A compound A has molecular formula C2Cl3OH. It reduces Fehling's solution and on oxidatioin gives a monocarboxylic acid B. A is obtained by action of Cl2 on ethyl alcohol. A is:
chloral
CHCl3
CH3Cl
chloro acetic acid
Carbonyl compounds when treated with sodium bisulphite solution generally a crystalline sodium bisulphite addition product is formed but which of the following carbonyl compound not forms crystalline addition product?
HCHO
CH3CHO
CH3COCH3
C2H5COC2H5
The reaction; 2 | COOHCOOH →OH- | CH2OHCOOH + | COONaCOOH is:
crosses Cannizzaro's reaction
intermolecular Cannizzaro's reaction
intramolecular Cannizzaro's reaction
Neither of the above
Which will form two oximes with NH2OH?
CH3CH2COCH3
CH3CH2COCH2CH3
The term hypnone is used for:
benzophenone
acetophenone
acetaldehyde
none of these
Collin's reageant causes the conversion:
>CO →>CHOH
>CHO →-COOH
>CHOH →>CO
>CHOH →-COOH
This polymer is obtained when acetone is saturated with hydrogen chloride gas. Polymer is:
phorone
formose
diacetonyl alcohol
mesityl oxide
C6H5CHO on reacting with Cl2 gives:
C6H5CHCl2
C6H5COOH
C6H5CH2OH
C6H5COCl
Dialkyl cadmium reacts with a compound to form a ketone
The compound is:
acid
acid chloride
ester
CO
Ketones are less reactive than aldehydes because:
C=O group is more polar in ketones
of electromeric effect
of steric hindrance to the attacking reagent
none of the above
The polymer is obtained when HCHO is allowed to stand. It is a white solid. The polymer is:
trioxane
para-formaldehyde
metaldehyde
The important step in Cannizzaro's reaction is the intermolecular shift of:
proton
H-atom
hydride ion
hydronium ion
Pinacole is:
2,3-dimethyl-2,3-butandiol
3,3-dimethyl-2-propanone
3-methylbutan-2-ol
None of the above
Which reaction is used for detecting the presence of carbonyl group?
Reaction with hydrazine
Reaction with phenylhydrazine
Reaction with hydroxylamine
All of the above
Acetone is used in:
face creams
vanilla
nail polishes
sweet-smelling erasers
Benedict's solution provides:
Ag+
Cu2+
Ba2+
Li+
Jones reagent is:
Acidified KMnO4
K2Cr2O7 + H2SO4 or chromic acid + H2SO4
Alkaline K2Cr2O7
Acetaldehyde undergoes self condensation in presence of aluminium ethoxide to give ethyl acetate. This reaction is called:
Perkin reaction
Tischenko's reaction
Cannizzaro's reaction
Aldol condensation
Oppenauer oxidation is the reverse process of:
Wolff-Kishner's reduction
Rosenmund's reduction
Clemmensen's reduction
Meerwein-Ponndorf Verley reduction
Semicarbazide is:
NH2CONH2
NH2-NH2
NH2CONHNH2
None of these
An aldehyde which undergoes Cannizzaro's reaction and reduces Schiff's reagent but does not reduce Fehling's solution is:
C6H5CHO
salicylaldehyde
b-hydroxy butyraldehyde is an example of:
aldol
diol
hemiacetal
acetal
A ketone reacted with C2H5MgBr reagent followed by hydrolysis gave a product which on dehydration gives an alken. The alkene on ozonolysis gave diethyl ketone and acetaldehyde. The ketone is:
dimethyl ketone
ethyl methyl ketone
diethyl ketone
ethyl propyl ketone
The reaction produces:
Treatement of propionaldehyde with dil. NaOH gives:
CH3CH2COOCH2CH2CH3
CH3CH2CHOHCH2CH2CHO
CH3CH2CHOHCH(CH3)CHO
CH3CH2COCH2CH2CHO
Which of the following will react with water ?
CCl3CHO
CCl4
CH2Cl.CH2Cl
Among the given compounds, the most susceptible to nucleophile attack at the carbonyl group is:
MeCOCl
MeCHO
MeCOOMe
MeCOOCOMe
In the Cannizzaro's reaction given below,
2Ph-CHO→OH-Ph-CH2OH + PhCOO-
the slowest step is:
The attack of OH- at the carbonyl group
the transfer of hydride to the carbonyl group
the abstraction of proton from the carboxylic acid
the deprotonation of Ph-CH2OH
The aldol condensation of acetaldehyde results in hte formation of:
CH3 C CHCH3 || | O OH
CH3 CHCH2 CH | || OH O
CH3CH2CH—CH | || OH O
CH2CH2OH+COOH
Wolff-Kishner's reaction is:
reduction of carbonyl compound into hydrocarbons
reduction of carbonyl compound into alcohols
reduction of nitrobenzene into aniline
reduction of carbohydrates to alcohol
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