The correct order of reactivity of PhMgBr with,
O O O || || ||PH—C—PH CH3—C—H CH3—C—CH3 is: (l) (ll) (lll)
I>II>III
III>II>I
II>III>I
II>I>III
The IUPAC name of the CH3COCH(CH3)2 is:
4-methyl isopropyl ketone
3-methyl-2-butanone
isopropylmethyl ketone
2-methyl-3-butanone
In the folllowing sequence products I, J and L are formed and K represents a regent.
(i) The structure of the product I is:
(ii) The structures of compounds J & K respectively are:
(iii) The structure of product L is:
A tertiary alcohol H upon acid catalysed dehydration gives a product I. Ozonolysis of I leads to compounds J & K. Compound J upon reaction with KOH gives benzyl alcohol and a compound L, whereas K on reaction with KOH gives only M.
(i) Compound H is formed by the reaction of:
Vanillin, used as a flavouring agent is-
An Aliphatic alcohol
An Aromatic aldehyde
A Hydrocarbon
A Carbohydrate
Acetophenone on oxidation by perbenzoic acid gives phenyl acetate. The reaction is named as:
Baeyer-Villiger oxidation
Perkin's reaction
Claisen condensation
Reformatsky reaction
In Etard's reaction, toluene is oxidised to benzaldehyde using:
H2O2
Cl2
chromium trioxide or CrO2Cl2
KMnO4
m-chlorobenzaldehyde on reaction with conc. KOH at room temperature gives:
potassium m-chlorobenzoate and m-hydroxybenzaldehyde
m-hydroxybenzaldehyde and m-chlorobenzyl alcohol
m-chlorobenzyl alcohol and m-hydroxy benzyl alcohol
potassium m-chlorobenzoate and m-chlorobenzyl alcohol
Formylchloride has not been prepared so far. Which can function as formylchloride in formylation ?
HCHO + HCl
HCOOCH3 + HCl
CO + HCl
HCONH2 + HCl
In the reaction, the compound 'X' is:
CH3COOH
Br·CH2COOH
(CH3CO)2O
CHO·COOH
The major product H of the given reaction sequence is:
CH3-CH2-CO-CH3→CN-G→Heat95 % H2SO4H
CH3-CH=C|-COOH CH3
CH3-CH=C|-CN CH3
OHCH3-CH-C||-COOH CH3
CH3-CH=C|-CO-NH2 CH3
In presence of iodine catalyst, chlorine reacts with acetic acid to form:
Acetic acid is obtained when:
glycerol is heated with sulphuric acid
methyl alcohol is oxidized with potassium permanganate
acetaldehyde is oxidized with potassium dichromate and sulphuric acid
calcium acetate is distilled in presence of calcium formate
Main product of the reaction,
CH3CONH2+HNO2 →... is:
CH3CH2NH2
CH3NH2
CH3COONH4
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