Identify C in the following sequence of reactions :

(1)  
(2)
(3)
(4)
  • 1
  • 2
  • 3
  • 4

Product (A) obtained is :

(1)  
(2)
(3)
(4)
  • 1
  • 2
  • 3
  • 4

A set of reagents (1 to 8) are successively reacted with the following compound

1. NaHCO3

2. 2, 4, DNP

3. Na metal

4. AgNO3 +OH

5. Fehling's solution

6. Cu2CI2 + NH4OH

7. Br2/H2O

8. NaNO2 + HCI

The reagents which give the positive test with the given compound are :

  • 1, 2, 3, 4, 5

  • 3, 4, 5, 6, 8

  • 1, 2, 3, 4, 8

  • All reagents except 1 and 8

Which of the following alcohol will show positive iodoform test ?

  • None of these

The compound A gives following reactions.

Its structure can be

(1)  
(2)
(3)
(4)
  • 1
  • 2
  • 3
  • 4

In compound A (C30H60O) following tests are observed negatively, A can be :

  • an unsaturated ether

  • an epoxide

  • a cyclic ketone

  • a cycloalkanol

 ?

The major product of the reaction is:-

  •   

  •   

  •   

  •   

Which one of the following is the intermediate in the preparation of a ketone by hydration of an alkyne in the presence of sulfuric acid and mercury (II) sulphate?

  •  

  •  

  •  

  •  

 RCO2H product; Product of this reaction is:

  • () 

  • () 

  • () both (a) and (b)

  • () none of these

Above conversion can be achieved by:

  • () Wolf-kishner reduction

  • () Clemmensen reduction

  • () LiAlH4

  • () NaBH4

Product (A) is:

  •  

  •  

  •   

  •    

Reagent to carry out above conversion,P,Q,R respectively are:

 

  • H2C=CH-CH2-Br,(HOθ),[HOθ,], Wacker-process

  • H2C=CH-CH2-Br(HOθ), Wacker-process, HOθ,

  • Wacker process, H2C=CH-CH2-Br(HOθ),HOθ()

  • Wacker process,HOθ(), H2C=CH-CH2-Br(HOθ)

Above compounds can be differentiated by following reagent:

  • 2-4 DNP (Brady reagent)

  • Tollen's reagent

  • Bromine water reagent

  • NaHSO3

Product (D) will be :

  •  

  •   

  •  

  •  

Product (B) in this reaction is :

  •  

  •      

  •     

  •     

Ph-CllO-CH3HClNaNO2(A)heatAC2O(B)H3O+(c)

Product (C) of the above reaction is :

  •  Ph-CO2H

  •  Ph-CllO-CO2H

  •  Ph-CllO-CllO-H

  •  Ph-CllO-CO2H

Product (B) of the reaction is :

  •  Ph-CH2-NO2

  •  Ph-CH2-ONO

  •  Ph-CHO

  •  Ph-O-N=O

Correct order of reactivity of following compounds towards Grignard reagent ?

CH3-CllO-H           (I)          H-CllO-H      (II)

  • I > II >III

  • II > I > III

  • II > III > I

  • I > III > I

What reagent and/or reaction conditions would you choose to bring about the following conversion?

  • (a) 1. LiAlH4, 2. H2O

  • (b) H2O, H2SO4, heat

  • (c) H2O, NaOH, heat

  • (d) PCC, CH2Cl2

CH3-cCHdil. H2SO4HgSO4(A)

CH3-cCH(2) H2SO4/HO-(1)BH3THF(B)

Product (A) and (B) is differentiated by:

  • () 2-4 DNP

  • () NaOI

  • () Na-metal

  • () NaHSO3

End Product (C) in above reaction is :

(b)

(c)

  • 1
  • 2
  • 3
  • 4

Compound (X) C4H8O, which reacts with 2, 4-DNP derivative and gives negative haloform test is.

  • () CH3-CllO-CH2-CH3

  • () CH3-CHlCH3-CHO

  • () 

  • () CH3-CH2-CHlOH-CH3

Product (B) of the reaction is :

  •  

  •  

  •  

  •  

Ph-CH=CH-C||O-CH3Ph-CH=CH-CO2H
Above conversion can be achieved by :

(a) KMnO4,  followed by H+

(b) I2/NaOH followed by H+

(c) H2/Pt

(d) LiAlH4

 

  • 1
  • 2
  • 3
  • 4

Product (A) of the reaction is :

  • 1
  • 2
  • 3
  • 4

R-CllO-HR-NH2R-CH=N-R. This reaction gives best yield at:

  • () pH 1 - 2

  • () pH 4 - 5

  • () pH 10 - 11

  • () pH 13 - 14

An aromatic compound A of the molecular formula C8H10O on reaction with iodine and dilute NaOH gives a yellow precipitate. The structure of the compound is expected to be-

  •  

  •  C6H5CHOHCH3

  •  

  •   

In the following sequence :

CH3CH2ClNaCN(i)Ni/H2(ii)acetic anhydride(iii), product (iii) is

  •  CH3CH2CH2NH2

  •  CH3CH2CH2CONHCH3

  •  CH3CH2CH2NHCOCH3

  •  CH3CH2CH2CONHCOCH3

Carbonyl compounds can generally be converted to hydrocarbons by :

  • H2/Pt

  • LiAlH4

  •  N2H4-KOH/

  •  K2Cr2O7-H2SO4

Which statement about the aldol condensation is correct ?

  • A Lewis acid is commonly used as a catalyst

  • The initial step is probably the formation of a carbanion

  • A Lewis base is employed to induce carbocation formation 

  • The carbon chain is lengthened through the elimination of 1 mole of water

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