – CH3

The most reactive compound among the following toward electrophilic aromatic substitution reaction is -

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The most acidic compound among the following is -

 
 
 

 

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 KOHKMnO4BFeCl3Br2CH+C2H5OHD

The product 'D' in the above-mentioned reaction is-

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H2COH.CH2OH on heating with per-iodic acid gives

 
 
 
 

 

 CH3 — O — CH(CH3)2 + HI → B (Product)

The product 'B' in the above mentioned reaction is-

  • CH3OH+(CH3)2CHl

  •  lCH2OCH(CH3)2

  •  CH3O C(CH3)2

  •  CH3l+(CH3)2CHOH

The structure of intermediate A in the following reaction is:

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Conversion of cyclohexanol into cyclohexene is most effective in -             

  • Concentrated H3PO4

  • Concentrated HCl

  • Concentrated HCl / ZnCl2

  • Concentrated HBr

When vapour of a secondary alcohol is passed over heated copper at 573 K, the product formed is -

  • A carboxylic acid

  • An aldehyde

  • A ketone

  • An alkene

The major products C and D formed in the following reaction respectively are-

H3C-CH2-CH2-OC(CH3)3excess HIC+D

  •  H3C-CH2-CH2-I and I-C(CH3)3

  •  H3C-CH2-CH2-OH and I-C(CH3)3

  •  H3C-CH2-CH2-I and HO-C(CH3)3

  • H3C-CH2-CH2-OH   and HO-C(CH3)3

"A" and "B" are respectively:

  • Both A and B are respectively.

  • Both A and B are   respectively.

  •  A is and B is respectively.

  •   A is and B is respectively.

What is the major product in the given following reaction?

  •                O                                          O             ||                                          ||H3C- C - CH2-CH2 -CH2 -C- H

  •                O                             O             ||                             ||CH3 - C-CH2-CH2-CH2 - C- OH

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In the reaction sequence, X and Y, respectively are

  •   H2O2; LiAlH4

  •   C6H5COOOH; LiAlH4

  •   C6H5COOOH; Zn/Hg.HCl

  •   Alkaline KMnO4; LiAlH4

Two isomers compounds I and II are healed with HBr

The products obtained are

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The major product of the following reaction is

       

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Phenol on treatment with dil.HNO3, gives two products P and Q. P is steam volatile but Q is not P and Q are. respectively

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The compound which reacts with excess bromine to produce 2, 4, 6-tribomophenol, is

  •   1, 3-cyclohexadiene

  •   1, 3-cyclohexanedione

  •   Salicylic acid

  •   Cyclohexanone

The major products formed in the reaction of t-butyl methyl ether with Hl are

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In the following reaction sequence

2. H2O2/NaOH1. B2H6XCrO3/H2SO4Y

X and Y are

  •   option

  •   option

  •   option

  •   option

A: The solubility of alcohols in water decreases with the increase in the number of carbon atoms.

R: The non-polar alkyl group or the hydrophobic portion supports the solubility of alcohol.

 

 

  • Both Assertion and Reason are true and the reason is the correct explanation of the assertion.

  • Both Assertion and Reason are true but the reason is not the correct explanation of the assertion.

  • Assertion is a true statement but the reason is false.

  • Both Assertion and Reason are false statements.

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