(NH4)2SO4 + KCNO upon heating generates -
Nitrogen gas
Carbon dioxide
Biuret
Ammonium carbonate
Which of the following reagents will convert nitromethane into methylamine ?
Zn/HCl
Zn/NaOH
Zn/C2H5OH
Ni/H2
Nitrobenze on reduction with Al-Hg and water gives:
azobenze
aniline
azoxy benzene
phenylhydroxylamine
The reduction of CH3CN to CH3CH2NH2 is called:
Rosenmund's reduction
Clemmensen's reduction
Mendius reduction
Hofmann's reduction
Aniline and ethylamine resembles in:
solubility
action with HNO2
action of Grignard reagent
coupling reaction
Mendius method of preparation of amines consists of:
catalytic reduction of alkyl cyanides
reduction of amide with LiAlH4
reduction of nitroparaffin with Sn + HCl
reduction of oximes with Na + C2H5OH
ln the reaction,
The product is:
The correct order of basicities of the following compounds is:
CH3-C|||NH2NH1, CH3CH2NH22 , CH32NH3 , CH3-C||O-NH24
2 > 1 > 3 > 4
1> 3 > 2 > 4
3 > 1 > 2 > 4
1 > 2 > 3 > 4
A primary amine heated with CS2 in presence of excess of HgCl2 gives isothiocyanate. The reaction is called:
Hofmann's bromamide reaction
Hofmann's mustard oil reaction
Perkin's condensation
Hofmann's elimination
In the compound given below,
the correct order of acidic nature of the positions (X), (Y) and (Z) is:
Z>X>Y
X>Y>Z
X>Z>Y
Y>X>Z
Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an acid forms a compound if water during the reaction is continuously removed. The compound formed is generally known as:
Schiff's base
an enamine
an imine
an amine
The alkene formed as a major product in the given elimination reaction is:
CH2=CH2
+
The product (A) in the above mentioned reaction is :
In the following reaction, the product X is:
→Cone.H2SO4cone.HNO3 x
The correct structure of ethylenediaminetetraacetic acid (EDTA) is:
Biuret test is not given by:
proteins
carbohydrates
polypeptides
urea
An aromatic amine (A) was treated with alcoholic potash and another compound (Y) when a foul smelling gas was formed with formula C6H5NC. (Y) was formed by reacting a compound (Z) with Cl2 in the presence of slaked lime. Compound (Z) is:
C6H5NH2
CH3OH
CH3COCH3
CHCl3
The product obtained on nitration followed by alkaline hydrolysis of acetylated aniline is:
o-Nitroacetanilide
o- and p-Nitroaniline
m-Nitroaniline
Acetanilide
The formula of picramide is :
Pyridine possesses :
aromatic nature
unsaturated aliphatic nature
alicyclic nature
aliphatic nature
Ammoniacal solution of Ni(CN)2 reacts with C6H6 to produce a light violet coloured crystaline compound of the formula:
Ni(CN)2·C6H5
C6H5CH3
Ni(CN)2C6H6
Ni(CN)2NH3·C6H6
The diazonium salt gives, with:
HCl/CuCl
HNO2/Cu
C2H5OH
SnCl2/HCl
The reaction, C6H5N2Cl →Cu2Cl2/HClC6H5Cl + N2 is called:
Etard's reaction
Sandmeyer's reaction
Wurtz-Fitting reaction
Perkin's reaction
Choose the correct statement from the ones given below for two anilium in:
II is not an acceptable canonical structure because carbonium ions are less stable than ammonium ions
II is not an acceptable canonical structure because it is non-aromatic
II is not an acceptable canonical structure because the nitrogen has 10 valence electrons
II is an acceptable canonical structure
When nitrobenzene is treated with Br2 in presence of FeBr3, the major product formed is m-bromonitrobenzene. Statements which are related to obtain the m-isomer are:
the relative electron density on meta carbon is more than that of ortho and para positions
loss of aromaticity when Br+ attacks at the ortho and para positions and not at meta position
easier loss of H+ to regain aromaticity from the meta positions than from ortho and para positions
none of the above
In the chemical reactions,
→HCl, 278 KNaNO2A→HBF4B
the compounds 'A' and 'B' respectively are:
Nitrobenzene and chlorobenzene
Nitrobenzene and fluorobenzene
Phenol and benzene
Benzene diazonium chloride and fluorobenzene
The presence of NH4+ radical in solution can be detected by:
Fehling’s solution
Benedict’s solution
Schiff's reagent
Nessler’s reagent
Potassium thiocyanate solution reacts with ferric chloride to give:
pink colour
deep blue colour
green colour
blood-red colour
An organic compound X (mol. formula C6H5O2N) has 6 carbon atoms in a ring system, three double bonds and also a nitro group as substituent X is:
Homocyclic but not aromatic
Aromatic but not homocyclic
Homocyclic and aromatic
Heterocyclic
A reaction that can convert acetamide to methanamine is -
Carbylamine reaction
Hoffmann bromamide reaction
Stephens reaction
Gabriels phthalimide synthesis
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