(NH4)2SO4 + KCNO upon heating generates -

  • Nitrogen gas

  • Carbon dioxide

  • Biuret

  • Ammonium carbonate

Which of the following reagents will convert nitromethane into methylamine ?

  • Zn/HCl

  • Zn/NaOH

  • Zn/C2H5OH

  • Ni/H2

Nitrobenze on reduction with Al-Hg and water gives:

  • azobenze

  • aniline

  • azoxy benzene

  • phenylhydroxylamine

The reduction of CH3CN to CH3CH2NH2 is called:

  • Rosenmund's reduction

  • Clemmensen's reduction

  • Mendius reduction

  • Hofmann's reduction

Aniline and ethylamine resembles in:

  • solubility

  • action with HNO2

  • action of Grignard reagent

  • coupling reaction

Mendius method of preparation of amines consists of: 

  • catalytic reduction of alkyl cyanides

  • reduction of amide with LiAlH4 

  • reduction of nitroparaffin with Sn + HCl

  • reduction of oximes with Na + C2H5OH

ln the reaction, 

The product is: 

 

  •  

  •  

  •  

  •  

The correct order of basicities of the following compounds is:

CH3-C|||NH2NH1,  CH3CH2NH22 , CH32NH3 ,  CH3-C||O-NH24

  • 2 > 1 > 3 > 4

  • 1> 3 > 2 > 4

  • 3 > 1 > 2 > 4

  • 1 > 2 > 3 > 4

A primary amine heated with CS2 in presence of excess of HgCl2 gives isothiocyanate. The reaction is called:

  • Hofmann's bromamide reaction

  •  Hofmann's mustard oil reaction

  • Perkin's condensation

  • Hofmann's elimination

In the compound given below,

the correct order of acidic nature of the positions (X), (Y) and (Z) is: 

  • Z>X>Y

  • X>Y>Z

  • X>Z>Y

  • Y>X>Z

Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an acid forms a compound if water during the reaction is continuously removed. The compound formed is generally known as:

  • Schiff's base

  • an enamine

  • an imine

  • an amine

The alkene formed as a major product in the given elimination reaction is:   

  •  

  •  CH2=CH2     

  •  

  •                            

 

The product (A) in the above mentioned reaction is :

  •  

  •  

  •  

  •  

In the following reaction, the product X is:

Cone.H2SO4cone.HNO3 x

  •  

  •  

  •  

  •  

The correct structure of ethylenediaminetetraacetic acid (EDTA) is: 

  •  

  •  

  •  

  •  

Biuret test is not given by: 

  • proteins

  • carbohydrates

  • polypeptides

  • urea

An aromatic amine (A) was treated with alcoholic potash and another compound (Y) when a foul smelling gas was formed with formula C6H5NC. (Y) was formed by reacting a compound (Z) with Cl2 in the presence of slaked lime. Compound (Z) is:

  •  C6H5NH2

  •  CH3OH

  •  CH3COCH3

  •  CHCl3

The product obtained on nitration followed by alkaline hydrolysis of acetylated aniline is:

  •  o-Nitroacetanilide

  •  o- and p-Nitroaniline

  •  m-Nitroaniline

  • Acetanilide

The formula of picramide is :

  •  

  •  

  •  

  •  

Pyridine possesses :

  • aromatic nature

  • unsaturated aliphatic nature

  • alicyclic nature

  • aliphatic nature

Ammoniacal solution of Ni(CN)2 reacts with C6H6 to produce a light violet coloured crystaline compound of the formula:

  •  Ni(CN)2·C6H5

  •  C6H5CH3

  •  Ni(CN)2C6H6

  •  Ni(CN)2NH3·C6H6

The diazonium salt  gives,  with:

  • HCl/CuCl

  • HNO2/Cu

  • C2H5OH

  •   SnCl2/HCl

The reaction, C6H5N2Cl Cu2Cl2/HClC6H5Cl + N2 is called:

  • Etard's reaction

  • Sandmeyer's reaction

  • Wurtz-Fitting reaction

  • Perkin's reaction

Choose the correct statement from the ones given below for two anilium in:

                   

  • II is not an acceptable canonical structure because carbonium ions are less stable than ammonium ions

  • II is not an acceptable canonical structure because it is non-aromatic

  • II is not an acceptable canonical structure because the nitrogen has 10 valence electrons

  • II is an acceptable canonical structure

When nitrobenzene is treated with Br2 in presence of FeBr3, the major product formed is m-bromonitrobenzene. Statements which are related to obtain the m-isomer are:

  • the relative electron density on meta carbon is more than that of ortho and para positions

  • loss of aromaticity when Br+ attacks at the ortho and para positions and not at meta position

  • easier loss of H+ to regain aromaticity from the meta positions than from ortho and para positions

  • none of the above

In the chemical reactions,

HCl, 278 KNaNO2AHBF4B

the compounds 'A' and 'B' respectively are:

  • Nitrobenzene and chlorobenzene

  • Nitrobenzene and fluorobenzene

  • Phenol and benzene

  • Benzene diazonium chloride and fluorobenzene

The presence of NH4+ radical in solution can be detected by:

 

  • Fehling’s solution

  • Benedict’s solution

  • Schiff's reagent

  • Nessler’s reagent

Potassium thiocyanate solution reacts with ferric chloride to give:

  • pink colour

  • deep blue colour

  • green colour

  • blood-red colour

An organic compound X (mol. formula C6H5O2N) has 6 carbon atoms in a ring system, three double bonds and also a nitro group as substituent X is:

  • Homocyclic but not aromatic

  • Aromatic but not homocyclic

  • Homocyclic and aromatic

  • Heterocyclic

A reaction that can convert acetamide to methanamine is -

  • Carbylamine reaction

  • Hoffmann bromamide reaction

  • Stephens reaction

  • Gabriels phthalimide synthesis

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