Ketones are first oxidation product of:
primary alcohols
secondary alcohols
dilhydric alcohols
trihydric alcohols
Alkaline hydrolysis of R2C.Cl2 forms:
propanone
propane
alkanone
alkanal
Ketones are prepared by:
Clemmensen's reduction
Rosenmund's reduction
Oppeanauer's oxidation
Cannizzaro's reaction
Chlorine does not react with:
methanal
CH3CHO
C6H5CHO
Both acetaldehyde and ketone react with:
ammoniacal AgNO3
rochelle salt
2,4-dinitro phenylhydrazine
all of the above
Aldehydes are produces in atmosphere by:
oxidation of secondary alcohols
reduction of alkenes
reaction of oxygen atoms with hydrocarbons
reaction of oxygen atoms with O3
Among acetic acid, phenol and n-hexanol which one of the following compound will react with NaHCO3 solution to give sodium salt and CO2?
Acetic acid
n-hexanol
Acetic acid and phenol
Phenol
The reagent used for the separation of acetaldehyde from acetophenone is-
NaHSO3
C6H5NHNH2
NH2OH
NaOH and I2
Iodoform test is not given by
2-pentanone
ethanol
ethanal
3-pentanone
Which of the following compounds with molecular formula, C5H10 yields acetone on ozonolysis?
2-methyl-2-butene
3-methyl-1-butene
Cyclopentane
2-methyl-1-butene
Two isomeric ketones 3-Pentanones and 2-pentanone can be distinguished by
I2/NaOH only
NaHSO3 only
NaCN/HCl
both of (a) and (b)
Products of the following reaction
CH3C≡C-CH2CH3 →(ii) hydrolysis(i) O3 ... are
CH3CHO + CH3CH2CHO
CH3COOH + CH3COCH3
CH3COOH + HOOC-CH2CH3
CH3COOH + CO2
Which alkene on ozonolysis gives CH3CH2CHO and CH3COCH3?
CH3CH2CH=C<CH3CH3
CH3CH2CH=CHCH2CH3
CH3CH2CH=CHCH3
CH3-C|=CHCH3 CH3
The major organic product formed from the following reaction
→(ii) LiAlH4 (iii) H2O(i) CH3NH2 ... is
Benzoic acid gives benzene on being heated with X and phenol gives benzene on being heated with Y. Therefore, X and Y are respectively
Sodalime and copper
Zn dust and NaOH
Cu and sodalime
Sodalime and zinc dust
Which one of the following on oxidation gives a ketone?
primary alcohol
secondary alcohol
tertiary alcohol
All of these
A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of α-hydroxy acid. The carbonyl compound is
acetaldehyde
acetone
diethyl ketone
formaldehyde
Consider the following transformations
CH3COOH →CaCO3A→heatB→NaOHI2C The molecular formula of C is
CH3-C||IOH-CH3
ICH2-COCH3
CHI3
CH3I
A and B in the following reactions are →KCNHCN/A→B
A=RR'CH2CN, B=NaOH
A=, B=CH3
A=, B=LiAlH4
The product formed in aldol condensation is
a beta-hydroxy acid
a beta-hydroxy aldehyde or a beta-hydroxy ketone
an alpha-hydroxy aldehyde or ketone
an alpha, beta unsaturated ester
Consider the following reaction,
Phenol→Zn-dustX→Anhy.AlCl3CH3ClY→Alk.KMnO4Z
The product Z is
toluene
benzaldehyde
benzoic acid
benzene
Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is called
Clemmenson reduction
Cope reduction
Dow reduction
Wolff-Kishner reduction
Aldol condensation will not take place in
HCHO
CH3COCH3
CH3CH2CHO
In the above reaction product, 'P' is-
The -OH group of an alcohol or the -COOH group of a carboxylic acid can be replaced by -Cl using
phosphorus pentachloride
hypochlorous acid
chlorine
hydrochloric acid
An ester is boiled with KOH. The product is cooled and acidified with conc. HCl. A white crystalline acid separates. The ester is
methyl acetate
ethyl acetate
ethyl formate
ethyl benzoate
The compound formed when malonic acid heated with urea, is
cinnamic acid
butyric acid
barbituric acid
crotonic acid
What is formed when a primary alcohol undergoes catalytic dehydrogenation?
Aldehyde
Ketone
Alkene
Acid
The compound which on reduction with LiAlH4 gives two diffrent alcohols:
CH3COOCH3
CH3COOC2H5
HCHO and HCOOH are distinguished by treating with:
Tollens reagent
NaHCO3
Fehling's Solution
Benedict Solution
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