Identify C in the following sequence of reactions :
Product (A) obtained is :
A set of reagents (1 to 8) are successively reacted with the following compound
1. NaHCO3
2. 2, 4, DNP
3. Na metal
4. AgNO3 +OH
5. Fehling's solution
6. Cu2CI2 + NH4OH
7. Br2/H2O
8. NaNO2 + HCI
The reagents which give the positive test with the given compound are :
1, 2, 3, 4, 5
3, 4, 5, 6, 8
1, 2, 3, 4, 8
All reagents except 1 and 8
Which of the following alcohol will show positive iodoform test ?
None of these
The compound A gives following reactions.
Its structure can be
In compound A (C30H60O) following tests are observed negatively, A can be :
an unsaturated ether
an epoxide
a cyclic ketone
a cycloalkanol
?
The major product of the reaction is:-
Which one of the following is the intermediate in the preparation of a ketone by hydration of an alkyne in the presence of sulfuric acid and mercury (II) sulphate?
→RCO2H product; Product of this reaction is:
()
() both (a) and (b)
() none of these
Above conversion can be achieved by:
() Wolf-kishner reduction
() Clemmensen reduction
() LiAlH4
() NaBH4
Product (A) is:
Reagent to carry out above conversion,P,Q,R respectively are:
H2C=CH-CH2-Br,(HOθ),[HOθ,∆], Wacker-process
H2C=CH-CH2-Br(HOθ), Wacker-process, HOθ,∆
Wacker process, H2C=CH-CH2-Br(HOθ),HOθ(∆)
Wacker process,HOθ(∆), H2C=CH-CH2-Br(HOθ)
Above compounds can be differentiated by following reagent:
2-4 DNP (Brady reagent)
Tollen's reagent
Bromine water reagent
NaHSO3
Product (D) will be :
Product (B) in this reaction is :
Ph-CllO-CH3→HClNaNO2(A)→heatAC2O(B)→H3O+(c)
Product (C) of the above reaction is :
Ph-CO2H
Ph-CllO-CO2H
Ph-CllO-CllO-H
Product (B) of the reaction is :
Ph-CH2-NO2
Ph-CH2-ONO
Ph-CHO
Ph-O-N=O
Correct order of reactivity of following compounds towards Grignard reagent ?
CH3-CllO-H (I) H-CllO-H (II)
I > II >III
II > I > III
II > III > I
I > III > I
What reagent and/or reaction conditions would you choose to bring about the following conversion?
(a) 1. LiAlH4, 2. H2O
(b) H2O, H2SO4, heat
(c) H2O, NaOH, heat
(d) PCC, CH2Cl2
CH3-c≡CH→dil. H2SO4HgSO4(A)
CH3-c≡CH→(2) H2SO4/HO-(1)BH3THF(B)
Product (A) and (B) is differentiated by:
() 2-4 DNP
() NaOI
() Na-metal
() NaHSO3
End Product (C) in above reaction is :
(b)
(c)
Compound (X) C4H8O, which reacts with 2, 4-DNP derivative and gives negative haloform test is.
() CH3-CHlCH3-CHO
() CH3-CH2-CHlOH-CH3
Ph-CH=CH-C||O-CH3→Ph-CH=CH-CO2HAbove conversion can be achieved by :
(a) KMnO4, ∆ followed by H+
(b) I2/NaOH followed by H+
(c) H2/Pt
(d) LiAlH4
Product (A) of the reaction is :
R-CllO-H→R-NH2R-CH=N-R. This reaction gives best yield at:
() pH 1 - 2
() pH 4 - 5
() pH 10 - 11
() pH 13 - 14
An aromatic compound A of the molecular formula C8H10O on reaction with iodine and dilute NaOH gives a yellow precipitate. The structure of the compound is expected to be-
C6H5CHOHCH3
In the following sequence :
CH3CH2Cl→NaCN(i)→Ni/H2(ii)→acetic anhydride(iii), product (iii) is
CH3CH2CH2NH2
CH3CH2CH2CONHCH3
CH3CH2CH2NHCOCH3
CH3CH2CH2CONHCOCH3
Carbonyl compounds can generally be converted to hydrocarbons by :
H2/Pt
LiAlH4
N2H4-KOH/∆
K2Cr2O7-H2SO4
Which statement about the aldol condensation is correct ?
A Lewis acid is commonly used as a catalyst
The initial step is probably the formation of a carbanion
A Lewis base is employed to induce carbocation formation
The carbon chain is lengthened through the elimination of 1 mole of water
Please disable the adBlock and continue. Thank you.