Which of the following is the strongest acid?

  • HCOOH (pKa 3.77)

  • C6H5COOH (pKa 4.22)

  • CH3COOH (pKa 4.71)

  • CH3CH2COOH (pKa 4.88)

Which of the following would produce secondary alcohol?

 

  • C6H5COCH32. H+1. CH3MgBr

  • C6H5COCH32. H+1. LiAlH4

  • C6H5CHO2. H+1. LiAlH4

  • C6H5COOMe2. H+1. LiAlH4

Product P in the above reaction is -

 

  •  

  •  

  •  

  •  

Amongst the following carboxylic acids the strongest acid is:

  • benzoic acid

  •  0-methoxybenzoic acid

  •  m-nitrobenzoic acid

  •  p-nitrobenzoic acid

Ethanal reacts with HCN and the addition product so obtained is hydrolyzed to form a new compound. The compound shows

  • Optical isomerism

  • Geometrical isomerism

  • Tautomerism

  • Metamerism

Ethyl acetate on reaction with excess of methyl magnesium chloride and dil. H2SO4 gives

  • dimethyl ketone

  • iso propyl alcohol

  • ethyl aceto acetate

  • t-butyl alcohol

A mixture of benzaldehyde and formaldehyde on heating with aqueous (conc.)NaOH       solution gives

  • benzyl alcohol and sodium formate

  • sodium benzoate and methyl alcohol

  • sodium benzoate and sodium formate

  • none of these

For the reaction:

 

Which reagent will be appropriate for the above conversion?

  • Zn-Hg/HCl

  • NH2-NH2/OH-

  • LiAlH4/H

  • HI/P

Identify X

  • CH3OH

  • Ethyl alcohol

  • Methyl cyanide

  • tert-Butyl alcohol

Phenolphthalein is produced on heating phthalic anhydride and conc. sulphuric acid with

  • Salicylic acid

  • Phenol

  • Phenacetin

  • Phenanthrene

The compound Y in the above sequence of reactions is- 

  • 1-Phenylethene

  • 2-Phenyl-2-propanol

  • Acetophenone

  • Benzaldehyde

In the following reaction:

The structure of the major product 'X' is

The compound  can be exclusively oxidized into

by

  • NaCN followed by hydrolysis

  • NaOI followed by H3O+

  • KMnO4 hot followed by hydrolysis

  • K2Cr2O7 followed by H3O+

KMnO4Y

In the above reaction, X and Y are:

  • Identical

  • Homologous

  • Structural Isomers

  • Stereoisomers

Reactant (A) in this reaction is : 

  •    

  •   (d) Both (b) and (c)

iiH+/H2OiNaOH/100°c

Major Product is:

  •  

  •  

Which compound is most reactive towards nucleophilic addition?

  • CH3CHO

  • PhCOCH3

  • PhCOPh

  • CH3COCH3

The reaction

is fastest when X is

  • Cl

  • NH2

  • OC2H5

  • OCOR

In a set of reaction propionic acid yielded a compound D.

CH3CH2COOHSOCl2 BNH3 CBr2KOH

The structure of D would be

  • CH3CH2NHCH3

  • CH3CH2NH2

  • CH3CH2CH2NH2

  • CH3CH2CONH2

Hex-3-ene2. Zn, H2O1. O3 A H+KMnO4 B Red PBr2 CKOH (aq)D

D is :-

  •  CH3-CH|Br-COOH                           

  •   CH3-CH2-CHO

  •  CH3-CH|Br-CHO                         

  •   CH3-CH|OH-COOH

ii·i·K2Cr2O7X; X is

  •  

 cold KMnO4P AcOHCrO3QNH2NH2/OH- R compound R and R :-

  • Identical (Homomer)

  • Not isomer

  • Positional isomer

  • Function group isomer

+ (1 eq)H+ A ii· H3O+i. LiAlH4 B, B is

(1)

(2)

(3)

(4)

 

  • 1
  • 2
  • 3
  • 4

PCCA H+CH3NH2 BH2/Pd-CProduct

Product is

1.

2.

3.

4.

 

  • 1
  • 2
  • 3
  • 4

Zn-Hg/HClProduct, Product is

  •     2.

  •  

  •     4.

  •  

I2+NaOH x + y(yellow ppt) yAg  z;z is

  • CHCH

  • CHI3

  • Ph-COONa

  • CH2=CH2

 Zn/H2OO3I mole PNaOH  Q; Q is

The presence of unsaturation in organic compounds can be tested with :

  • Schiff's reagent

  • Tollen's reagent

  • Fehling's reagent

  • Baeyer's reagent

and can be distinguished by

1. I2+NaOH

2. NaSO3H

3. NaCN/HCl

4. 2,4-DNP

 

  • a,b,d

  • a,b

  • a,c,d

  • a,d

Fehling solution gives red precipitated with

(a) Aromatic aldehyde

(b) Aliphatic aldehyde

(c) Ketone

(d) terminal α-Hydroxy ketone

 

  • b,d

  • a,b

  • a,d

  • b,c

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