The correct order of reactivity of PhMgBr with,

 

         O                    O                    O         ||                    ||                    ||PHCPH CH3CH   CH3CCH3 is:         (l)           (ll)                     (lll)

  • I>II>III

  • III>II>I

  • II>III>I

  • II>I>III

The IUPAC name of the CH3COCH(CH3)2 is:

  • 4-methyl isopropyl ketone

  • 3-methyl-2-butanone

  • isopropylmethyl ketone

  • 2-methyl-3-butanone

In the folllowing sequence products I, J and L are formed and K represents a regent.

 

(i) The structure of the product I is:

(ii) The structures of compounds J & K respectively are:

(iii) The structure of product L is:

  • 1
  • 2
  • 3
  • 4

A tertiary alcohol H upon acid catalysed dehydration gives a product I. Ozonolysis of I leads to compounds J & K. Compound J upon reaction with KOH gives benzyl alcohol and a compound L, whereas K on reaction with KOH gives only M.

(i) Compound H is formed by the reaction of: 

 

 

  • 1
  • 2
  • 3
  • 4

Vanillin, used as a flavouring agent is-

  • An Aliphatic alcohol

  • An Aromatic aldehyde

  • A Hydrocarbon

  • A Carbohydrate

Acetophenone on oxidation by perbenzoic acid gives phenyl acetate. The reaction is named as:

  • Baeyer-Villiger oxidation

  • Perkin's reaction

  • Claisen condensation

  • Reformatsky reaction

In Etard's reaction, toluene is oxidised to benzaldehyde using:

  • H2O2

  • Cl2

  • chromium trioxide or CrO2Cl2

  • KMnO4

m-chlorobenzaldehyde on reaction with conc. KOH at room temperature gives:

  • potassium m-chlorobenzoate and m-hydroxybenzaldehyde

  •  m-hydroxybenzaldehyde and m-chlorobenzyl alcohol

  •  m-chlorobenzyl alcohol and m-hydroxy benzyl alcohol

  • potassium m-chlorobenzoate and m-chlorobenzyl alcohol

Formylchloride has not been prepared so far. Which can function as formylchloride in formylation ?

  • HCHO + HCl

  • HCOOCH3 + HCl

  • CO + HCl

  • HCONH2 + HCl

In the reaction, the compound 'X' is:

  •  CH3COOH

  •  Br·CH2COOH

  •  (CH3CO)2O

  •  CHO·COOH

The major product H of the given reaction sequence is:

CH3-CH2-CO-CH3CN-GHeat95 % H2SO4H

  •  CH3-CH=C|-COOH                      CH3

  •  CH3-CH=C|-CN                      CH3

  •                       OHCH3-CH-C||-COOH                      CH3

  •  CH3-CH=C|-CO-NH2                      CH3

In presence of iodine catalyst, chlorine reacts with acetic acid to form:
 

Acetic acid is obtained when:

  • glycerol is heated with sulphuric acid

  • methyl alcohol is oxidized with potassium permanganate

  • acetaldehyde is oxidized with potassium dichromate and sulphuric acid

  • calcium acetate is distilled in presence of calcium formate

Main product of the reaction, 

CH3CONH2+HNO2 ... is:

  • CH3COOH

  • CH3CH2NH2

  • CH3NH2

  • CH3COONH4

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