The compound formed when malonic ester reacts with urea is:
cinnamic acid
butyric acid
barbituric acid
crotonic acid
The type of isomerism shown by C6H5CN and C6H5NC is:
Position
Functional
enantiomer
Tautomerism
Compound that will undergo Hoffmann reaction is-
RCONHCH3
RCOONH4
RCONH2
RCONHOH
The reagent needed to convert acetamide into methyl amine is -
NaOH/ Br2
Sodalime
Hot conc. H2SO4
PCl5
The above reaction is an example of....
Intermolecular C-N coupling
The hydrochlorides of amines form double salt with:
PtCl4
AuCl3
both (a) and (b)
none of these
Which of the following can not be formed by Gabriel phthalimide synthesis:-
(CH3)2CH-NH2
C2H5NH2
Ph-CH2-NH2
Ph-N⊕≡C⊝
An amine gives a solid compound that is insoluble in alkali with benzene sulphonyl chloride.
The amine is -
CH3-CH2-NH2
CH3-NH-CH2-CH3
(CH3)3N
C6H5-NH2
The compound A and B respectively are
The compound 'B' is-
Hydrolysis of alkyl isocyanide yields -
Primary Amine
Tertiary Amine
Alcohol
Aldehyde
The major product (A) formed in the above mentioned reaction is -
None of the above
Which of the following is hydrolyzed to give secondary amine?
Alkyl cyanide
HCON\CH3/CH3
Nitroparaffins
Acidamide
Ethylamine reacts with nitrosyl chloride (NOCl) to form:
ethyl chloride
ethyl alcohol
ethyl nitrite
nitroethane
Name the end product in the following series of reactions,
CH3COOH →NH3A→∆B→P2O5C:
CH4
CH3OH
acetonitrile
ammonium acetate
An organic compound A on reduction gives compound B which on reaction with chloroform and potassium hydroxide forms C. The compound C on catalytic reduction gives N-methylaniline. The compound A is
Nitromethane
Methylamine
Aniline
Acetamide and ethyl amine can be distinguished by reacting with
aq. HCl and heat
aq. NaOH and heat
acidified KMnO4
bromine water
Which of the following compound gives dye test
Diphenylamine
Ethylamine
CH3CH2Cl→NaCNX→Ni/H2Y→Acetic anhydrideZ
In the above reaction sequence, Z is
CH3CH2CH2NHCOCH3
CH3CH2CH2NH2
CH3CH2CH2CONHCH3
CH3CH2CH2CONHCOCH3
Predict the product,
Aniline in a set of reactions yield the following products
The structure of the product D would be -
C6H5CH2OH
C6H5CH2NH2
C6H5NHCH2CH3
C6H5NHOH
Intermediates formed during the reaction of RCONH2 with Br2 and KOH are -
RCONHBr and RNCO
RNHCOBr and RNCO
RNHBr and RCONHBr
RCONBr2
In a reaction of aniline a colored product C was obtained.
The structure of C would be
Product Q in the above reaction is
C in the above-mentioned reaction is -
Aniline when diazotised in cold and then treated with dimethylaniline, gives a coloured product. Its structure would be :
What is the end product in the following sequences of operations;
Acetamide→P2O5A→4HB ?
CH3NH2
CH3CN
CH3COONH4
are ........... isomers.
Chain
functional
position
all of these
Primary nitroalkanes on hydrolysis give:
RCOOH + NH2OH
RCOOH
NH2OH
RCOR
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