The numbers of primary amines posible for the formula C4H11N is -

  • 1

  • 2

  • 3

  • 4

The product D in the following sequence of reactoins is, 

CH3COOH NH3 A Heat B P2O5 C Na + C2H5OH D :

  • Ester

  • Amine

  • Acid

  • Alcohol

An aromatic primary amine with cold nitrous acid leads to the formation of:

  • alcohol

  • nitrite

  • diazonium salt

  • benzene

The least basic aqueous solution among the following is -

  •  (CH3)2NH

  •  CH3NH2

  •  (CH3)3N

  •  C6H5NH2

Which one of the following on reduction with LiAlH4 yields a secondary amine ?

[2007]

  • Methyl isocyanide

  • Acetamide

  • Methyl cyanide

  • Nitroethane

The IUPAC name of the compound having formula,

 O=CCHCH2      |       |        |    OH    NH2    OH is :

  • 3-Aminohydroxypropionic acid

  • 2-Amino-propan-3-oic acid

  • Amino hydroxy propionic acid

  • 2-Amino-3-hydroxy propanoic acid

In the reaction,

CH3CN+2HSnCl2HClX Boiling H2O Y, the term Y is 

[1999]

  • Acetone

  • Ethanamine

  • Acetaldehyde

  • Dimethyl amine

RMgX on reacting with cyanogen chloride gives:

  •  R-NC

  •  R-Cl

  •  R-CN

  • None of the above

X and Y in the given reaction are:

  •  CH3COOH + (CH3)2NH

  •  CH3CONH2 + CH3OH

  •  CH3CHO + (CH3)2NH

  •  CH3COCH3 + CH3NH2

Which of the following is the strongest base ?

  •  

  •  

  •  

  •  

Primary, secondary and tertiary nitroalkanes can be identifier by the action of:

  •  HNO2 + NaOH(aq)

  •  CHCl3 + NaOH (aq)

  •  CHCl3 + KOH(alc.)

  • none of these

Consider the following sequence of reactions

Compound[A]Reduction[B] HNO3CH3CH2OH 

The compound [A] is

 

  • CH3CH2CN

  • CH3NO2

  • CH3NC

  • CH3CN

Which of the following statements about primary amines is false ?

[2010]

  • Alkyl amines are stronger bases than aryl amines

  • Alkyl amines react with nitrous acid to produce alcohols

  • Aryl amines react with nitrous acid to produce phenols

  • Alkyl amines are stronger bases than ammonia

When NaNO2 and dilute HCl were added to an amine at 0°c, a colourless gas was evolved and an ionic compound is formed. The amine is:

  • any primary amine

  • an aromatic primary amine

  • any amine

  • none of the above

The compound obtained by heating a mixture of primary amine and chloroform with ethanolic potassium hydroxide (KOH) is

[1997]

  • An alkyl isocyanide

  • An alkyl halide

  • An amide

  • An amide and nitro compound

Identify 'Z' in the change;

C6H5NH2280KNaNO2/HClXCuBr/HBrZ:

  •  

  •  

  •  

  •  

Among the following, the strongest base is:

  • C6H5NH2

  •  p-NO2-C6H4NH2

  •  m-NO2-C2H4NH2

  • C2H5CH2NH2

A nitrogenous substance X is treated with HNO2 and the product so formed is further treated with NaOH solution, which produces blue colouration. X can be:

  •  CH3CH2NH2

  •  CH3CH2NO2

  •  (CH3)2C(N=O)(NO2)

  •  (CH3)2CHNO2

Alkanamide that gives 1-phenylethylamine on Hoffmann's reaction is:

  • 2-Phenylpropanamide

  • 3-Phenylpropanamide

  • 2-Phenylethanamide

  •  N-Phenylethanamide

The IUPAC name of the given comound is -

  

  • 1-Methyl-aminopropane

  • Butan-2-amine

  • 2-Methyl-2-aminopropane

  • None of the above

The correct order of increasing reactivity of C-X bond towards nucleophile in the following compound is

[2010]

  • I<II<IV<III

  • II<III<I<IV

  • IV<III<I<II

  • III<II<I<IV

Aniline is reacted with bromine water and the resulting product is treated with an aqueous solution of sodium nitrite in presence of dilute hydrochloric acid. The compound so formed is converted into a tertafluoroborate which is subsequently heated. The final product is    

  • 1,3,5-tribromobenzene

  •  p-bromofluorobenzene

  •  p-bromoaniline

  • 2,4,6-tribromofluorobenzene

Alkyl halide (RX) on treatment with KCN followed by reduction leads to the formation of:

  • RNH2

  •  RCH2NH2

  •  RH + NH3

  •  RCH3 + N2

The end product in the following sequence of reactions is -

C2H5NH2HNO2A PCl5BNH3C?

  • Ethyl cyanide

  • Ethylamine

  • Methylamine

  • Acetamide

CH3CH2NH2 contains a basic NH2 group, but CH3CONH2 does not, because;

  • acetamide is amphoteric in character

  • in CH3CH2NH2 the electron pair on N-atom is delocalized by resonance

  • in CH3CH2NH2 there is no resonance, while in acetamide the lone pair of electron on N-atom is delocalized and therefore less available for protonation

  • none of the above

Dehydration of an amide gives:

  • Cyanide

  • Amine

  • Isocyanide

  • Fatty acid

A secondary amine is:

  • a compound with two -NH2 groups

  • a compound with 2 carbon atoms and a -NH2 group

  • a compound with a -NH2 group on the carbon atom in number 2 position

  • a compound in which 2 of the hydrogens of NH3 have been replaced by alkyl or aryl groups

NH42SA0-5°CNaNO2/HClBC2H5OHC

Product (C) is 

  • Nitrobenzene

  • 1,3-Diethoxybenzene

  • Ethoxybenzene

  • Benzene

Reaction of R-C||O-NH2 with a mixture of Br2 and KOH gives R-NH2 as the main product. The intermediates involved in this reaction are: 

  •  R-C||O-NHBr and R-N=C=O

  • RCN

  •  R-C||O-NBr2

  • RNHBr

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