Which of the following is the strongest acid?
HCOOH (pKa 3.77)
C6H5COOH (pKa 4.22)
CH3COOH (pKa 4.71)
CH3CH2COOH (pKa 4.88)
Which of the following would produce secondary alcohol?
C6H5COCH3→2. H+1. CH3MgBr
C6H5COCH3→2. H+1. LiAlH4
C6H5CHO→2. H+1. LiAlH4
C6H5COOMe→2. H+1. LiAlH4
Product P in the above reaction is -
Amongst the following carboxylic acids the strongest acid is:
benzoic acid
0-methoxybenzoic acid
m-nitrobenzoic acid
p-nitrobenzoic acid
Ethanal reacts with HCN and the addition product so obtained is hydrolyzed to form a new compound. The compound shows
Optical isomerism
Geometrical isomerism
Tautomerism
Metamerism
Ethyl acetate on reaction with excess of methyl magnesium chloride and dil. H2SO4 gives
dimethyl ketone
iso propyl alcohol
ethyl aceto acetate
t-butyl alcohol
A mixture of benzaldehyde and formaldehyde on heating with aqueous (conc.)NaOH solution gives
benzyl alcohol and sodium formate
sodium benzoate and methyl alcohol
sodium benzoate and sodium formate
none of these
For the reaction:
Which reagent will be appropriate for the above conversion?
Zn-Hg/HCl
NH2-NH2/OH-
LiAlH4/H⊕
HI/P
Identify X
CH3OH
Ethyl alcohol
Methyl cyanide
tert-Butyl alcohol
Phenolphthalein is produced on heating phthalic anhydride and conc. sulphuric acid with
Salicylic acid
Phenol
Phenacetin
Phenanthrene
The compound Y in the above sequence of reactions is-
1-Phenylethene
2-Phenyl-2-propanol
Acetophenone
Benzaldehyde
In the following reaction:
The structure of the major product 'X' is
The compound can be exclusively oxidized into
by
NaCN followed by hydrolysis
NaOI followed by H3O+
KMnO4 hot followed by hydrolysis
K2Cr2O7 followed by H3O+
X ←∆KMnO4→∆Y
In the above reaction, X and Y are:
Identical
Homologous
Structural Isomers
Stereoisomers
Reactant (A) in this reaction is :
(d) Both (b) and (c)
→iiH+/H2OiNaOH/100°c
Major Product is:
Which compound is most reactive towards nucleophilic addition?
CH3CHO
PhCOCH3
PhCOPh
CH3COCH3
The reaction
is fastest when X is
Cl
NH2
OC2H5
OCOR
In a set of reaction propionic acid yielded a compound D.
CH3CH2COOH→SOCl2 B→∆NH3 C→Br2KOH
The structure of D would be
CH3CH2NHCH3
CH3CH2NH2
CH3CH2CH2NH2
CH3CH2CONH2
Hex-3-ene→2. Zn, H2O1. O3 A →H+KMnO4 B →Red PBr2 C→KOH (aq)D
D is :-
CH3-CH|Br-COOH
CH3-CH2-CHO
CH3-CH|Br-CHO
CH3-CH|OH-COOH
→ii·∆i·K2Cr2O7X; X is
→cold KMnO4P →AcOHCrO3Q→NH2NH2/OH- R compound R and R :-
Identical (Homomer)
Not isomer
Positional isomer
Function group isomer
+ →(1 eq)H+ A →ii· H3O+i. LiAlH4 B, B is
(1)
(2)
(3)
(4)
→PCCA →H+CH3NH2 B→H2/Pd-CProduct
Product is
1.
2.
3.
4.
→Zn-Hg/HClProduct, Product is
→I2+NaOH x + y(yellow ppt) y→∆Ag z;z is
CH≡CH
CHI3
Ph-COONa
CH2=CH2
→Zn/H2OO3I mole P→∆NaOH Q; Q is
The presence of unsaturation in organic compounds can be tested with :
Schiff's reagent
Tollen's reagent
Fehling's reagent
Baeyer's reagent
and can be distinguished by
1. I2+NaOH
2. NaSO3H
3. NaCN/HCl
4. 2,4-DNP
a,b,d
a,b
a,c,d
a,d
Fehling solution gives red precipitated with
(a) Aromatic aldehyde
(b) Aliphatic aldehyde
(c) Ketone
(d) terminal α-Hydroxy ketone
b,d
b,c
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