A compound A has molecular formula C2Cl3OH. It reduces Fehling's solution and on oxidatioin gives a monocarboxylic acid B. A is obtained by action of Cl2 on ethyl alcohol. A is:

  • chloral

  • CHCl3

  • CH3Cl

  • chloro acetic acid

Carbonyl compounds when treated with sodium bisulphite solution generally a crystalline sodium bisulphite addition product is formed but which of the following carbonyl compound not forms crystalline addition product?

  • HCHO

  • CH3CHO

  •  CH3COCH3

  • C2H5COC2H5

The reaction; 2 |       COOHCOOH OH- |       CH2OHCOOH + |       COONaCOOH is:

  • crosses Cannizzaro's reaction

  • intermolecular Cannizzaro's reaction

  • intramolecular Cannizzaro's reaction

  • Neither of the above

Which will form two oximes with NH2OH?

  • CH3COCH3

  • CH3CH2COCH3

  • CH3CH2COCH2CH3

  •  

The term hypnone is used for:

  • benzophenone

  • acetophenone

  • acetaldehyde

  • none of these

Collin's reageant causes the conversion: 

  • >CO >CHOH

  • >CHO -COOH

  • >CHOH >CO

  • >CHOH -COOH

This polymer is obtained when acetone is saturated with hydrogen chloride gas. Polymer is:

  • phorone

  • formose

  • diacetonyl alcohol

  • mesityl oxide

C6H5CHO on reacting with Cl2 gives:

  •  C6H5CHCl2

  •  C6H5COOH

  •  C6H5CH2OH

  •  C6H5COCl

Dialkyl cadmium reacts with a compound to form a ketone

The compound is:

  • acid

  • acid chloride

  • ester

  • CO

Ketones are less reactive than aldehydes because:

  • C=O group is more polar in ketones

  • of electromeric effect

  • of steric hindrance to the attacking reagent 

  • none of the above

The polymer is obtained when HCHO is allowed to stand. It is a white solid. The polymer is:

  • trioxane

  • formose

  • para-formaldehyde

  • metaldehyde

The important step in Cannizzaro's reaction is the intermolecular shift of:

  • proton

  • H-atom

  • hydride ion

  • hydronium ion

Pinacole is:

  • 2,3-dimethyl-2,3-butandiol

  • 3,3-dimethyl-2-propanone

  • 3-methylbutan-2-ol

  • None of the above

Which reaction is used for detecting the presence of carbonyl group?

  • Reaction with hydrazine

  • Reaction with phenylhydrazine

  • Reaction with hydroxylamine

  • All of the above

Acetone is used in:

  • face creams

  • vanilla

  • nail polishes

  • sweet-smelling erasers

Benedict's solution provides:

  • Ag+

  • Cu2+

  • Ba2+

  • Li+

Jones reagent is:

  • Acidified KMnO4

  • K2Cr2O7 + H2SO4 or chromic acid + H2SO4

  • Alkaline K2Cr2O7

  • None of the above

Acetaldehyde undergoes self condensation in presence of aluminium ethoxide to give ethyl acetate. This reaction is called:

  • Perkin reaction

  • Tischenko's reaction

  • Cannizzaro's reaction

  • Aldol condensation

Oppenauer oxidation is the reverse process of:

  • Wolff-Kishner's reduction

  • Rosenmund's reduction

  • Clemmensen's reduction

  • Meerwein-Ponndorf Verley reduction

Semicarbazide is:

 

  • NH2CONH2

  • NH2-NH2

  •  NH2CONHNH2

  • None of these

An aldehyde which undergoes Cannizzaro's reaction and reduces Schiff's reagent but does not reduce Fehling's solution is:

  • CH3CHO

  • HCHO

  • C6H5CHO

  • salicylaldehyde

b-hydroxy butyraldehyde is an example of: 

  • aldol

  • diol

  • hemiacetal

  • acetal

A ketone reacted with C2H5MgBr reagent followed by hydrolysis gave a product which on dehydration gives an alken. The alkene on ozonolysis gave diethyl ketone and acetaldehyde. The ketone is:

  • dimethyl ketone

  • ethyl methyl ketone

  • diethyl ketone

  • ethyl propyl ketone

The reaction  produces:

  •  

  •  

  •  

  •  

Treatement of propionaldehyde with dil. NaOH gives:

  •  CH3CH2COOCH2CH2CH3

  •  CH3CH2CHOHCH2CH2CHO

  •  CH3CH2CHOHCH(CH3)CHO

  •  CH3CH2COCH2CH2CHO

Which of the following will react with water ?

  • CHCl3

  • CCl3CHO

  • CCl4

  • CH2Cl.CH2Cl

Among the given compounds, the most susceptible to nucleophile attack at the carbonyl group is:

  • MeCOCl

  • MeCHO

  • MeCOOMe

  • MeCOOCOMe

In the Cannizzaro's reaction given below,

2Ph-CHOOH-Ph-CH2OH + PhCOO-

the slowest step is:

  • The attack of OH- at the carbonyl group

  • the transfer of hydride to the carbonyl group

  • the abstraction of proton from the carboxylic acid

  • the deprotonation of Ph-CH2OH

The aldol condensation of acetaldehyde results in hte formation of:

  •  CH3 C CHCH3        ||  |        O OH

  •  CH3 CHCH2 CH              |         ||           OH        O

  •  CH3CH2CHCH           |               ||         OH             O

  •  CH2CH2OH+COOH

Wolff-Kishner's reaction is:

  • reduction of carbonyl compound into hydrocarbons

  • reduction of carbonyl compound into alcohols

  • reduction of nitrobenzene into aniline

  • reduction of carbohydrates to alcohol

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